The present invention is to provide powder made of iron-based metallic glass, the corrosion resistance of which is improved over the conventional powder made of iron-based metallic glass. The basic composition includes a group of iron-based metallic elements that predominantly has Fe, a group of metalloid elements that consists of Si, B, P, and C, and a little amount of a group of elements for improving the degree of supercooling that consists of either or both of Nb and Mo. The powder made of the iron-based metallic glass is obtained by adding to the basic composition an element for improving the corrosion resistance. The obtained powder made of the iron-based metallic glass has an excellent corrosion resistance, an excellent magnetic property, and an excellent insulating property.

The present disclosure is directed and formulations and methods to provide alloys having relative high strength and ductility. The alloys may be provided in seamless tubular form and characterized by their particular alloy chemistries and identifiable crystalline grain size morphology. The alloys are such that they include boride pinning phases. In what is termed a Class 1 Steel the alloys indicate tensile strengths of 700 MPa to 1400 MPa and elongations of 10-70%. Class 2 Steel indicates tensile strengths of 800 MPa to 1800 MPa and elongations of 5-65%. Class 3 Steel indicates tensile strengths of 1000 MPa to 2000 MPa and elongations of 0.5-15%.

Embodiments disclosed herein relate to the production of amorphous metals having compositions of iron, chromium, molybdenum, carbon and boron for usage in additive manufacturing, such as in layer-by-layer deposition to produce multi-functional parts. Such parts demonstrate ultra-high strength without sacrificing toughness and also maintain the amorphous structure of the materials during and after manufacturing processes. Two additive manufacturing techniques are provided: (1) the complete melting of amorphous powder and re-solidifying to amorphous structure to eliminate the formation of crystalline structure therein by controlling a heating source power and cooling rate without affecting previous deposited layers; and (2) partial melting of the outer surface of the amorphous powder, and solidifying powder particles with each-other without undergoing a complete melting stage. Amorphous alloy compositions have oxygen impurities in low concentration levels to optimize glass forming ability (GFA). Specific techniques of additive manufacturing include those based on lasers, electron beams and ultrasonic sources.

There is provided an amorphous alloy thin strip having a chemical composition represented by a chemical formula: Fe.sub.xB.sub.ySi.sub.z (x: 78-83 at %, y: 8-15 at % and z: 6-13 at %) capable of stably attaining a low iron loss even when shaped into a wound core, wherein a generation density of air pockets on a face contacting with a cooling roll is not more than 8 per 1 mm.sup.2 and an arithmetic mean height Sa on portions other than the air pockets is not more than 0.3 μm.

An amorphous soft magnetic alloy of the formula (Fe.sub.1-αTM.sub.α).sub.100-w-x-y-zP.sub.wB.sub.xL.sub.ySi.sub.z Ti.sub.pC.sub.qMn.sub.rCu.sub.s, wherein TM is Co or Ni; L is Al, Cr, Zr, Mo or Nb; 0≦α≦0.3, 2≦w≦18 at %, 2≦x≦18 at %, 15≦w+x≦23 at %, 1<y≦5 at %, 0≦z≦4 at %; p, q, r, and s represents an addition ratio such that the total mass of Fe, TM, P, B, L and Si is 100, and 0≦p≦0.3, 0≦q≦0.5, 0≦r≦2, 0≦s≦1 and r+s>0; the composition fulfills one of the following conditions: L is Cr, Zr, Mo or Nb; or L is a combination of Al and Cr, Zr, Mo or Nb, wherein 0<Al≦5 at %, 1≦Cr≦4 at %, 0<Zr≦5 at %, 2≦Mo≦5 at %, and 2≦Nb≦5 at %; the alloy has a crystallization start temperature (Tx) which is 550° C. or less, a glass transition temperature (Tg) which is 520° C. or less, and a supercooled liquid region represented by ΔTx=Tx−Tg, which is 20° C. or more.

Ferrous metal alloys including Fe, Co and optionally Ni with metalloids Si, B and P are provided that are substantially close to the peak in glass forming ability and have a combination of both good glass formability and good ferromagnetic properties. In particular, Fe/Co-based compositions wherein the Co content is between 15 and 30 atomic percent and the metalloid content is between 22 and 24 atomic percent at a well-defined metalloid moiety, have been shown to be capable of forming bulk glassy rods with diameters as large as 4 mm or larger. In addition, incorporating a small content of Ni under 10 atomic percent and additions of Mo, Cr, Nb, Ge, or C at an incidental impurity level of up to 2 atomic percent are not expected to impair the bulk-glass-forming ability of the present alloys.

Described herein is a crucible with a rod fused thereon to optimize pouring of molten material, and method of using the same. The crucible has a body configured for receipt of an amorphous alloy material in a vertical direction, and the rod extends in a horizontal direction from the body. The body of the crucible and the rod are formed from silica or quartz. The rod may be fused to the body of the crucible and provided off a center axis so that pouring molten material is improved when the crucible is rotated.

Embodiments disclosed herein relate to production of amorphous alloys having compositions of iron, chromium, molybdenum, carbon and boron for usage in additive manufacturing, such as in layer-by-layer deposition to produce multi-functional parts. Such parts demonstrate ultra-high strength without sacrificing toughness and also maintain the amorphous structure of the materials during and after manufacturing processes. An Amorphous alloy composition has a formula Fe.sub.100-(a+b+c+d)Cr.sub.aMo.sub.bC.sub.cB.sub.d, wherein a, b, c and d represent an atomic percentage, wherein: a is in the range of 10 at. % to 35 at. %; b is in the range of 10 at. % to 20 at. %; c is in the range of 2 at. % to 5 at. %; and d is in the range of 0.5% at. % to 3.5 at. %.

Exemplary embodiments described herein relate to methods and apparatus for forming a coating layer at least partially on surface of a BMG article formed of bulk solidifying amorphous alloys. In embodiments, the coating layer may be formed in situ during formation of a BMG article and/or post formation of a BMG article. The coating layer may provide the BMG article with surface hardness, wear resistance, surface activity, corrosion resistance, etc.

The embodiments described herein relate to BMG articles with high bulk having all dimensions greater than the critical dimension. Exemplary BMG article can include at least one bulk component and/or one or more fixation elements configured on surface of the bulk component or inserted into the bulk component. Other embodiments relate to methods of making the BMG articles by thermo-plastic-formation of BMG alloy materials.