A method for producing a chemically treated alloy material is provided that suppresses a decrease in chemical treatability even in a case where chemical treatment is repeatedly performed. The method for producing a chemically treated alloy material of the present disclosure includes a chemical treatment step and a treatment solution regeneration step. In the chemical treatment step, an alloy material (6) is immersed in an oxalate treatment solution (4) containing oxalate ions and fluorine ions to perform a chemical treatment. In the treatment solution regeneration step, light is radiated to the oxalate treatment solution (4) during the chemical treatment and/or the oxalate treatment solution (4) after the chemical treatment.

A method for producing a chemically treated alloy material is provided that suppresses a decrease in chemical treatability even in a case where chemical treatment is repeatedly performed. The method for producing a chemically treated alloy material of the present disclosure includes a chemical treatment step and a treatment solution regeneration step. In the chemical treatment step, an alloy material (6) is immersed in an oxalate treatment solution (4) containing oxalate ions and fluorine ions to perform a chemical treatment. In the treatment solution regeneration step, light is radiated to the oxalate treatment solution (4) during the chemical treatment and/or the oxalate treatment solution (4) after the chemical treatment.

A surface treatment plant for treating objects, in particular vehicle bodies, has a thin film conversion process in which a ceramic thin film is applied to the objects using a process medium, a subsequent rinsing step in which the objects are rinsed with rinsing medium after the thin film conversion process, and a deionization plant which has a cation exchanger and a downstream anion exchanger and is configured for deionizing the process medium and/or the rinsing medium. For economical operation, the deionization plant is preceded by a preconditioning apparatus which is configured for removing complex anions which are formed and/or present in the thin film conversion process from the process medium and/or the rinsing medium. Furthermore, a corresponding preconditioning apparatus and a treatment process are described.

A method for corrosion protection treatment, comprising contacting a series of components having metallic surfaces of iron and/or zinc with a passivating aqueous pretreatment solution, present in a system tank, containing compounds of the elements zirconium and/or titanium, and contacting with a source of fluoride ions wherein a portion of the pretreatment solution is discarded and replaced with a volume portion of one or more such replenishment solutions which in total are at least of equal size, by metered addition to the system tank of the pretreatment and wherein discarding as a function of the molar ratio of the elements fluorine to zirconium and/or titanium must not drop below a predefined value, the metered addition of replenishment solution takes place such that maintaining the concentration of the elements zirconium and/or titanium in the passivating aqueous pretreatment solution in the form of water-soluble compounds is ensured.

A method for corrosion protection treatment, comprising contacting a series of components having metallic surfaces of iron and/or zinc with a passivating aqueous pretreatment solution, present in a system tank, containing compounds of the elements zirconium and/or titanium, and contacting with a source of fluoride ions wherein a portion of the pretreatment solution is discarded and replaced with a volume portion of one or more such replenishment solutions which in total are at least of equal size, by metered addition to the system tank of the pretreatment and wherein discarding as a function of the molar ratio of the elements fluorine to zirconium and/or titanium must not drop below a predefined value, the metered addition of replenishment solution takes place such that maintaining the concentration of the elements zirconium and/or titanium in the passivating aqueous pretreatment solution in the form of water-soluble compounds is ensured.

The present invention relates to a method for the serial surface treatment of metal components that have zinc surfaces, wherein the method comprises an alkaline pretreatment, and a method for the selective removal of zinc ions from an alkaline bath solution for the serial surface treatment of metal surfaces that have zinc surfaces. According to the invention, in order to perform each method, part of the alkaline aqueous bath solution is brought in contact with an ion exchange resin that bears functional groups selected from OPO.sub.3X.sub.2/n and/or PO.sub.3X.sub.2/n, wherein X is either a hydrogen atom or an alkali metal and/or alkaline-earth metal atom to be exchanged having the particular valency n.

The present invention relates to a method for the serial surface treatment of metal components that have zinc surfaces, wherein the method comprises an alkaline pretreatment, and a method for the selective removal of zinc ions from an alkaline bath solution for the serial surface treatment of metal surfaces that have zinc surfaces. According to the invention, in order to perform each method, part of the alkaline aqueous bath solution is brought in contact with an ion exchange resin that bears functional groups selected from OPO.sub.3X.sub.2/n and/or PO.sub.3X.sub.2/n, wherein X is either a hydrogen atom or an alkali metal and/or alkaline-earth metal atom to be exchanged having the particular valency n.

Disclosed is a method of making a treatment composition. A lithium cation and carbon dioxide are combined in an aqueous medium to form the treatment composition comprising lithium carbonate in situ. Also disclosed is a system and method for maintaining a treatment bath formed from a treatment composition comprising lithium carbonate. Carbon dioxide and/or a lithium salt are supplied to the bath in an amount sufficient to maintain the pH of the treatment bath at 9.5 to 12.5, lithium in an amount of 5 ppm to 5,500 ppm (calculated as lithium cation) and carbonate in an amount of 15 ppm to 25,000 ppm (calculated as carbonate) based on total weight of the treatment bath. Substrates treated with the composition, system and method also are disclosed.

Disclosed is a method of making a treatment composition. A lithium cation and carbon dioxide are combined in an aqueous medium to form the treatment composition comprising lithium carbonate in situ. Also disclosed is a system and method for maintaining a treatment bath formed from a treatment composition comprising lithium carbonate. Carbon dioxide and/or a lithium salt are supplied to the bath in an amount sufficient to maintain the pH of the treatment bath at 9.5 to 12.5, lithium in an amount of 5 ppm to 5,500 ppm (calculated as lithium cation) and carbonate in an amount of 15 ppm to 25,000 ppm (calculated as carbonate) based on total weight of the treatment bath. Substrates treated with the composition, system and method also are disclosed.

The purpose of the present invention is to provide a method for replenishing an aluminum metal chemical conversion bath, the method being capable of maintaining the corrosion resistance and coating film adhesiveness of the chemical conversion coating formed even if the aluminum metal chemical conversion bath is used continuously. Provided is a method for replenishing an aluminum metal chemical conversion bath with a replenishing agent, wherein the replenishing agent comprises a zirconium salt and/or a titanium salt and an effective fluoride, and the replenishing agent is supplied so that the ratio F/Al of the fluorine ion concentration (mg/L) with respect to the aluminum ion concentration (mg/L) in the aluminum metal chemical conversion bath is 1.8-4.5.