In an embodiment, a method comprises adding a methanol feed stream from a source methanol reservoir to a loop; wherein the loop comprises an electrolyzer, a base methanol reservoir, an electrolyzer inlet stream that directs a methanol mixture from the base methanol reservoir to the electrolyzer, and a methanol carbon dioxide stream that directs an unreacted methanol from the electrolyzer to the base methanol reservoir; and maintaining a methanol concentration in the base methanol reservoir through the opening and closing of a purge valve that allows a purge stream to flow from the base methanol reservoir to the source methanol reservoir and through the opening and closing of a feed valve that allows the methanol feed stream to flow from the source methanol reservoir into the loop. A product hydrogen stream can be recovered for use in an engine.

The present disclosure is directed towards flow structures in electrochemical cells for use in high differential pressure operations. The flow structure on the low pressure-side of the cell has a larger surface area than the flow structure on the high-pressure side of the cell at the flow structure—MEA interface. The boundary of the high pressure flow structure is entirely within the boundary of the low pressure flow structure. A seal around the high pressure flow structure is also contained within the boundary of the low pressure flow structure. In such an arrangement, high fluid pressures acting on the electrolyte membrane from the high-pressure side of the cell is fully and continuously balanced by the flow structure on the low pressure-side of the membrane. Use of the low pressure flow structure as a membrane support prevents the rupture or deformation of the membrane under high stresses.

A tube-type ozone generator 1 including an ozone generation unit 30A is provided. The ozone generation unit 30A includes an outer electrode tube 31 and an inner electrode tube 32 provided inside the outer electrode tube with a discharge gap 36 interposed between the outer and inner electrode tubes 31 and 32. The inner electrode tube 32 has a dielectric tube 33 and a cylindrical electrode 34 being in close contact with an inner circumferential surface of the dielectric tube 33. The electrode 34 is removably disposed inside the dielectric tube 33.

Disclosed is an ion exchange membrane electrolytic cell, comprising an anode chamber and a cathode chamber; a gas-liquid separation chamber is arranged in the anode chamber and/or the cathode chamber; the gas-liquid separation chamber is partially located inside the anode chamber and/or the cathode chamber; a first portion of the gas-liquid separation chamber, which is configured to accommodate liquid, is arranged inside the anode chamber and/or the cathode chamber; and a second portion of the gas-liquid separation chamber, which is configured to accommodate gas, is disposed outside of the anode chamber and/or the cathode chamber. The ion exchange membrane electrolytic cell is provided with the gas-liquid separation chamber partially located inside the anode chamber and/or the cathode chamber, thereby improving the yield of the ion exchange membrane electrolytic cell. On the other hand, the products of electrolysis can be drained rapidly.

The present invention concerns a method of retrofitting of a membrane electrolysis cell, wherein a rigid cathode is shaped by plastic deformation of the regions in correspondence of cathodic supports; a pre-shaped conductive elastic element having compressed regions in correspondence of said cathodic supports is overlaid onto said rigid cathode; a flexible planar cathode provided with a catalytic coating is overlaid onto said conductive elastic element. The invention also concerns a correspondingly retrofitted electrolysis cell.

The invention relates to the field of electrochemical production of disinfectants, where a solution of alkaline metals is used as the electrolyte in the anode chamber. The invention offers a new design for electrolyzers, reducing power consumption in the production of disinfectants by known methods. As a result of this invention, power consumed in the production of 1 gram of active chlorine by known methods will be reduced by 20%, and the possibilities for producing disinfectants with active chlorine content 7500 ppm in an electrolyzer without channelling the water into external cooling devices will also expand.

Compositions comprising hydrogenated and dehydrogenated graphite comprising a plurality of flakes. At least one flake in ten has a size in excess of ten square micrometers. For example, the flakes can have an average thickness of 10 atomic layers or less.

A gasket for sealing two mating surfaces of a fuel cell is described. The gasket has a core layer comprising exfoliated vermiculite. The core layer is interposed between a first and second coating layer, the said coating layers each comprising glass, glass-ceramic and/or ceramic material. Methods for producing gaskets according to the invention are also described. A solid oxide cell or a solid oxide cell component comprising one or more of the gaskets; use of the gasket to improve sealing properties in a solid oxide cell; and a method of producing a solid oxide cell or of sealing a solid oxide cell comprising incorporating at least one of the gaskets into the solid oxide cell are also defined.

Techniques for photocatalytic hydrogen generation are provided. In one aspect, a hydrogen producing cell is provided. The hydrogen producing cell includes an anode electrode; a photocatalytic material adjacent to the anode electrode; a solid electrolyte adjacent to a side of the photocatalytic material opposite the anode electrode; and a cathode electrode adjacent to a side of the solid electrolyte opposite the photocatalytic material. A solar hydrogen producing system including at least one solar concentrating assembly having the hydrogen producing cell, and a method for producing hydrogen using the hydrogen producing cell are also provided.

A process is provided for electrochemical reduction, particularly the electrochemical reduction of carbon dioxide to formate. According one embodiment, an electrochemical process includes the electrochemical reduction of carbon dioxide to formate utilizing periodic pulsed anodic polarization, periodic pulsed deep cathodic polarization, or combinations thereof to remove cathodic deposits. Various polarization techniques are disclosed which improve overall Faradaic Efficiency.