Patent classifications
C22C23/06
Magnesium-based alloy wrought product and method for producing same
Provided is Mg-based alloy wrought material having improved ductility, formality, and resistance against fracture. Intermetallic compounds may be formed by mutual bonding of added elements to be a fracture origin. While maintaining microstructure for activating non-basal dislocation movement of Mg-based alloy wrought material, added elements to create no fracture origin, but to promote grain boundary sliding were found from among inexpensive and versatile elements. Provided is Mg-based alloy wrought material including at least one element from Zr, Bi, and Sn and at least one element from Al, Zn, Ca, Li, Y, and Gd wherein remainder comprises Mg and unavoidable impurities; an average grain size in a parent phase is 20 μm or smaller; a value of (σ.sub.max−σ.sub.bk)/σ.sub.max (maximum load stress (σ.sub.max), breaking stress (σ.sub.bk)) in a stress-strain curve obtained by tension-compression tests of the wrought material is 0.2 or higher; and resistance against breakage shows 100 kJ or higher.
MAGNESIUM ALLOY
Magnesium alloys and a process of manufacturing an article using magnesium alloys. During additive manufacturing, where the magnesium alloy is being deposited in a layer-by-layer manner, solidification of the melted portion of a deposited layer is performed in such a way as to ensure that about 15 percent or more of the portion being solidified includes a non-equilibrium eutectic constituent. This in turn reduces the likelihood of encountering solidification conditions that otherwise would lead to hot tearing problems. Further, upon subsequent heat treatment of the solidified layer, the eutectic constituents that were used for hot tearing resistance are dissolved so that the solidified layer may be returned to a substantially single-phase magnesium matrix such that desirable material properties such as improved flammability point, improved corrosion resistance and one or more of high yield strength, ultimate tensile strength and elongation are promoted.
MAGNESIUM ALLOY
Magnesium alloys and a process of manufacturing an article using magnesium alloys. During additive manufacturing, where the magnesium alloy is being deposited in a layer-by-layer manner, solidification of the melted portion of a deposited layer is performed in such a way as to ensure that about 15 percent or more of the portion being solidified includes a non-equilibrium eutectic constituent. This in turn reduces the likelihood of encountering solidification conditions that otherwise would lead to hot tearing problems. Further, upon subsequent heat treatment of the solidified layer, the eutectic constituents that were used for hot tearing resistance are dissolved so that the solidified layer may be returned to a substantially single-phase magnesium matrix such that desirable material properties such as improved flammability point, improved corrosion resistance and one or more of high yield strength, ultimate tensile strength and elongation are promoted.
CORRODIBLE DOWNHOLE ARTICLE
A corrodible downhole article includes a magnesium alloy. The magnesium alloy includes: 1-9 wt % Zn; 1-2 wt % Cu; 0.5-1.0 wt % Mn; and 0.1-5 wt % of a corrosion promoting element (e.g., Ni). The alloy can have a 0.2% proof strength of at least 150 MPa when tested using standard tensile test method ASTM B557-10.
CORRODIBLE DOWNHOLE ARTICLE
A corrodible downhole article includes a magnesium alloy. The magnesium alloy includes: 1-9 wt % Zn; 1-2 wt % Cu; 0.5-1.0 wt % Mn; and 0.1-5 wt % of a corrosion promoting element (e.g., Ni). The alloy can have a 0.2% proof strength of at least 150 MPa when tested using standard tensile test method ASTM B557-10.
Additive manufacturing methods using aluminum-rare earth alloys and products made using such methods
Described herein are additive manufacturing methods and products made using such methods. The alloy compositions described herein are specifically selected for the additive manufacturing methods and provide products that exhibit superior mechanical properties as compared to their cast counterparts. Using the compositions and methods described herein, products that do not exhibit substantial coarsening, such as at elevated temperatures, can be obtained. The products further exhibit uniform microstructures along the print axis, thus contributing to improved strength and performance. Additives also can be used in the alloys described herein.
HIGH-STRENGTH AND HIGH-CORROSION-RESISTANT TERNARY MAGNESIUM ALLOY AND PREPARATION METHOD THEREOF
The present invention relates to a high-strength, high-corrosion resistance ternary magnesium alloy and a preparation method therefor, the magnesium alloy comprising the following element components by mass percentage: 8-12 wt % of Y, 0.6-3 wt % of Al and the remainder being Mg. The method comprises: (1) under a protective atmosphere, preparing a Mg—Y intermediate alloy, an aluminum ingot and a magnesium ingot into a magnesium alloy melt; (2) under a protective atmosphere, allowing the magnesium alloy melt to stand after stirring, then carrying out refining, degassing, and slag removal, allowing the magnesium alloy melt to stand again, then thermally insulating to obtain a magnesium alloy liquid; and (3) casting and molding the magnesium alloy liquid under a protective atmosphere, and forming a cast ingot; the three steps above ultimately obtain a high-strength, high-corrosion resistance ternary magnesium alloy.
HIGH-STRENGTH AND HIGH-CORROSION-RESISTANT TERNARY MAGNESIUM ALLOY AND PREPARATION METHOD THEREOF
The present invention relates to a high-strength, high-corrosion resistance ternary magnesium alloy and a preparation method therefor, the magnesium alloy comprising the following element components by mass percentage: 8-12 wt % of Y, 0.6-3 wt % of Al and the remainder being Mg. The method comprises: (1) under a protective atmosphere, preparing a Mg—Y intermediate alloy, an aluminum ingot and a magnesium ingot into a magnesium alloy melt; (2) under a protective atmosphere, allowing the magnesium alloy melt to stand after stirring, then carrying out refining, degassing, and slag removal, allowing the magnesium alloy melt to stand again, then thermally insulating to obtain a magnesium alloy liquid; and (3) casting and molding the magnesium alloy liquid under a protective atmosphere, and forming a cast ingot; the three steps above ultimately obtain a high-strength, high-corrosion resistance ternary magnesium alloy.
METALLIC DELAY BARRIER COATING FOR SWELLABLE PACKERS
A swellable packer assembly that includes a mandrel, a sealing element disposed about a least a portion of the mandrel, and a degradable metal coating disposed about at least a portion of an outer surface of the sealing element. The degradable metal coating fluidly isolates the portion of an outer surface of the sealing element from an exterior of the coating and the sealing element is formed of a material responsive to exposure to a fluid in a wellbore to radially expand from the mandrel. The degradable metal coating is selectively removable from the mandrel downhole so as to expose the sealing element to the fluid in the wellbore.
METALLIC DELAY BARRIER COATING FOR SWELLABLE PACKERS
A swellable packer assembly that includes a mandrel, a sealing element disposed about a least a portion of the mandrel, and a degradable metal coating disposed about at least a portion of an outer surface of the sealing element. The degradable metal coating fluidly isolates the portion of an outer surface of the sealing element from an exterior of the coating and the sealing element is formed of a material responsive to exposure to a fluid in a wellbore to radially expand from the mandrel. The degradable metal coating is selectively removable from the mandrel downhole so as to expose the sealing element to the fluid in the wellbore.