A Sn-plated steel sheet including a base plated steel sheet having a steel sheet, a Sn-plated layer on at least one surface of the steel sheet, and a film layer containing a zirconium oxide and a tin oxide. An adhesion amount of Sn per surface of the Sn-plated steel sheet is 0.1 g/m.sup.2 or more and 15 g/m.sup.2 or less, an amount of the zirconium oxide in the film layer is in a range of 1 mg/m.sup.2 or more and 30 mg/m.sup.2 or less in terms of an amount of metal Zr, a peak position of a binding energy of Sn3d.sub.5/2 of the tin oxide is 1.4 eV or more and less than 1.6 eV from a peak position of a binding energy of metal Sn, and a quantity of electricity required for reduction of the tin oxide is more than 5.0 mC/cm.sup.2 and 20 mC/cm.sup.2 or less.

This disclosure relates to use of a conversion coating for reduction or prevention of hydrogen sulfide production in cans holding hydrogen sulfide producing liquids, such as wine. This disclosure also relates to metal cans comprising a conversion coating layer deposited on at least a portion of the inside surface of the metal can, a film-forming layer deposited on such conversion coating layer, and a hydrogen sulfide producing liquid deposited inside the metal can.

Described herein is an aqueous, chromium-free composition for a pretreatment of aluminum surfaces, which includes at least one water-soluble phosphorus compound, at least one water-soluble zirconium compound, at least one water-soluble titanium compound, and at least one water-soluble molybdenum compound, a phosphorus compound content being in a range from 15 to 50 mg/l (calculated as phosphorus), a zirconium compound content being in a range from 400 to 600 mg/l (calculated as metal), a titanium compound content being in a range from 85 to 400 mg/l (calculated as metal), and a molybdenum compound content being in a range from 40 to 150 mg/l (calculated as metal). Also described herein are a corresponding method and a correspondingly pretreated component or strip.

A steel sheet for a fuel tank includes: a Zn—Ni alloy plated layer which is placed on one surface or each of both surfaces of a base metal and formed on at least one surface; and an inorganic chromate-free chemical conversion coating film which is placed over the Zn—Ni alloy plated layer. The Zn—Ni alloy plated layer has a crack starting from an interface between the Zn—Ni alloy plated layer and the inorganic chromate-free chemical conversion coating film and reaching an interface between the Zn—Ni alloy plated layer and the steel sheet, and a water contact angle on a surface of the inorganic chromate-free chemical conversion coating film is more than or equal to 50 degrees.

A chemical conversion-treated steel pipe has a chemical conversion treatment film on a plated layer on a steel sheet. The plated layer is configured from a zinc alloy comprising 0.05-60 mass % aluminum and 0.1-10.0 mass % magnesium. The chemical conversion treatment film contains a fluorine resin, a base resin, metal flakes and a chemical conversion treatment component. The base resin is one or more selected from a group consisting of polyurethane, polyester, acrylic resins, epoxy resins and polyolefin. The content of fluorine resin with respect to the total amount of fluorine resin and base resin is at least 3.0 mass % calculated as fluorine atoms. The content of the base resin with respect to 100 parts by mass of the fluorine resin is at least 10 parts by mass. The content of metal flakes in the chemical conversion treatment film is greater than 20 mass % up to and including 60 mass %.

The invention relates to a process for coating metal surfaces with an aqueous composition in the form of a solution or in the form of a dispersion, the composition comprising at least one phosphate, at least 3 g/l of at least one titanium or/and zirconium compound and at least one complexing agent, and also to corresponding aqueous compositions. The coatings prepared thereby have very good bare corrosion protection in the NSS salt spray test and in the condensation-water/constant-climate test

Disclosed are pretreatment compositions and associated methods for treating metal substrates with pretreatment compositions, including ferrous substrates, such as cold rolled steel and electrogalvanized steel. The pretreatment composition includes: (a) a group IIIB and/or IVB metal; (b) free fluorine; (c) a source of aluminum ions; and (d) water. The methods include contacting the metal substrates with the pretreatment composition.

A manufacturing method for steel sheets for containers produces steel sheets with excellent film adhesion qualities. This steel sheet for containers has, on a steel sheet, a chemical conversion coating with a metal Zr content of 1-100 mg/m.sup.2, a P content of 0.1-50 mg/m.sup.2, and an F content of no more than 0.1 mg/m.sup.2, upon which is formed a phenolic resin layer with a C content of 0.1-50 mg/m.sup.2. Moreover, the manufacturing method for steel sheets for containers is a method for obtaining the steel sheet for containers wherein the chemical conversion coating is formed on the steel sheet by subjecting the steel sheet to immersion in or electrolytic treatment with a treatment solution containing Zr ions, phosphoric acid ions, and F ions; and subsequently, the steel sheet upon which the chemical conversion coating has been formed is immersed in, or undergoes topical application of, an aqueous solution containing phenolic resin, then dried.

The invention relates to the use of an acidic aqueous composition for pretreating cans, wherein an inorganic-organic conversion layer is formed in the course of the pretreatment, said conversion layer, as such, offering an excellent adhesive base for wax which improves sliding of the formed can and for the subsequent coating. The invention relates to a wet-chemical pretreatment method in which a can cylinder is first contacted with an acidic aqueous composition that contains water-soluble inorganic compounds of Zr, Ti, Si, Hf or Ce, and water-soluble polymers comprising carboxyl groups or hydroxyl groups; and subsequently is contacted with an aqueous wax dispersion. The invention further relates to an acidic aqueous composition suitable for the pretreatment method comprising water-soluble polymers selected from condensation products of glycoluril and aldehydes. The invention further relates to a method for producing can cylinders, said method including the pretreatment according to the invention.

A method of producing a hot-dip Zn alloy-plated steel sheet includes: dipping a base steel sheet in a hot-dip Zn alloy plating bath to form a hot-dip Zn alloy plating layer on a surface of the base steel sheet; and contacting an aqueous solution containing a water-soluble corrosion inhibitor with a surface of the hot-dip Zn alloy plating layer to cool the base steel sheet and the hot-dip Zn alloy plating layer having a raised temperature through formation of the hot-dip Zn alloy plating layer. A temperature of the surface of the hot-dip Zn alloy plating layer when the aqueous solution is to be contacted with the surface of the hot-dip Zn alloy plating layer is equal to or more than 100° C. and equal to or less than a solidifying point of the plating layer. The aqueous solution containing the water-soluble corrosion inhibitor satisfies the Equation [{(Z.sub.0−Z.sub.1)/Z.sub.0}100≧201.