Articles, such as sanitary tissue products, including fibrous structures, and more particularly articles including fibrous structures having a plurality of fibrous elements wherein the article exhibits differential cellulose content throughout the thickness of the article and methods for making same are provided.

Articles, such as sanitary tissue products, including fibrous structures, and more particularly articles including fibrous structures having a plurality of fibrous elements wherein the article exhibits differential cellulose content throughout the thickness of the article and methods for making same are provided.

The present invention provides nanometer-sized fibers that are produced by an electrospinning method with use of a spinning solution for electrospinning, said spinning solution being environmentally friendly and taking the effects of an organic solvent on the human body into consideration. The fibers are formed from a resin that contains a silicone-modified polyurethane resin which is a reaction product of (A) a polyol, (B) a water dispersant, (C) an active hydrogen group-containing organopolysiloxane represented by formula (1)

R.sup.1R.sup.2R.sup.3SiO(SiR.sup.2R.sup.3O).sub.nSiR.sup.1R.sup.2R.sup.3  (1)

(wherein R.sup.1 represents a monovalent hydrocarbon group which may have an oxygen atom in the chain, while having from 1 to 10 carbon atoms and a hydroxyl group or a mercapto group, or a monovalent hydrocarbon group which has a primary amino group or a secondary amino group, while having from 1 to 10 carbon atoms; each of R.sup.2 and R.sup.3 represents a group that is selected from among an alkyl group having from 1 to 10 carbon atoms, an aralkyl group having from 7 to 10 carbon atoms, an aryl group having from 6 to 12 carbon atoms and a vinyl group; and n represents an integer from 1 to 200), and (D) a polyisocyanate.

The present invention provides nanometer-sized fibers that are produced by an electrospinning method with use of a spinning solution for electrospinning, said spinning solution being environmentally friendly and taking the effects of an organic solvent on the human body into consideration. The fibers are formed from a resin that contains a silicone-modified polyurethane resin which is a reaction product of (A) a polyol, (B) a water dispersant, (C) an active hydrogen group-containing organopolysiloxane represented by formula (1)

R.sup.1R.sup.2R.sup.3SiO(SiR.sup.2R.sup.3O).sub.nSiR.sup.1R.sup.2R.sup.3  (1)

(wherein R.sup.1 represents a monovalent hydrocarbon group which may have an oxygen atom in the chain, while having from 1 to 10 carbon atoms and a hydroxyl group or a mercapto group, or a monovalent hydrocarbon group which has a primary amino group or a secondary amino group, while having from 1 to 10 carbon atoms; each of R.sup.2 and R.sup.3 represents a group that is selected from among an alkyl group having from 1 to 10 carbon atoms, an aralkyl group having from 7 to 10 carbon atoms, an aryl group having from 6 to 12 carbon atoms and a vinyl group; and n represents an integer from 1 to 200), and (D) a polyisocyanate.

An enzyme responsive shape memory polymer formed from a glassy, cross-linked shape memory polymer that incorporates ester bonds that are responsive to the present of an enzyme. PCL-based polyurethanes (featuring simple alternation of PCL diol and lysine-based diisocyanate) are degradable by Amano lipase PS. A non-degradable thermoplastic elastomer may be dual electrospun with a polycaprolactone based TPU with the fixing phase compressed so that the composite is ready for enzymatically triggered contraction. Alternatively, the elastomer may be a PCL copolymer-based polyurethane amorphous elastomer that is both degradable and elastomeric and put into compression so that upon enzymatic degradation of the elastomeric phase the scaffold expands.

An enzyme responsive shape memory polymer formed from a glassy, cross-linked shape memory polymer that incorporates ester bonds that are responsive to the present of an enzyme. PCL-based polyurethanes (featuring simple alternation of PCL diol and lysine-based diisocyanate) are degradable by Amano lipase PS. A non-degradable thermoplastic elastomer may be dual electrospun with a polycaprolactone based TPU with the fixing phase compressed so that the composite is ready for enzymatically triggered contraction. Alternatively, the elastomer may be a PCL copolymer-based polyurethane amorphous elastomer that is both degradable and elastomeric and put into compression so that upon enzymatic degradation of the elastomeric phase the scaffold expands.

The present disclosure is relates to an artificial leather. The artificial leather includes multi-layer thermoplastic polyurethane (TPU) mesh layers. Fiber fineness of the TPU mesh layers ranges from 5 μm to 30 μm, and peeling strength of the TPU mesh layers is greater than 2.5 Kg/cm.

The present disclosure is relates to an artificial leather. The artificial leather includes multi-layer thermoplastic polyurethane (TPU) mesh layers. Fiber fineness of the TPU mesh layers ranges from 5 μm to 30 μm, and peeling strength of the TPU mesh layers is greater than 2.5 Kg/cm.

A thermoplastic artificial leather is provided, which includes a first structure layer, a second structure layer, a plurality of recycled particles, and a third structure layer, in which the second structure layer is disposed on the first structure layer, the plurality of recycled particles disposed on the second structure layer, and the third structure layer is disposed to cover the plurality of recycled particles. According to above stacked structure, the thermoplastic artificial leather with environment friendly is formed, and the plurality of recycled particles is processed in a physical manner, which can solve the problem, the environmental protection issue, caused by the use of solvent to process the recycled particle in the prior art. Use of the material characteristics of each structure layer to reprocess the recycled particles, so the reprocess procedure without using any solvent, so the environmental pollution and the production cost are greatly reduced.

The present invention generally relates to the design and manufacture of nanofiber layers, webs, films, or membranes that may be self-supporting and can function as standalone products. More particularly, the present invention relates to a microporous nanofiber films and the use of such films in a wide variety of products and applications, including applications where physical property tuning is typically limited. Generally, the microporous films of the present invention can function as a standalone nanofiber membrane or can be bonded to other microporous films to produce a layered stacked film stack with customizable properties. Unlike conventional microporous films available in today's market, the microporous films of the present invention can be lighter, require less raw material cost to produce, and can improve operating performances in a variety of applications.