The present invention relates to the desulfurisation of lead-containing waste. In particular, the present invention relates to a method in which lead-containing waste is desulfurised to form a desulfurised lead-containing waste material which is suitable for recycling into lead or leady oxide. The method is particularly suitable for desulfurising lead-acid battery paste.

Lead is recovered from lead paste of a lead acid battery in a continuous and electrochemical lead recovery process. In especially preferred aspects, lead paste is processed to remove residual sulfates, and the so treated lead paste is subjected to a thermal treatment step that removes residual moisture and reduces lead dioxide to lead oxide. Advantageously, such pretreatment will avoid lead dioxide accumulation and electrolyte dilution.

A method for preparing lead directly from a lead-containing material by a solid phase reaction, includes: step 1, adding the lead-containing material to be processed to the grinder, and adding a metal substance and water to the grinder, wherein an activity of the metal substance is larger than that of lead; the solid phase reaction between the lead-containing material and the metal substance is caused directly by the grinder through a mechanical force to obtain a reaction product; step 2, washing and filtering the reaction product to obtain the lead and a metal salt solution corresponding to the metal substance; step 3, performing a melt casting on the lead to obtain a crude lead, crystallizing the metal salt solution to obtain a metal salt corresponding to the metal substance.

A method for recycling lead from spent lead-acid battery paste, relating to the technical field of hydrometallurgy. In the method, firstly a reducing agent, and a lead paste are added into a zinc chloride solution for leaching in a stirring mill to cause lead in the lead paste to enter the solution, a lead cementation is performed by using zinc in the leached solution, after the lead cementation, the electrolytic zinc is produced by controlling an electrodeposition on the zinc chloride solution for a short time, the reducing agent is zinc, lead or hydrogen peroxide, a part of the electrolytic zinc is returned as the reducing agent for leaching, the step of returning the electrolytic zinc as the reducing agent can be omitted when the lead or the hydrogen peroxide is used as the reducing agent.

A system for melting lead scrap pieces. The system includes a vessel. A vortexing chamber is disposed in the vessel. The vortexing chamber includes an inlet, an outlet and an open top configured to receive lead pieces. A pump is disposed in the vessel and directs molten lead to the inlet of the vortexing chamber. A dross dam divides the vessel into a first region and a second region. The vortexing chamber is disposed in the second region and a conduit extends between the vortexing chamber outlet and the first region. A transfer pump is disposed in the second region and is configured for removal of molten lead from the vessel. The system allows dross to be skimmed from a surface of the molten lead bath in the first region.

Lead is recovered from lead paste of a lead acid battery in a continuous and electrochemical lead recovery process. In especially preferred aspects, lead paste is processed to remove residual sulfates, and the so treated lead paste is subjected to a thermal treatment step that removes residual moisture and reduces lead dioxide to lead oxide. Advantageously, such pretreatment will avoid lead dioxide accumulation and electrolyte dilution.

The present invention relates to the desulfurisation of lead-containing waste. In particular, the present invention relates to a method in which lead-containing waste is desulfurised to form a desulfurised lead-containing waste material which is suitable for recycling into lead or leady oxide. The method is particularly suitable for desulfurising lead-acid battery paste.

The present invention relates, on one hand, to a metal cementing apparatus (1) formed by a vessel (2) with a liquid phase formed by a solution (3) containing noble metal, and a solid phase formed by a cementing metal or a less noble metal in contact with the solution (3), where one of said phases moves at a high speed with respect to the other one, and the difference in speeds allows the cementation of the noble metal on the solid phase, and the simultaneous detachment and separation thereof, and comprises means for generating the movement of at least the phase with the high speed and removing means for removing the precipitated noble metal. The invention describes, on the other hand, a continuous cementation method consisting of passing a continuous flow of solution in a vessel (2); reacting the solid phase with the liquid phase, where one of said phases moves at a high speed with respect to the other one, causing the fixing of the noble metal and the simultaneous detachment thereof; removing the precipitated noble metal.

A hydrometallurgical method for simultaneously extracting zinc, lead, silver, iron and calcium from electric arc furnace dust (hazardous waste) produced by the steelmaking industry (steelworks), in the form of industrial products: zinc as zinc sulphate or zinc cathodes; lead and silver as a concentrate of lead and silver; iron as reduced elemental iron for return to the electric arc furnace; and, lastly, calcium as gypsum, without solid waste or liquid effluents being generated relates to the chemical nature of the electric arc furnace dust (complex oxides) changes to a sulfide complex, and eliminating the hazards associated with the generation of fugitive heavy-metal salts. In addition, the hydrometallurgical problem of low recovery of zinc and iron is solved. Consequently, hydrometallurgy is made easier and more environmentally friendly, as condensed water is used as a leachate, the condensed water being continuously regenerated by vacuum evaporation systems without generating effluents.

The invention relates to the field of efficient separation and recovery of bromine by full wet method, especially to a two-step separating method of bromide and recovery of lead and zinc from printed circuit board Incineration ash. It mainly includes first sodium hydroxide alkaline leaching, secondary sodium peroxide alkaline leaching, pH adjustment, separate lead and zinc, bromide evaporation and crystallization to recover crude bromide and other steps. Compared with traditional comprehensive recovery process of ash, the invention uses sodium hydroxide to dissolve bromide, lead and zinc, and uses the strong oxidation of sodium peroxide in alkaline environment, copper bromide and other bromine are oxidized and leached; through two-step method, the efficient leaching of bromine, lead and zinc is realized, silver and other precious metals are enriched at the same time. It is beneficial to subsequent recovery of precious metals and has the characteristics of short tail liquid discharge.