The present disclosure provides a three-dimensional alkynyl-containing porous aromatic framework polymer and a preparation method and use thereof. The polymer has a structure represented by Formula I:

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The preparation method includes: under a protective atmosphere, mixing tetrakis(p-bromophenyl)methane, 1,3,5-triethynyl benzene, a catalyst and an amine solvent, and subjecting to a Sonogashira-Hagihara coupling reaction to obtain the three-dimensional alkynyl-containing porous aromatic framework polymer having the structure represented by Formula I.

The invention discloses a method for cracking slag and smelting soot of the waste circuit board, belongs to the field of comprehensive recycling of valuable elements from typical soot of waste circuit boards, and particularly relates to a method for cracking slag and smelting soot of the waste circuit board for debromination and comprehensive recovery of copper and zinc. The method includes the following steps of: crushing and sorting, mixture roasting, reinforced leaching, replacement and silver precipitation, sulfuration and copper precipitation, and evaporation crystallization. Compared to traditional recycling technology, the purpose of treating two kinds of solid waste in a coupling mode through one recycling technology is achieved. Through mixed sulfuric acid roasting, the requirement of bromide synergistic removal of the waste circuit board cracking slag and smelting soot is met, and the purpose of selective conversion of copper and zinc is achieved.

Recovery of noble metals (including the recovery of gold and/or silver from gold and/or silver containing material) is generally described. The gold and/or silver can be recovered selectively, in some cases, such that gold and/or silver are at least partially separated from non-silver and/or non-gold material. Gold and/or silver may be recovered from material using mixtures of acids, in some instances. In some cases, the mixture can comprise nitric acid and at least one supplemental acid, such as sulfuric acid, phosphoric acid, and/or a sulfonic acid. The amount of nitric acid within the mixture can be, in some instances, relatively small compared to the amount of sulfuric acid or phosphoric acid within the mixture. In some cases, the recovery of gold and/or silver using the acid mixtures can be enhanced by transporting an electric current between an electrode and the gold and/or silver of the material. In some cases, acid mixtures can be used to recover silver from particular types of materials, such as material comprising silver metal and cadmium oxide and/or material comprising silver metal and tungsten metal.

A method for recovering precious metal from an acidic aqueous solution containing dissolved precious metal and free chlorine, comprising the following successive steps: (1) combining a salt of a non-precious metal present in a low oxidation state as a solid or as an aqueous solution with the acidic aqueous solution to consume the free chlorine and form an acidic aqueous mixture, and (2) adding non-precious metal to the acidic aqueous mixture formed in step (1) to precipitate elementary precious metal.

The invention discloses a method for co-processing cracking slag and smelting soot of the waste circuit board, belongs to the field of comprehensive recycling of valuable elements from typical soot of waste circuit boards, and particularly relates to a method for co-processing cracking slag and smelting soot of the waste circuit board for debromination and comprehensive recovery of copper and zinc. The method mainly comprises the following steps of: crushing and sorting, mixture roasting, reinforced leaching, replacement and silver precipitation, sulfuration and copper precipitation, and evaporation crystallization. Compared with a traditional recycling technology, the purpose that two kinds of solid waste are treated in a coupling mode through one recycling technology is achieved. Through mixed sulfuric acid roasting, the requirement of bromide synergistic removal of the waste circuit board cracking slag and smelting soot is met, and the purpose of selective conversion of copper and zinc is achieved.

A method for extracting noble metals from mining tailings and other solids is provided. The method uses a Lewis acid, Brønsted acid, complexing agent and oxygen to provide excellent extraction without the need for chorine gas or cyanide.

The invention relates to a method of recovering Pt or Ag or Pt and Ag from a sulfate solution on an electrode. In particular, the invention concerns a method for recovering Pt or Ag or Pt and Ag from base metal bearing process solution, particularly from a hydrometallurgical sacrificial metal bearing solution containing Zn and/or Ni. In general, the method of the present invention can be used for recovery of precious metals, which are dissolvable in sulfuric acid, from sulfate media based solutions. In addition to Pt and Ag, especially Pd should be mentioned. Deposited precious metal(s) can be recovered from the electrode or the deposition containing electrode can be used as such.

Provided is a platinum-group metal recovery method for efficiently recovering a platinum-group metal. The method for recovering a platinum-group metal includes an immobilization step of causing a molten product of a raw material containing a platinum-group metal, a molten product of a carbonate or hydroxide of an alkali metal, a molten product of an oxide, and a ceramic material to make contact with each other so as to immobilize the platinum-group metal on the ceramic material.

A method for recovering metals from waste materials includes steps of contacting a waste material feed stream with a first lixiviant adapted to leach copper and other base metals from the waste material feed stream and provide a treated waste material feed stream, recovering copper metal from the first lixiviant, contacting the treated waste material stream with a second lixiviant adapted to leach noble metals from the treated waste material feed stream and recovering gold from the second lixiviant.

The present invention relates to a method for recovering metals using an adsorbent, which comprises preparing a leachate comprising metal ions and cyanides, wherein the metal ions comprise gold ions and copper ions; and in a state where the leachate has a cyanide (CN) concentration of 0.1 ppm or greater, adding to the leachate an adsorbent, which has an open circuit potential value between the open circuit potential value of the gold ions and that of the copper ions; and selectively adsorbing the copper ions to the adsorbent.