A corrosion inhibition package for use with an aqueous acid composition, said package comprising: a terpene; a cinnamaldehyde or a derivative thereof; at least one amphoteric surfactant; and a solvent. Also disclosed are compositions comprising said corrosion inhibitor package. Preferably, the corrosion inhibition package meets the environmental requirements for classification as yellow according to the Norwegian North Sea offshore drilling regulatory requirements.

A method of inhibiting corrosion of a metal surface may include contacting the metal surface with a corrosion inhibitor compound that includes a substituted carboxamide.

Disclosed herein is a novel class of multiple charged cationic or anionic compounds that are derived from an aza-Michael Addition reaction between a polyamine (Michael donor) and an activated olefin (Michael acceptor), methods of making the same, and use thereof. Also disclosed herein are the methods of using multiple charged cationic or anionic compounds disclosed herein in a reverse emulsion breaker composition to break reverse emulsion commonly found in a produced fluid in oil and gas operations. The disclosed REB methods or compositions are found to be more effective than those methods or compositions including commonly used for oil/solid and water separation.

Disclosed are oleyl propylenediamine-based compounds used in compositions and methods for inhibiting corrosion. The method comprises introducing into a fluid source a composition comprising one or more oleyl propylenediamine-based compounds comprising Formula I:

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wherein Y.sub.1, Y.sub.2, and Y.sub.3 independently are hydrogen or a substituent of Formula (II):

##STR00002##

wherein V is —O— or —NH—, W is optionally present and is a linear or branched C.sub.1-10 aliphatic group, X is —H, —NZ.sub.3.sup.+, —COOH, —SO.sub.3H, —OSO.sub.3H.sub.2, —PO.sub.3H, —OPO.sub.3H.sub.2, or a salt thereof, each Z independently is hydrogen or a linear or branched C.sub.1-20 aliphatic group optionally interrupted or substituted with one or more oxygen atoms, and R is hydrogen or methyl, provided that at least one of Y.sub.1, Y.sub.2, or Y.sub.3 is a substituent of Formula (II).

Graphene quantum dots are functionalized by covalently bonding a corrosion inhibitor molecule thereto. In a useful method, a corrosion inhibitor compound is blended with a graphene quantum dot-tagged corrosion inhibitor compound, and the blend is applied to a metal surface, such as the interior of a carbon steel pipe. The blend inhibits corrosion arising from contact with produced water generated by hydrocarbon recovery from one or more subterranean reservoirs. The produced water having the blend dispersed therein is irradiated with a source of light having a selected first range of wavelengths, and the luminescent emission of the graphene quantum dot-tagged corrosion inhibitor is measured at a selected second range of wavelengths, thereby providing for real-time measurement of corrosion inhibitor concentration within the pipe.

A composition useful as corrosion inhibitor formulation for application in heavy brine systems, comprising at least one amidoamine; at least one sulfur synergist; at least one phosphate ester. In a preferred embodiment, the composition comprises additionally formulation bonding surfactant; and/or at least one solvent system.

Imidazoline functionalized oxidized fatty substance emulsifiers are made by obtaining a fatty substance composition; performing an oxidative oligomerization of the fatty substance composition to produce an oxidized fatty substance composition comprising from about 10 to about 75% by weight of oligomeric fatty acid components based on the total weight of fatty acid containing components in the composition; reacting the oxidized fatty substance composition with a polyamine comprising at least one ethylene diamine functional group with at least three hydrogens attached to the two nitrogens to form an aminoethylamido functionalized oxidized fatty substance composition; and forming an imidazoline functionalized oxidized fatty substance emulsifier from the amino-ethylamido functionalized oxidized fatty substance composition. Such compositions are particularly useful in asphalt applications and corrosion inhibition.

Disclosed are methods for inhibiting the corrosion of metal containments such as carbon-steel pipes used in oil recovery processes, the methods comprising adding urine and/or compositions comprising urine to water sources to form corrosion inhibitor compositions, and contacting metal containments with the corrosion inhibitor compositions. The water sources are for example aqueous solutions that are corrosive to metal containments such as carbon-steel pipes. Compositions comprising urine that provide reduced corrosion or corrosion inhibition are also described. Metal containment assemblages comprising corrosion inhibitor compositions and a metal containment are also described.

A corrosion inhibiting composition is provided which comprises a salt of a fatty acid-amine condensate and an aromatic solvent. The composition can be used in reducing, inhibiting or preventing corrosion of a metal surface used in recovery, transportation, refining or storage of a hydrocarbon fluid containing elemental sulfur or polysulfide.

The invention relates to a composition comprising a) at least one N-methyl-N-acylglucamine of formula (I), wherein R.sup.1 represents a linear or branched, saturated or unsaturated hydrocarbon chain with 7 to 21 carbon atoms, one or more organic acids of formula (II) and/or the salts thereof, R.sup.2—COOM, wherein R.sup.2 represents a linear or branched alkyl group or a linear or branched mono- or poly-unsaturated alkenyl group with 5 to 29 carbon atoms, and M represents hydrogen or one or more cations, wherein the cations are present in charge-equalizing amounts, and c) one or more alkanolamines of formula (III), wherein NR.sup.1R.sup.2R.sup.3R.sup.1, R.sup.2 and R.sup.3 represent hydrogen, a linear or branched alkyl group with 1 to 4 carbon atoms, a cycloalkyl group with 5 to 7 carbon atoms, a linear or branched hydroxyalkyl group with 2 to 5 carbon atoms and 1 or 2 hydroxy groups or a hydroxyether group with 2 to 6 carbon atoms, with the provision that at least one of the groups is a hydroxyalkyl group or a hydroxyether group.

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