Pyro-hydrometallurgical methods are described to economically and environmentally recover a target metal from iron slag or steel slag. For instance, the method can enable subjecting an iron or steel slag feed to acid-baking with an acid to produce a dried mixture comprising at least one soluble metal salts, then subjecting the dried mixture to water leaching to an aqueous solution comprising an aqueous leachate rich in said target metal and solid residues and subsequently separating the aqueous leachate rich in said target metal from the solid residues. This acid-baking water-leaching method facilitates efficient recovery of target metal compared to conventional methods.

Pyro-hydrometallurgical methods are described to economically and environmentally recover a target metal from iron slag or steel slag. For instance, the method can enable subjecting an iron or steel slag feed to acid-baking with an acid to produce a dried mixture comprising at least one soluble metal salts, then subjecting the dried mixture to water leaching to an aqueous solution comprising an aqueous leachate rich in said target metal and solid residues and subsequently separating the aqueous leachate rich in said target metal from the solid residues. This acid-baking water-leaching method facilitates efficient recovery of target metal compared to conventional methods.

The present disclosure provides a method for co-extraction of vanadium, titanium and chromium from vanadium slag. The method selectively reduces pyroxene and fayalite wrapped on spinel through low-temperature hydrogen reduction, iron removal by ferric chloride, and low-temperature leaching of the vanadium slag by oxalic acid, thereby destroying a structure of the spinel, dissociating a spinel phase and a silicate phase, and fully exposing the spinel phase. The method also directly leaches the vanadium slag at a low temperature by acidity and strong complexation of the oxalic acid, and destroys the structure of the spinel, such that vanadium, titanium, chromium and oxalate are complexed into a solution to co-extract vanadium, titanium and chromium. The present disclosure extracts vanadium, titanium and chromium from the vanadium slag, with a leaching rate each being greater than 99%.

The present disclosure provides a method for co-extraction of vanadium, titanium and chromium from vanadium slag. The method selectively reduces pyroxene and fayalite wrapped on spinel through low-temperature hydrogen reduction, iron removal by ferric chloride, and low-temperature leaching of the vanadium slag by oxalic acid, thereby destroying a structure of the spinel, dissociating a spinel phase and a silicate phase, and fully exposing the spinel phase. The method also directly leaches the vanadium slag at a low temperature by acidity and strong complexation of the oxalic acid, and destroys the structure of the spinel, such that vanadium, titanium, chromium and oxalate are complexed into a solution to co-extract vanadium, titanium and chromium. The present disclosure extracts vanadium, titanium and chromium from the vanadium slag, with a leaching rate each being greater than 99%.

The invention discloses a method for co-processing cracking slag and smelting soot of the waste circuit board, belongs to the field of comprehensive recycling of valuable elements from typical soot of waste circuit boards, and particularly relates to a method for co-processing cracking slag and smelting soot of the waste circuit board for debromination and comprehensive recovery of copper and zinc. The method mainly comprises the following steps of: crushing and sorting, mixture roasting, reinforced leaching, replacement and silver precipitation, sulfuration and copper precipitation, and evaporation crystallization. Compared with a traditional recycling technology, the purpose that two kinds of solid waste are treated in a coupling mode through one recycling technology is achieved. Through mixed sulfuric acid roasting, the requirement of bromide synergistic removal of the waste circuit board cracking slag and smelting soot is met, and the purpose of selective conversion of copper and zinc is achieved.

The invention provides cement additives comprising calcium sulfate and silica which are derived from a material comprising perovskite and silica, along with cements and cementitious products comprising the cement additives. The invention also provides methods for the making the cement additive and cements and cementitious products comprising the cement additives.

A method for recovering metal zinc from a solid metallurgical waste containing zinc and manganese, may include: (a) bringing the solid metallurgical waste into contact with an aqueous leaching solution comprising chloride ions and ammonium ions to produce at least one leachate including zinc ions and manganese ions and at least one insoluble solid residue; (b) cementing the leachate, by adding metal zinc as a precipitating agent, to eliminate at least one metal other than zinc and manganese possibly present in the leachate as ions and producing a purified leachate; (c) subjecting the purified leachate to electrolysis in an electrolytic cell including at least one cathode and at least one anode immersed in the purified leachate to deposit metal zinc on the cathode and producing at least one exhausted leachate, and, before the electrolysis, precipitating manganese ions by oxidation with permanganate ions and subsequently separating a precipitate including MnO.sub.2.

A process for separating a fusion mix sample comprising a slag material and a collector material using a separator. The separator comprising a plurality of impact members configured to rotate. The process comprising the steps of providing a solid fusion mix sample and loading the solid sample into the separator. Dislodging the slag material from the solid fusion mix sample by rotating the impact members and contacting the rotating impact members and the solid fusion mix sample. Separating into a first fraction substantially comprising the collector material and a second fraction substantially comprising slag material.

A method for treating converter slag for the purpose of recirculating iron, wherein a converter slag is brought into contact with oxygen in such a way that by means of turbulence, the slag is mixed, the iron and iron oxide components that are present are oxidized, and the slag is then allowed to stand in the vessel or a vessel until a segregation into a solidifying, silicate and phosphorus-rich first fraction and an underlying liquid iron oxide-rich second fraction has taken place, with the converter slag that is used being mixed with a partial flow from the iron oxide-rich second fraction in such a way that the total FeO content of the slag that is to be treated with oxygen is over 35% by weight, thus enabling the segregation into two fractions.

A method for treating converter slag for the purpose of recirculating iron, wherein a converter slag is brought into contact with oxygen in such a way that by means of turbulence, the slag is mixed, the iron and iron oxide components that are present are oxidized, and the slag is then allowed to stand in the vessel or a vessel until a segregation into a solidifying, silicate and phosphorus-rich first fraction and an underlying liquid iron oxide-rich second fraction has taken place, with the converter slag that is used being mixed with a partial flow from the iron oxide-rich second fraction in such a way that the total FeO content of the slag that is to be treated with oxygen is over 35% by weight, thus enabling the segregation into two fractions.