Patent classifications
C22B11/046
METHODS FOR THE SEPARATION AND/OR PURIFICATION OF METALS
A method for separating at least two metals from each other in a metal refining process, the method comprising: injecting a feed solution comprising the metals into a column or flow pipe comprising a monolithic solid body having a plurality of channels; and flowing the feed solution through the plurality of channels in the monolithic solid body to separate the metals.
Cost-effective method for recovering precious metals in circuit board components
The invention discloses a cost-effective method for recovering precious metals in circuit board components, and belongs to the area of waste resource recovery. The method mainly solves the problem of selective recovery of precious metals in chlorination leachate, utilizes the basic principle of oxidation-reduction reaction, adopts a mixed solution of sulfuric acid and hydrogen peroxide and a mixed solution of hydrochloric acid, sodium chloride and sodium chlorate, and also adopts ammonia water and formaldehyde to reduce silver. According to the characteristic that the redox potential of gold and palladium ions is higher, the gold and palladium ions in the chlorination leaching solution are selectively reduced into elements by using a reducing agent which is low in price and moderate in reducibility, then the elements are separated through filtration to realize resource recycling. The whole recycling process is greatly shortened, combined with the lower price of reducing agents, leading to the low cost of process. The method is commercially viable and is beneficial to industrialization. Meanwhile, a large amount of tail liquid is prevented from being generated to pollute the environment in the recycling process.
System and method for obtaining mineral rich powder from electronic waste
Ways of obtaining a mineral rich powder from an electronic waste substrate include a shredder configured to receive the electronic waste substrate and process the electronic waste substrate into a plurality of fragments. A mill is provided that includes a container configured to receive the plurality of fragments, the container including a milling media, the mill configured to abrade the plurality of fragments with the milling media to produce a milled product. A separator is provided that is configured to receive the milled product, where the separator is configured to apply a predetermined size selection to the milled product to provide a first output including a plurality of particles and a second output including a plurality of abraded fragments. A skid is coupled to and provides structural support for the shredder, the mill, and the separator.
METHOD OF RECOVERING MATERIALS BOUND TO A METALLIC SUBSTRATE USING CRYOGENIC COOLING AND AN AQUEOUS SOLUTION
A recycling process that facilitates separation of materials from metallic substrates by cryogenically cooling the recyclable items to induce embrittlement of the metals. Embrittled metals may be shattered more efficiently and with a higher yield of materials bound to the metallic substrates. Metal embrittlement may be induced by mixing the source stream with liquid nitrogen, and cooling the stream to approximately minus 200° F. Multiple recovery stages may be employed to maximize the yield of the target materials. Embodiments may enable recovery of platinum group metals (PGMs) from catalytic converters with metallic foil substrates. Yield of PGMs may be enhanced by employing a primary recovery stage and a secondary recovery stage, by cryogenically cooling input materials for each stage, by mixing the pulverized material in secondary recovery with an aqueous solution to dissipate attractive charges, and by wet screening the pulverized material slurry to obtain the PGM particles.
Method for whole component microwave fast digestion and precious metal extraction from ionic liquid of waste circuit board
The invention discloses Method for whole component microwave fast digestion and precious metal extraction from ionic liquid of waste circuit board, and belongs to the field of hydrometallurgy. Based on the theory that microwaves can directly penetrate through a leaching medium to directly heat a circuit board, microwave-assisted leaching can reinforce mass transfer and heat transfer in the traditional leaching process, the leaching time is greatly shortened, and the leaching efficiency is improved. Before leaching, a waste circuit board does not need to be smashed, and environmental protection is achieved while energy is saved. The temperature rising process and reaction time of the reaction can be controlled, the whole process is conducted under the airtight condition, heat loss in the leaching process is avoided, the valuable leaching rate is high, the selectivity is high, and efficient leaching of valuable metal can be achieved. Precious metal leachate is extracted through imidazolium ionic liquid, the selectivity of the imidazolium ionic liquid to gold is high, and the co-extraction phenomenon of gold, nickel, copper and other ions is avoided. The method for extracting the precious metal leachate through ionic liquid is a green and clean recycling method, and the overall recycling rate of gold, nickel and copper can reach 99% or above
SIMPLIFIED METHOD OF GOLD RECOVERY FROM ELECTRONIC WASTE
The present invention related to generally to a process to recover metals from waste electronics, and more particularly a process to recover gold from waste electronics. The gold is first delaminated in a first step using a solution containing a weak acid in combination with an oxidizer. The second step isolates and purifies the delaminated gold from the chip debris using solvents, water and a wetting agent/surfactant. The proposed two step method of gold recovery from electronic waste is effective without the need for strong or costly chemicals or leaching.
