Methods and systems directed to recovery of lithium (e.g., lithium salts) from liquid streams are provided. In some embodiments, methods relate to obtaining lithium (e.g., as a solid lithium salt) by removing at least a portion of liquid from a feed stream to form a concentrated stream with respect to solubilized lithium cations. Liquid removal may include transporting at least a portion of the feed stream to an osmotic unit and/or a humidifier. Some methods include removing impurities (e.g., non-lithium cations) from the concentrated stream (e.g., via precipitation and/or crystallization). In some embodiments, solutions containing solubilized lithium cations and anions are electrochemically-treated such that first solubilized anions are replaced with second, different anions. In some embodiments, solid lithium salt containing at least a portion of the lithium cations and the second anions is obtained (e.g., via precipitation and/or crystallization following concentration of the electrochemically-treated solution in a humidifier).

The invention relates to a method for producing hydrogen, in which, in a non-electrolytic method, a carbonaceous feed material is converted into non-electrolytically produced hydrogen and one or more further non-electrolytically produced products, and furthermore excess steam is provided using the non-electrolytic process. According to the invention at least a part of the excess steam is used at least intermittently to provide feed steam, which is converted by means of steam electrolysis to electrolytic hydrogen and electrolytic oxygen. The present invention also relates to a corresponding plant.

A system and method for producing olefin via dry reforming and olefin synthesis in the same vessel, including providing feed including methane and carbon dioxide to the vessel, converting methane and carbon dioxide in the vessel into syngas (that includes hydrogen and carbon monoxide) via dry reforming in the vessel, and cooling the syngas via a heat exchanger in the vessel. The method includes synthesizing olefin from the syngas in the vessel, wherein the olefin includes ethylene, propylene, or butene, or any combinations thereof.

Disclosed are membrane electrode assemblies having a cathode layer comprising a carbon oxide reduction catalyst that promotes reduction of a carbon oxide; an anode layer comprising a catalyst that promotes oxidation of a water; a polymer electrolyte membrane (PEM) layer disposed between, and in contact with, the cathode layer and the anode layer; and a salt having a concentration of at least about 10 uM in at least a portion of the MEA.

Disclosed are membrane electrode assemblies having a cathode layer comprising a carbon oxide reduction catalyst that promotes reduction of a carbon oxide; an anode layer comprising a catalyst that promotes oxidation of a water; a polymer electrolyte membrane (PEM) layer disposed between, and in contact with, the cathode layer and the anode layer; and a salt having a concentration of at least about 10 uM in at least a portion of the MEA.

An individual solid oxide cell (SOC) constructed of a sandwich configuration including in the following order: an oxygen electrode, a solid oxide electrolyte, a fuel electrode, a fuel manifold, and at least one layer of mesh. In one embodiment, the mesh supports a reforming catalyst resulting in a solid oxide fuel cell (SOFC) having a reformer embedded therein. The reformer-modified SOFC functions internally to steam reform or partially oxidize a gaseous hydrocarbon, e.g. methane, to a gaseous reformate of hydrogen and carbon monoxide, which is converted in the SOC to water, carbon dioxide, or a mixture thereof, and an electrical current. In another embodiment, an electrical insulator is disposed between the fuel manifold and the mesh resulting in a solid oxide electrolysis cell (SOEC), which functions to electrolyze water and/or carbon dioxide.

An individual solid oxide cell (SOC) constructed of a sandwich configuration including in the following order: an oxygen electrode, a solid oxide electrolyte, a fuel electrode, a fuel manifold, and at least one layer of mesh. In one embodiment, the mesh supports a reforming catalyst resulting in a solid oxide fuel cell (SOFC) having a reformer embedded therein. The reformer-modified SOFC functions internally to steam reform or partially oxidize a gaseous hydrocarbon, e.g. methane, to a gaseous reformate of hydrogen and carbon monoxide, which is converted in the SOC to water, carbon dioxide, or a mixture thereof, and an electrical current. In another embodiment, an electrical insulator is disposed between the fuel manifold and the mesh resulting in a solid oxide electrolysis cell (SOEC), which functions to electrolyze water and/or carbon dioxide.

The plant control method includes the following. Calculating a first reference amount to be supplied for an amount of hydrogen to be supplied to a second production device (40). Making a decision on whether or not the amount of remaining hydrogen in a storage device (20) at the beginning of a subject term falls within a reference range.

Integrated plants and associated processes for producing ammonia and sulfuric acid have been developed comprising air separation and water electrolysis subsystems and which make surprisingly efficient use of the products from these subsystems (i.e. oxygen and nitrogen from the former and hydrogen and oxygen from the latter). The invention is particularly suitable for use as part of an integrated fertilizer production plant.

A process for the separation of electrolyte from the carbon in a solid carbon/electrolyte cathode product formed at the cathode during molten carbonate electrolysis. The processes allow for easy separation of the solid carbon product from the electrolyte without any observed detrimental effect on the structure and/or stability of the resulting solid carbon nanomaterial.