The present invention refers to an electrolytic treatment device having an anodic compartment comprising a non-chromium (VI) etching solution to be treated and immersed therein an anode. The anodic compartment is separated by a membrane from a cathodic compartment comprising a cathodic solution comprising an inorganic acid, wherein the anode and the cathode are used comprising or consisting of a ternary or higher Pb alloy with Sn and at least one further metal selected from the group consisting of Sb, Ag, Co, Bi and combinations thereof. Moreover, a method for etching plastic parts is provided as well.

In various aspects and embodiments the invention provides a method for preparing a metal periodate by anodic oxidation of a metal iodide in an electrolysis cell comprising one or more anodes and one or more cathodes, characterised in that the one or more anodes are carbon-comprising electrodes. In certain embodiments the method is characterised in that the one or more anodes comprise a diamond layer doped with one or more IUPAC group 13, 15 or 16 elements of the periodic table.

In various aspects and embodiments the invention provides a method for preparing a metal periodate by anodic oxidation of a metal iodide in an electrolysis cell comprising one or more anodes and one or more cathodes, characterised in that the one or more anodes are carbon-comprising electrodes. In certain embodiments the method is characterised in that the one or more anodes comprise a diamond layer doped with one or more IUPAC group 13, 15 or 16 elements of the periodic table.

The present invention refers to an electrolytic treatment device having an anodic compartment comprising a non-chromium (VI) etching solution to be treated and immersed therein an anode. The anodic compartment is separated by a membrane from a cathodic compartment comprising a cathodic solution comprising an inorganic acid, wherein the anode and the cathode are used comprising or consisting of a ternary or higher Pb alloy with Sn and at least one further metal selected from the group consisting of Sb, Ag, Co, Bi and combinations thereof. Moreover, a method for etching plastic parts is provided as well.

Provided is an oral care product comprising an effective amount of a soluble orally acceptable sulfate, e.g., sodium or potassium bisulfate, in a buffered, electrically conductive medium, which product is useful in a method for in situ production of per sulfate (S.sub.2O.sub.8.sup.2−), and methods of making and using the same, for example for whitening the teeth.

A process for preparing or regenerating peroxodisulfuric acid and its salts by electrolysis of an aqueous solution containing sulfuric acid and/or metal sulfates at diamond-coated electrodes without addition of promoters is described, with bipolar silicon electrodes which are coated with diamond on one side and whose uncoated silicon rear side serves as cathode being used.

Described herein are three methods for making halogenated fluorinated ether-containing compounds using a fluorinated olefin or hexafluoropropylene oxide.

Systems and methods for the recovery of noble metal from noble-metal-containing material are generally described. Certain embodiments related to systems and methods in which an electric current is transported between an electrode and the noble metal of a noble-metal-containing material to dissolve at least a portion of the noble metal from the noble-metal-containing material. The dissolved noble metal can subsequently be precipitated out of solution and recovered, according to certain embodiments. Noble metals can be recovered from any suitable noble-metal-containing material, including plated and/or filled scrap materials and/or other materials.

Systems and methods for the recovery of noble metal from noble-metal-containing material are generally described. Certain embodiments related to systems and methods in which an electric current is transported between an electrode and the noble metal of a noble-metal-containing material to dissolve at least a portion of the noble metal from the noble-metal-containing material. The dissolved noble metal can subsequently be precipitated out of solution and recovered, according to certain embodiments. Noble metals can be recovered from any suitable noble-metal-containing material, including plated and/or filled scrap materials and/or other materials.

A durable composite diamond electrode is disclosed which comprise at least a relatively thicker conductive UNCD (Ultrananocrystalline Diamond) layer, with low deposition cost, on a substrate underlying a relatively thinner conductive MCD (Microcrystalline Diamond) layer. The electrode exhibits long life and superior delamination resistance under extremely stressed electrochemical oxidation conditions. It is hypothesized that this improvement in electrode reliability is due to a combination of stress relief by the composite film with the slightly softer underlying UNCD root layer and the electrochemically durable overlying MCD shield layer, an effective disruption mechanism of the fracture propagation between the compositing layers, and thermal expansion coefficient match between the diamond layers and the substrate. The diamond composite electrode can be applied to any electrochemical application requiring extreme voltages/current densities, extreme reliability or biomedical inertness such as electrochemical systems to generate ozone, hydroxyl radicals, or biomedical electrode applications.