The present invention lies in the field of pyrometallurgy and discloses a process and a slag suitable for the recovery of Ni and Co from Li-ion batteries or their waste. The slag composition is defined according to:

10%<MnO<40%;

(CaO+1.5*Li.sub.2O)/Al.sub.2O.sub.3>0.3;

CaO+0.8*MnO+0.8*Li.sub.2O<60%;

(CaO+2*Li.sub.2O+0.4*MnO)/SiO.sub.2≥2.0;

Li.sub.2≥1%; and,

Al.sub.2O.sub.3+SiO.sub.2+CaO+Li.sub.2O+MnO+FeO+MgO>85%.

This composition is particularly adapted to limit or avoid the corrosion of furnaces lined with magnesia-bearing refractory bricks.

The present invention lies in the field of pyrometallurgy and discloses a process and a slag suitable for the recovery of Ni and Co from Li-ion batteries or their waste. The slag composition is defined according to:
10%<MnO<40%;
(CaO+1.5*Li.sub.2O)/Al.sub.2O.sub.3>0.3;
CaO+0.8*MnO+0.8*Li.sub.2O<60%;
(CaO+2*Li.sub.2O+0.4*MnO)/SiO.sub.2≥2.0;
Li.sub.2≥1%; and,
Al.sub.2O.sub.3+SiO.sub.2+CaO+Li.sub.2O+MnO+FeO+MgO>85%.
This composition is particularly adapted to limit or avoid the corrosion of furnaces lined with magnesia-bearing refractory bricks.

The present invention lies in the field of pyrometallurgy and discloses a process and a slag suitable for the recovery of Ni and Co from Li-ion batteries or their waste. The slag composition is defined according to:

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This composition is particularly adapted to limit or avoid the corrosion of furnaces lined with magnesia-bearing refractory bricks.

The present disclosure is directed to processes for separating a mixture of oxalates of two or more of Ni (nickel), Co (cobalt) and Mn (manganese). Such processes are useful, for example, to separate recovery of two or more of Ni, Co and Mn from used ithium ion batteries or from waste of the production of lithium ion batteries or of cells or components of lithium ion batteries.

The present invention lies in the field of pyrometallurgy and discloses a process and a slag suitable for the recovery of Ni and Co from Li-ion batteries or their waste, particularly from Black Mass. The slag composition is defined according to: 25% < MnO < 70%; Al.sub.2O.sub.3 + 0.5 MnO < 45% SiO.sub.2 > 5%; Li.sub.2O > 1%; MnO + Li.sub.2O + Al.sub.2O.sub.3 + CaO + SiO.sub.2 + FeO + MgO + P.sub.2O.sub.5 > 90%; and, wherein (CaO + 2 Li.sub.2O + 0.4 MnO) / SiO.sub.2 ≥ 2.0. This composition is particularly adapted to limit or avoid the wear or corrosion of furnaces lined with magnesia-bearing refractory bricks.

The present disclosure provides a method for recovering nickel and cobalt, the method comprising: a first step of heat-treating lithium nickel cobalt aluminum oxide to produce a mixture; a second step of water-washing the mixture produced in the first step to obtain a residue; and a third step of heat-treating the residue obtained in the second step.

A method for recovering the valuable materials from energy storage devices (e.g., spent rechargeable lithium batteries, especially those batteries using nickel-based or nickel and cobalt containing cathode materials) are described. In particular, the proposed method applies carbonyl technology, also known as vapometallurgy, to regenerate pure materials which can be reused as raw materials for making active cathode materials for new lithium batteries.

The present invention lies in the field of pyrometallurgy and discloses a process and a slag suitable for the recovery of Ni and Co from Li-ion batteries or their waste. The slag composition is defined according to:
10%<MnO<40%;
(CaO+1.5*Li.sub.2O)/Al.sub.2O.sub.3>0.3;
CaO+0.8*MnO+0.8*Li.sub.2O<60%;
(CaO+2*Li.sub.2O+0.4*MnO)/SiO.sub.22.0;
Li.sub.2O1%; and,
Al.sub.2O.sub.3+SiO.sub.2+CaO+Li.sub.2O+MnO+FeO+MgO>85%. This composition is particularly adapted to limit or avoid the corrosion of furnaces lined with magnesia-bearing refractory bricks.

The present invention lies in the field of pyrometallurgy and discloses a process and a slag suitable for the recovery of Ni and Co from Li-ion batteries or their waste, particularly from Black Mass. The slag composition is defined according to: 25%<MnO<70%; Al.sub.2O.sub.3+0.5 MnO<45% SiO.sub.2>5%; Li.sub.2O>1%; MnO+Li.sub.2O+Al.sub.2O.sub.3+CaO+SiO.sub.2+FeO+MgO+P.sub.2O.sub.5>90%; and, wherein (CaO+2 Li.sub.2O+0.4 MnO)/SiO.sub.22.0. This composition is particularly adapted to limit or avoid the wear or corrosion of furnaces lined with magnesia-bearing refractory bricks.