Disclosed is a system for maintaining a pretreatment bath containing a pretreatment comprising a Group IVB metal. The system comprises an aqueous reducing agent comprising a metal cation and a latent source of sulfate which, upon reaction with a contaminant in the pretreatment bath, forms a metal sulfate. The contaminant comprises a nitrite source. The metal sulfate salt has a pKsp of 4.5 to 11 at a temperature of 25° C. Also disclosed is a method for maintaining a pretreatment bath containing a pretreatment composition comprising a Group IVB metal. The method comprises supplying the reducing agent to the pretreatment bath in an amount sufficient to reduce a pollution ratio of the pretreatment bath to less than 1:1. Also disclosed are substrates with a pretreatment bath maintained according to the system and method.

A method for corrosion protection treatment, comprising contacting a series of components having metallic surfaces of iron and/or zinc with a passivating aqueous pretreatment solution, present in a system tank, containing compounds of the elements zirconium and/or titanium, and contacting with a source of fluoride ions wherein a portion of the pretreatment solution is discarded and replaced with a volume portion of one or more such replenishment solutions which in total are at least of equal size, by metered addition to the system tank of the pretreatment and wherein discarding as a function of the molar ratio of the elements fluorine to zirconium and/or titanium must not drop below a predefined value, the metered addition of replenishment solution takes place such that maintaining the concentration of the elements zirconium and/or titanium in the passivating aqueous pretreatment solution in the form of water-soluble compounds is ensured.

A method for corrosion protection treatment, comprising contacting a series of components having metallic surfaces of iron and/or zinc with a passivating aqueous pretreatment solution, present in a system tank, containing compounds of the elements zirconium and/or titanium, and contacting with a source of fluoride ions wherein a portion of the pretreatment solution is discarded and replaced with a volume portion of one or more such replenishment solutions which in total are at least of equal size, by metered addition to the system tank of the pretreatment and wherein discarding as a function of the molar ratio of the elements fluorine to zirconium and/or titanium must not drop below a predefined value, the metered addition of replenishment solution takes place such that maintaining the concentration of the elements zirconium and/or titanium in the passivating aqueous pretreatment solution in the form of water-soluble compounds is ensured.

The present invention relates to a method for the serial surface treatment of metal components that have zinc surfaces, wherein the method comprises an alkaline pretreatment, and a method for the selective removal of zinc ions from an alkaline bath solution for the serial surface treatment of metal surfaces that have zinc surfaces. According to the invention, in order to perform each method, part of the alkaline aqueous bath solution is brought in contact with an ion exchange resin that bears functional groups selected from —OPO.sub.3X.sub.2/n and/or —PO.sub.3X.sub.2/n, wherein X is either a hydrogen atom or an alkali metal and/or alkaline-earth metal atom to be exchanged having the particular valency n.

The present disclosure provides an electrochemical deposition apparatus set. The electrochemical deposition apparatus set includes: an electrochemical deposition device configured to form an electrochemical deposition film layer on an area to be coated of a substrate; an antioxidation treatment device located on a side of the electrochemical deposition device and configured to performing antioxidation treatment on the substrate formed with the electrochemical deposition film layer; a transmission device configured to carry the substrate and drive the substrate to move at least from the electrochemical deposition device to the antioxidation treatment device.

The invention relates to a method for operating a treatment system, by means of which an optimized workpiece treatment is facilitated. The method for operating a treatment system comprises the following steps: guiding workpieces through a treatment basin filled with a treatment medium in order to treat the workpieces; rinsing the workpieces with a rinsing medium while and/or after the workpieces are removed from the treatment basin; and producing the rinsing medium from the treatment medium, wherein the rinsing medium is produced using a preparation device preferably by filtering, in particular nano-filtering, the treatment medium.

An acidic treatment liquid processing apparatus includes: a tank having an interior space; a diaphragm permeable to a metal cation and separating the interior space of the tank into a first chamber and a second chamber; a first electrode disposed in the first chamber; a second electrode disposed in the second chamber; a power supply configured to apply a voltage while using the first electrode as an anode and the second electrode as a cathode; a first liquid passing part configured to pass an acidic treatment liquid containing a dichromate ion and a metal cation into the first chamber; and a second liquid passing part configured to pass an acid aqueous solution into the second chamber.

Disclosed is a system for maintaining a pretreatment bath containing a pretreatment comprising a Group IVB metal. The system comprises an aqueous reducing agent comprising a metal cation and a latent source of sulfate which, upon reaction with a contaminant in the pretreatment bath, forms a metal sulfate. The contaminant comprises a nitrite source. The metal sulfate salt has a pKsp of 4.5 to 11 at a temperature of 25 C. Also disclosed is a method for maintaining a pretreatment bath containing a pretreatment composition comprising a Group IVB metal. The method comprises supplying the reducing agent to the pretreatment bath in an amount sufficient to reduce a pollution ratio of the pretreatment bath to less than 1:1. Also disclosed are substrates with a pretreatment bath maintained according to the system and method.

A method for producing a chemically treated alloy material is provided that suppresses a decrease in chemical treatability even in a case where chemical treatment is repeatedly performed. The method for producing a chemically treated alloy material of the present disclosure includes a chemical treatment step and a treatment solution regeneration step. In the chemical treatment step, an alloy material (6) is immersed in an oxalate treatment solution (4) containing oxalate ions and fluorine ions to perform a chemical treatment. In the treatment solution regeneration step, light is radiated to the oxalate treatment solution (4) during the chemical treatment and/or the oxalate treatment solution (4) after the chemical treatment.

A method for producing a chemically treated alloy material is provided that suppresses a decrease in chemical treatability even in a case where chemical treatment is repeatedly performed. The method for producing a chemically treated alloy material of the present disclosure includes a chemical treatment step and a treatment solution regeneration step. In the chemical treatment step, an alloy material (6) is immersed in an oxalate treatment solution (4) containing oxalate ions and fluorine ions to perform a chemical treatment. In the treatment solution regeneration step, light is radiated to the oxalate treatment solution (4) during the chemical treatment and/or the oxalate treatment solution (4) after the chemical treatment.