A steel sheet for a fuel tank according to the present invention includes: a Zn—Ni alloy plated layer placed on one surface or each of both surfaces of a base metal; and a chromate-free chemical conversion coating film which is placed over the Zn—Ni alloy plated layer. The Zn—Ni alloy plated layer has a crack starting from an interface with the chromate-free chemical conversion coating film and reaching an interface with the steel sheet, the chromate-free chemical conversion coating film consists of an organosilicon compound consisting of a condensation polymer of a silane coupling agent, a phosphoric acid compound and/or a phosphonic acid compound, a vanadium compound, and a titanium compound and/or a zirconium compound, and a concentration of a total of amounts in terms of metal, per surface, of the phosphoric acid compound and/or the phosphonic acid compound+the vanadium compound+the titanium compound and/or the zirconium compound, is 5 mass % to 20 mass %.

A steel sheet for a fuel tank according to the present invention includes: a Zn—Ni alloy plated layer placed on one surface or each of both surfaces of a base metal; and a chromate-free chemical conversion coating film which is placed over the Zn—Ni alloy plated layer. The Zn—Ni alloy plated layer has a crack starting from an interface with the chromate-free chemical conversion coating film and reaching an interface with the steel sheet, the chromate-free chemical conversion coating film consists of an organosilicon compound consisting of a condensation polymer of a silane coupling agent, a phosphoric acid compound and/or a phosphonic acid compound, a vanadium compound, and a titanium compound and/or a zirconium compound, and a concentration of a total of amounts in terms of metal, per surface, of the phosphoric acid compound and/or the phosphonic acid compound+the vanadium compound+the titanium compound and/or the zirconium compound, is 5 mass % to 20 mass %.

Provided is a solution composition for steel sheet surface treatment, comprising 30 wt % to 60 wt % of a trivalent chromium compound containing chromium phosphate (A) and chromium nitrate (B); 0.2 wt % to 0.4 wt % of a rust-inhibiting and corrosion-resisting agent; 0.1 wt % to 0.3 wt % of a molybdenum-based compound; 5 wt % to 10 wt % of a water-soluble cationic urethane resin; 0.5 wt % to 2.0 wt % of a silane coupling agent; and 27.3 wt % to 64.2 wt % of water, a zinc-based plated steel sheet surface-treated with the same, and a manufacturing method therefor, the zinc-based plated steel sheet surface-treated with the solution composition for steel sheet surface treatment containing trivalent chromium may have an excellent effect on corrosion resistance, blackening resistance, fingerprint resistance, oil resistance, and alkali resistance.

Provided is a solution composition for steel sheet surface treatment, comprising 30 wt % to 60 wt % of a trivalent chromium compound containing chromium phosphate (A) and chromium nitrate (B); 0.2 wt % to 0.4 wt % of a rust-inhibiting and corrosion-resisting agent; 0.1 wt % to 0.3 wt % of a molybdenum-based compound; 5 wt % to 10 wt % of a water-soluble cationic urethane resin; 0.5 wt % to 2.0 wt % of a silane coupling agent; and 27.3 wt % to 64.2 wt % of water, a zinc-based plated steel sheet surface-treated with the same, and a manufacturing method therefor, the zinc-based plated steel sheet surface-treated with the solution composition for steel sheet surface treatment containing trivalent chromium may have an excellent effect on corrosion resistance, blackening resistance, fingerprint resistance, oil resistance, and alkali resistance.

A surface treatment solution composition for forming an inorganic film, comprising: 10 to 30% by weight of a trivalent chromium compound containing chromium phosphate (A) and chromium nitrate (B) and satisfying a content ratio A/(A+B) of 0.3 to 0.6; 5 to 50% by weight of a silane compound; 0.2 to 3% by weight of a vanadium-based rust-inhibiting and corrosion-resisting agent; 0.5 to 5% by weight of a cobalt-based rust-inhibiting and corrosion-resisting agent; and 12 to 84.3% by weight of water, an alloyed hot-dip galvanized steel sheet surface-treated using the composition, and a method for manufacturing the alloyed hot-dip galvanized steel sheet, are provided, and the surface treatment solution composition containing the trivalent chromium compound has an excellent effect on corrosion resistance, blackening resistance, fuel resistance, weldability, and alkali resistance.

A surface treatment solution composition for forming an inorganic film, comprising: 10 to 30% by weight of a trivalent chromium compound containing chromium phosphate (A) and chromium nitrate (B) and satisfying a content ratio A/(A+B) of 0.3 to 0.6; 5 to 50% by weight of a silane compound; 0.2 to 3% by weight of a vanadium-based rust-inhibiting and corrosion-resisting agent; 0.5 to 5% by weight of a cobalt-based rust-inhibiting and corrosion-resisting agent; and 12 to 84.3% by weight of water, an alloyed hot-dip galvanized steel sheet surface-treated using the composition, and a method for manufacturing the alloyed hot-dip galvanized steel sheet, are provided, and the surface treatment solution composition containing the trivalent chromium compound has an excellent effect on corrosion resistance, blackening resistance, fuel resistance, weldability, and alkali resistance.

This disclosure relates to use of a conversion coating for reduction or prevention of hydrogen sulfide production in cans holding hydrogen sulfide producing liquids, such as wine. This disclosure also relates to metal cans comprising a conversion coating layer deposited on at least a portion of the inside surface of the metal can, a film-forming layer deposited on such conversion coating layer, and a hydrogen sulfide producing liquid deposited inside the metal can.

A steel sheet has a hot-dip Zn—Al—Mg-based coating film, the coating film containing 1 mass % to 22 mass % of Al and 0.1 mass % to 10 mass % of Mg on a surface of the steel sheet, in which an X-ray diffraction peak intensity ratio of a Mg—Zn compound phase in the coating film, that is, MgZn.sub.2/Mg.sub.2Zn.sub.11, is 0.2 or less.

A steel sheet has a hot-dip Zn—Al—Mg-based coating film, the coating film containing 1 mass % to 22 mass % of Al and 0.1 mass % to 10 mass % of Mg on a surface of the steel sheet, in which an X-ray diffraction peak intensity ratio of a Mg—Zn compound phase in the coating film, that is, MgZn.sub.2/Mg.sub.2Zn.sub.11, is 0.2 or less.

Provided is a surface treated steel sheet for a fuel tank, the surface treated steel sheet including: a Zn plated layer or a Zn—Ni alloy plated layer which is formed on at least a surface of the steel sheet to be an inner surface of the fuel tank; and a chromate-free chemical conversion coating layer containing a water-and-oil repellent, the chromate-free chemical conversion coating layer being placed over the Zn plated layer or the Zn—Ni alloy plated layer on the surface to be the inner surface of the fuel tank. A water contact angle on a surface of the chromate-free chemical conversion coating layer is more than or equal to 70 degrees and an n-hexadecane contact angle on the surface of the chromate-free chemical conversion coating layer is more than or equal to 30 degrees and less than or equal to 70 degrees.