A composition for application to a substrate comprising a carrier, a permanganate ion source, and a corrosion inhibitor comprising a rare earth ion, an alkali metal ion, an alkaline earth metal ion, and/or a transition metal ion is disclosed. A substrate or article including the composition for application to a substrate, and a method of treating a substrate comprising applying the composition to a substrate to form a permanganate treated surface of the substrate and applying a lithium containing composition on the permanganate treated surface are also disclosed.

A manufacturing method of an antibacterial surface treated copper material includes: etching a metal base material including copper; primary heat-treating the metal base material; coating the metal base material with a composition for a coating; and secondary heat-treating the metal base material. The composition for the coating includes an acryl resin at 40 wt % to 50 wt % and CuO at 1 wt % to 5 wt % for an entire weight of the composition for the coating.

Disclosed herein is a phosphonate-free, aqueous pickling composition having a pH value at 55° C. in the range from 5 to 9, and containing at least one copolymer, which is water-soluble or water-dispersible and selected from the group consisting of polyvinylpyrrolidones; the content of water being in the range from 95.0 wt.-% to 99.9 wt.-% based on the total weight of the composition. Further disclosed herein is a concentrate to produce such compositions, a pickling method for pickling metallic substrates making use of the compositions, a coating method for coating metallic substrates including the pickling method and a method of using the compositions for pickling metallic substrates.

Disclosed herein is a phosphonate-free, aqueous pickling composition having a pH value at 55° C. in the range from 5 to 9, and containing at least one copolymer, which is water-soluble or water-dispersible and selected from the group consisting of polyvinylpyrrolidones; the content of water being in the range from 95.0 wt.-% to 99.9 wt.-% based on the total weight of the composition. Further disclosed herein is a concentrate to produce such compositions, a pickling method for pickling metallic substrates making use of the compositions, a coating method for coating metallic substrates including the pickling method and a method of using the compositions for pickling metallic substrates.

A manufacturing method of an antibacterial surface treated copper material includes: etching a metal base material including copper; primary heat-treating the metal base material; coating the metal base material with a composition for a coating; and secondary heat-treating the metal base material. The composition for the coating includes an acryl resin at 40 wt % to 50 wt % and CuO at 1 wt % to 5 wt % for an entire weight of the composition for the coating.

A new and improved method for producing electrical steel sheet enabling production of electrical steel sheet excellent in magnetic characteristics and coating film adhesion, the method for producing electrical steel sheet containing a process of bringing an electrical steel sheet containing, by mass %, C: more than 0% and 0.10% or less, Si: 2.5% or more and 4.5% or less, Mn: 0.01% or more and 5.0% or less, a total of one or more of S, Se, and Te: more than 0% and 0.050% or less, acid soluble Al: more than 0% and 5.0% or less, N: more than 0% and 0.015% or less, and P: more than 0% and 1.0% or less and having a balance of Fe and impurities into contact with a solution, the solution containing one or more elements from among Cu, Hg, Ag, Pb, Cd, Co, Zn, and Ni, a total of concentrations of the elements being 0.00001% or more and 1.0000% or less.

Disclosed herein is an aqueous composition having a pH value at 55° C. in the range from 5 to 9, containing at least one different amino organophosphonic acid derivatives of formula (I)

##STR00001##

where residues R independently of each other are CH.sub.2—PO(OR″).sub.2, residues R′ independently of each other are alkylene residues with 2 to 4 carbon atoms, residues R″ independently of each other are H, Na, K, Li or NH.sub.4; and n is an integer from 0 to 4; and at least one copolymer, which is water-soluble or water-dispersible Further disclosed herein are a concentrate to produce such compositions, a pickling method for pickling metallic substrates making use of the compositions, a coating method for coating metallic substrates including the pickling method and a method of using the compositions for pickling metallic substrates.

Disclosed herein is an aqueous composition having a pH value at 55° C. in the range from 5 to 9, containing at least one different amino organophosphonic acid derivatives of formula (I)

##STR00001##

where residues R independently of each other are CH.sub.2—PO(OR″).sub.2, residues R′ independently of each other are alkylene residues with 2 to 4 carbon atoms, residues R″ independently of each other are H, Na, K, Li or NH.sub.4; and n is an integer from 0 to 4; and at least one copolymer, which is water-soluble or water-dispersible Further disclosed herein are a concentrate to produce such compositions, a pickling method for pickling metallic substrates making use of the compositions, a coating method for coating metallic substrates including the pickling method and a method of using the compositions for pickling metallic substrates.

A composition for application to a substrate comprising a carrier, a permanganate ion source, and a corrosion inhibitor comprising a rare earth ion, an alkali metal ion, an alkaline earth metal ion, and/or a transition metal ion is disclosed. A substrate or article including the composition for application to a substrate, and a method of treating a substrate comprising applying the composition to a substrate to form a permanganate treated surface of the substrate, and applying a lithium containing composition on the permanganate treated surface are also disclosed.

A composition for application to a substrate comprising a carrier, a permanganate ion source, and a corrosion inhibitor comprising a rare earth ion, an alkali metal ion, an alkaline earth metal ion, and/or a transition metal ion is disclosed. A substrate or article including the composition for application to a substrate, and a method of treating a substrate comprising applying the composition to a substrate to form a permanganate treated surface of the substrate, and applying a lithium containing composition on the permanganate treated surface are also disclosed.