METHOD FOR RECYCLING SILVER PRESENT ON A PHOTOVOLTAIC CELL
A method for recycling silver present on a photovoltaic cell comprising: —a step a) of supplying a photovoltaic cell including —a support substrate made of silicon, —an upper layer of doped silicon arranged on the support substrate, —a plurality of silver lines arranged on the upper layer, —at least one anti-reflective layer arranged on the upper layer and adjacent to the silver lines; —a step b) of etching the anti-reflective layer by immersing the photovoltaic cell in an acid solution; —a step c) of etching the upper layer by immersing the photovoltaic cell without an anti-reflective layer in a basic solution, leading to the separation of the silver lines; —a step d) of drying the assembly formed by the support substrate and the separated silver lines; —a step e) of extracting the silver lines in the solid state.
METHOD FOR RECOVERING VALUABLES
A method for recovering valuables, which can suppress the loss of valuables in recovering the valuables is provided. The method for recovering valuables of the disclosure comprises: a preparation step of preparing a treatment object including a valuables-containing member that contains valuables on or above a surface of a base material; an immersion step of immersing the treatment object in a liquid such that the valuables-containing member of the treatment object is disposed in the liquid; a collection step of irradiating the valuables-containing member of the treatment object immersed in the liquid with laser light through the liquid so as to remove the valuables-containing member from the treatment object, thereby collecting removed matter of the valuables-containing member into the liquid; and a recovery step of recovering the removed matter of the valuables-containing member from the liquid.
Comprehensive Recovery Method Of Pyrolysis Polymetallic Product From Waste Integrated Circuit Board
The invention relates to a method for multi-metal products recovery from pyrolytic waste integrated circuit boards. The method mainly comprises the steps of smelting and blending, atomization, acidolysis and filtration, noble metal recycling, copper extraction and back extraction, nickel extraction and back extraction. Compared with the prior art, the method has the advantages that smoke pollution and the smelting slag treatment in the process of preparing a black copper ingot through multi-metal collaborative smelting are reduced, and the problems of low anode efficiency of the black copper electrolysis process are solved. Meanwhile, the high-temperature high-oxygen atomized gas generated in the atomizing process provides a heat source and an oxygen source for subsequent acidolysis, so that the energy consumption is further reduced. The method has the advantages such as short process, remarkable energy conservation and emission reduction.
Method of recovering materials bound to a metallic substrate using cryogenic cooling
A recycling process that facilitates separation of materials from metallic substrates by cryogenically cooling the recyclable items to induce embrittlement of the metals. Embrittled metals may be shattered more efficiently and with a higher yield of materials bound to the metallic substrates. Metal embrittlement may be induced by mixing the source stream with liquid nitrogen, and cooling the stream to approximately minus 200° F. Multiple recovery stages may be employed to maximize the yield of the target materials. Embodiments may enable recovery of platinum group metals (PGMs) from catalytic converters with metallic foil substrates. Yield of PGMs may be enhanced by employing a primary recovery stage and a secondary recovery stage, by cryogenically cooling input materials for each stage, by mixing the pulverized material in secondary recovery with an aqueous solution to dissipate attractive charges, and by wet screening the pulverized material slurry to obtain the PGM particles.