Yarns and fabrics that include modacrylic fibers are described herein. A yarn and/or fabric may include modacrylic fibers, meta-aramid fibers, anti-static fibers, and optionally para-aramid fibers. In some embodiments, the modacrylic fibers, meta-aramid fibers, and, if present, para-aramid fibers, may each be fiber dyed, optionally solution-dyed.

Yarns and fabrics that include modacrylic fibers are described herein. A yarn and/or fabric may include modacrylic fibers, meta-aramid fibers, anti-static fibers, and optionally para-aramid fibers. In some embodiments, the modacrylic fibers, meta-aramid fibers, and, if present, para-aramid fibers, may each be fiber dyed, optionally solution-dyed.

A pipe liner comprising a nonwoven felt, and process for making said nonwoven felt, the nonwoven felt consisting essentially of 0 to 85 weight percent polyester staple fibers and 15 to 100 weight percent para-aramid staple fibers, the nonwoven felt having a basis weight of 250 to 600 grams per square meter and a thickness of 2.0 to 5.0 mm; wherein: 20 to 100 weight percent of the total amount of para-aramid staple fibers are re-purposed para-aramid staple fibers, 0 to 80 weight percent of the total amount of para-aramid staple fibers are crimped virgin para-aramid staple fibers having a uniform cut length, and at least 50 weight percent of the total amount of the combined polyester and para-aramid staple fibers are crimped staple fibers.

A process for manufacturing a fiber including meta-aramid having a breaking tenacity of at least 300 mN/tex including the steps of preparing a spin dope including meta-aramid and sulfuric acid having a concentration of at least 80 wt % and passing the spin dope through a spinneret into a coagulation bath, wherein the spin dope has a meta-aramid concentration of at least 10 wt %. The invention also pertains to a meta-aramid fiber, a multifilament yarn, a textile sheet and protective clothing.

A process for manufacturing a fiber including meta-aramid having a breaking tenacity of at least 300 mN/tex including the steps of preparing a spin dope including meta-aramid and sulfuric acid having a concentration of at least 80 wt % and passing the spin dope through a spinneret into a coagulation bath, wherein the spin dope has a meta-aramid concentration of at least 10 wt %. The invention also pertains to a meta-aramid fiber, a multifilament yarn, a textile sheet and protective clothing.

A nonwoven fabric sheet exhibiting high flame shielding performance, heat insulating property, and wear resistance is described, where the nonwoven fabric sheet is fabricated and includes at least one fire barrier layer formed of a web containing a non-melting fiber A having a high-temperature shrinkage rate of 3% or less and a thermal conductivity conforming to ISO22007-3 (2008) of 0.060 W/m.Math.K or less and in which the fire barrier layer is coupled with a scrim layer containing a carbide-forming heat resistant fiber B having a LOI value conforming to JIS K 7201-2 (2007) of 25 or more.

A nonwoven fabric sheet exhibiting high flame shielding performance, heat insulating property, and wear resistance is described, where the nonwoven fabric sheet is fabricated and includes at least one fire barrier layer formed of a web containing a non-melting fiber A having a high-temperature shrinkage rate of 3% or less and a thermal conductivity conforming to ISO22007-3 (2008) of 0.060 W/m.Math.K or less and in which the fire barrier layer is coupled with a scrim layer containing a carbide-forming heat resistant fiber B having a LOI value conforming to JIS K 7201-2 (2007) of 25 or more.

An aramid-based paper comprising at least 90 wt. % of aramid material, the aramid material including at least one of aramid shortcut and aramid fibrid, the paper including at most 40 wt. % aramid pulp, calculated on the total amount of aramid material, wherein the paper includes 0.1-10 wt. % of polyamido-amine epichlorohydrin (PAE). It has been found that the incorporation of 0.1-10 wt. % of polyamido-amine epichlorohydrin (PAE) into an aramid-based paper including at least 90 wt. % of aramid material calculated on the weight of the paper not including the PAE, the aramid material including at least one of aramid shortcut and aramid fibrid, the paper including at most 40 wt. % aramid pulp, leads to a surprising improvement of the z-strength and the tear strength of the paper.

An aramid-based paper comprising at least 90 wt. % of aramid material, the aramid material including at least one of aramid shortcut and aramid fibrid, the paper including at most 40 wt. % aramid pulp, calculated on the total amount of aramid material, wherein the paper includes 0.1-10 wt. % of polyamido-amine epichlorohydrin (PAE). It has been found that the incorporation of 0.1-10 wt. % of polyamido-amine epichlorohydrin (PAE) into an aramid-based paper including at least 90 wt. % of aramid material calculated on the weight of the paper not including the PAE, the aramid material including at least one of aramid shortcut and aramid fibrid, the paper including at most 40 wt. % aramid pulp, leads to a surprising improvement of the z-strength and the tear strength of the paper.

A nonwoven for use in a thermal liner for protective apparel includes 1-45 wt % of a first inherently heat resistant fiber excluding an aramid, and a balance of a second heat resistant fiber. The nonwoven excludes wool and has a thickness less than 3 mm and a basis weight of less than 2.9 osy (100 gsm). In another embodiment, the insulating layer for protective apparel includes a nonwoven including an inherently flame resistant fiber and fibers being inherently resistant to moisture absorption. The inherently flame resistant fiber is different from said inherently resistant to moisture absorption fiber. The nonwoven has an equivalent or better thermal protective performance (TPP) and a lower basis weight than an industry standard nonwoven consisting of a nonwoven of para-aramids or meta-aramids or a blend of both.