Patent classifications
C22B1/005
Chemical process for the recovery of alkaline and zinc-carbon battery components
A process is described for the recovery of the chemical components of the “black paste” resulting from the opening of dead alkaline and zinc-carbon batteries.
METHOD FOR RECOVERING PLATINUM GROUP METALS
A method for recovering platinum group metals, includes melting a material to be treated containing platinum group metals, under heating in a furnace, along with a copper source material containing at least one kind of metallic copper and copper oxide, a flux component, and a reducing agent. The molten metal absorbing the platinum group metals is separated from a slag oxide through difference in specific gravity. The molten metal absorbing the platinum group metals is subjected to an oxidation treatment. An oxide layer containing as a major component copper oxide and a molten metal containing as a major component metallic copper containing the platinum group metals concentrated therein are separated through difference in specific gravity. A silver content in the molten metal separated in melting under heating is controlled to 2,000 ppm or more and 8,000 ppm or less, thereby recovering platinum group metals with high efficiency.
Lithium Iron Phosphate (LFP) battery recycling
The inventions described herein provide methods and systems for recycling lithium iron phosphate batteries, including: adding an oxidizing agent to a recycling stream of lithium iron phosphate (LiFePO.sub.4) batteries to form a leach solution; filtering the leach solution to remove a residue and obtain a lithium rich solution; modifying pH of the lithium rich solution for filtering impurities and obtaining a purified Li solution; and adding a precipitant to the purified Li solution thereby precipitating a lithium compound.
Method for processing electronic and electrical device component scrap
Provided is a method for processing electronic and electrical device component scrap, which can accurately and efficiently sort electronic and electrical device component scrap. The method for processing electronic and electrical device component scrap includes a separation step of separating non-metal objects 1b or metal objects 1a.sub.1, 1a.sub.2 from electronic and electrical device component scrap 1 containing the metal objects 1a.sub.1, 1a.sub.2 and the non-metal objects 1b using a sorter 10 comprising a metal sensor 2, a color camera 3, an air valve 4, and a conveyor 5, wherein a fixed distance is provided between the metal objects 1a.sub.1, 1a.sub.2 adjacent to each other so as to prevent the non-metal objects 1b between the metal objects 1a.sub.1, 1a.sub.2 from being erroneously detected, when detecting the metal objects 1a.sub.1, 1a.sub.2 in the electronic and electrical device component scrap 1 by the metal sensor 2.
METHOD FOR PRETREATING MAGNESIUM-ALLOY WASTE MATERIAL
A method comprises sorting and removing impurities from magnesium alloy waste material, and cleaning and drying said material, the cleaning being high-pressure rinsing, pickling, and water washing, performed in sequence. The method employs high-pressure rinsing during the pretreatment of magnesium alloy waste material; the cleaning effectiveness is excellent, the effectiveness of the removal of impurities from the surface of the magnesium alloy waste material is much better than in conventional processes, and the amount of clean waste material can exceed 90% of the total amount of processed waste material; the clean magnesium alloy waste material obtained from the pretreatment method may be used as the entire raw materials for casting national-standard alloy ingots, the addition of costly high-purity magnesium is unnecessary, and the amount of alloy raw material that must be added is significantly reduced; during processing, little waste material is lost, costs are low, and efficiency is high.
Recycling of cobalt and nickel from lithium-ion batteries
A process for recovering a nickel cobalt manganese hydroxide from recycled lithium-ion battery (LIB) material such as black mass, black powder, filter cake, or the like. The recycled LIB material is mixed with water and either sulfuric acid or hydrochloric acid at a pH less than 2. Cobalt, nickel, and manganese oxides from the recycled lithium-ion battery material dissolve into the acidic water with the reductive assistance of gaseous sulfur dioxide. Anode carbon is filtered from the acidic water, leaving the dissolved cobalt, nickel, and manganese oxides in a filtrate. The filtrate is mixed with aqueous sodium hydroxide at a pH greater than 8. Nickel cobalt manganese hydroxide precipitates from the filtrate. The nickel cobalt manganese hydroxide is filtered from the filtrate and dried. The filtrate may be treated ammonium fluoride or ammonium bifluoride to precipitate lithium fluoride from the filtrate. The composition ratio of nickel to cobalt to manganese in the acid filtrate may be adjusted to a desired ratio. The anode carbon is recovered and purified for reuse.
DESULFURISATION OF LEAD-CONTAINING WASTE
The present invention relates to the desulfurisation of lead-containing waste. In particular, the present invention relates to a method in which lead-containing waste is desulfurised to form a desulfurised lead-containing waste material which is suitable for recycling into lead or leady oxide. The method is particularly suitable for desulfurising lead-acid battery paste.
METHOD FOR REUSING ACTIVE MATERIAL BY USING POSITIVE ELECTRODE SCRAP
A method for reusing a positive electrode active material includes dry-milling a positive electrode scrap comprising an active material layer on a current collector to convert the active material layer into a powdered state and to separate the active material layer from the current collector. The active material layer is a lithium composite transition metal oxide positive material active material layer. The method further includes adding a lithium precursor to a the active material layer. The method further includes thermally treating the active material layer in the powdered state to collect an active material. The method further includes obtaining a reusable active material by washing the collected active material with a basic lithium compound aqueous solution and drying the collected active material.
METHOD FOR RECYCLING RARE EARTH SINTERED MAGNET
A method for recycling a rare earth magnet is described. The rare earth magnet has a film containing Ni on the surface thereof, and the method involves immersing the rare earth magnet in a stripping solution containing a derivative of nitrobenzene, ethylenediamine, and ammonia. This strips the Ni on the surface of the rare earth magnet without deteriorating the characteristics of the rare earth magnet, thereby improving its product yield.
Method to open up electro chemical energy storage devices and thermal treatment system
A method for breaking down electrochemical energy storage devices in conjunction with a subsequent reclamation of recyclable materials contained therein as secondary raw materials. The devices are broken down by a thermal treatment in a negative pressure environment in a process chamber to remove electrolyte and reactive substances, before the thermally treated material is subjected to downstream processing, by which the secondary raw materials are separated from one another. After introducing a batch of storage devices, in a first process step, the process chamber is evacuated with simultaneous heating of the devices to a first temperature level such that electrolytes in the devices evaporate and, due to the resulting vapor pressure, the devices are opened, wherein produced process gases containing electrolytes in the vapor phase are withdrawn from the process chamber. The devices are then heated to a second temperature level for further breakdown with a simultaneous pressure increase in the process chamber in a reducing atmosphere, before the chamber is ventilated and cooled and the broken down devices are removed, wherein the pressure increase is monitored during this second process step so that it increases continuously. Also, a thermal treatment system for removing electrolytes and reactive substances in electrochemical energy storage devices, thus for pyrolytically breaking them down.