A nickel recovery process capable of decreasing nickel remaining in a byproduct by recovering nickel from the byproduct of electrolytic nickel manufacturing process by chlorine-leaching, and also, capable of simplifying a cementation step simultaneously, is provided. In a nickel recovery step S60, a nickel recovery step S70 and a nickel recovery step S80, nickel is recovered in each step from S.sup.0 slurry, residue flaker and chlorine-leached residue, which are byproducts of electrolytic nickel manufacturing process by chlorine-leaching, by using an aqueous solution containing 80 g/L to 390 g/L of chlorine and 30 g/L to 70 g/L of copper.

The present disclosure relates to a process for the recovery of transition metals from batteries comprising treating a transition metal material with a leaching agent to yield a leach which contains dissolved salts of nickel and/or cobalt, injecting hydrogen gas in the leach at a temperature above 100° C. and a partial pressure above 5 bar to obtain a nickel and/or cobalt precipitate in elemental form, and separating the obtained nickel and/or cobalt precipitate.

What is provided is a method for separating cobalt and nickel including: a crushing and sorting step of crushing and classifying the lithium ion secondary battery to obtain an electrode material containing at least cobalt, nickel, copper, and lithium; a leaching step of immersing the electrode material in a processing liquid containing sulfuric acid and hydrogen peroxide to obtain a leachate; a copper separation step of adding a hydrogen sulfide compound to the leachate with stirring and subsequently carrying out solid-liquid separation to obtain an eluate containing cobalt and nickel and a residue containing copper sulfide; and a cobalt/nickel separation step of adding an alkali metal hydroxide to the eluate to adjust a pH and subsequently, adding a hydrogen sulfide compound with stirring and carrying out solid-liquid separation to obtain a precipitate containing cobalt sulfide and nickel sulfide and a residual liquid containing lithium.

This invention discloses a process and its products for spent lithium-ion batteries treatment, which relates to the field of spent battery treatment technology. This process comprises: fully discharging spent lithium-ion batteries to obtain discharged spent lithium-ion batteries; crushing spent lithium-ion batteries to obtain crushed products of spent lithium-ion batteries; screening crushed products of spent lithium-ion batteries by screens to obtain an overflow and an underflow; sorting the overflow to obtain separator products, plastic products, iron products, copper foil products and aluminum foil products; mechanochemically activating the underflow to obtain activated products; acid leaching the activated products by degradable organic acid to obtain a mixture containing activated products and the organic acid leaching solution; filtering the mixture which contains the activated products and the organic acid leaching solution to obtain graphite as filter residues. Copper mud products and LiNi.sub.0.85Co.sub.0.1Al.sub.0.05O.sub.2 can be obtained after further treatments. This process can effectively recover recyclable resources in spent lithium-ion batteries, and reduce pollution of heavy metals.

The present description relates to a process for producing magnesium metal from magnesium-bearing ores using serpentine. The process described herein consists generally in a mineral preparation and classification followed by leaching with dilute hydrochloric acid. The slurry is filtered and the non-leached portion, containing amorphous silica is recovered. The residual solution is neutralized and purified by chemical precipitation with non activated and activated serpentine. The nickel is also recovered by precipitation at higher pH. A final neutralisation and purification step of magnesium chloride solution by precipitation allows eliminating any traces of residual impurities. The purified magnesium chloride solution is evaporated until saturation and the MgCl.sub.2.6H.sub.2O is recovered by crystallization in an acid media. The salt is dehydrated and subsequent electrolysis of anhydrous magnesium chloride produces pure magnesium metal and hydrochloric acid.

A process for recovering non-ferrous metals from a solid matrix may include: (a) leaching the solid matrix with an aqueous-based solution containing chloride ions, ammonium ions, and Cu.sup.2+ ions, having a pH of 6.5-8.5, in a presence of oxygen, at a temperature of 100 C.-160 C. and a pressure of 150 kPa-800 kPa, so as to obtain an extraction solution comprising leached metals and solid leaching residue; (b) separating the solid leaching residue from the extraction solution; and/or (c) subjecting the extraction solution to at least one cementation so as to recover the leached metals in elemental state. The pH may be greater than or equal to 6.5 and less than or equal to 8.5. Temperature may be greater than or equal to 100 C. and less than or equal to 160 C. Pressure may be greater than or equal to 150 kPa and less than or equal to 800 kPa.

An aqueous cobalt chloride solution refinement method, in which metallic nickel is washed with an acidic liquid having a pH of not more than 2.5 before the metallic nickel is brought into contact with the aqueous solution containing cobalt chloride. Since the metallic nickel is washed with the acidic liquid having a pH of not more than 2.5, a passive film on a surface of the metallic nickel is removed and therefore, when the metallic nickel comes in contact with the aqueous solution containing cobalt chloride, an impurity more noble than the metallic nickel can be precipitated by a cementation reaction. In addition, since the metallic nickel is only washed with acid to be brought into contact with the aqueous solution containing cobalt chloride, impurities can be easily removed from the aqueous solution containing cobalt chloride.

The present invention provides a method for removing copper from lithium ion battery scrap containing copper, comprising a leaching step of adding the lithium ion battery scrap to an acidic solution and leaching the lithium ion battery scrap under a condition that an aluminum solid is present in the acidic solution; and a copper separating step of separating copper contained in the acidic solution as a solid from the acidic solution, after the leaching step.

A nickel recovery process capable of decreasing nickel remaining in a byproduct by recovering nickel from the byproduct of electrolytic nickel manufacturing process by chlorine-leaching, and also, capable of simplifying a cementation step simultaneously, is provided. In a nickel recovery step S60, a nickel recovery step S70 and a nickel recovery step S80, nickel is recovered in each step from S.sup.0 slurry, residue flaker and chlorine-leached residue, which are byproducts of electrolytic nickel manufacturing process by chlorine-leaching, by using an aqueous solution containing 80 g/L to 390 g/L of chlorine and 30 g/L to 70 g/L of copper.

An aqueous cobalt chloride solution purification method, in which impurities can be efficiently removed from a cobalt salt solution, includes bringing metallic nickel into contact with an aqueous solution containing cobalt chloride to remove an impurity by a substitution reaction, in which the pH of the aqueous solution containing cobalt chloride is adjusted to not less than 1.5 and not more than 2.5. Since the pH of the aqueous solution containing cobalt chloride is adjusted to not less than 1.5 and not more than 2.5, a passive film on a surface of the metallic nickel can be effectively removed, and the metallic nickel comes in contact with the aqueous solution containing cobalt chloride, so that an impurity more noble than the metallic nickel can be precipitated by the substitution reaction. The metallic nickel is only brought into contact with the aqueous solution containing cobalt chloride, and the impurity can be easily removed.