An emulsified liquid composition is disclosed comprising a hydrophobic phase, an emulsifying composition of a protonated amide and a protonated amine having defined carbon to nitrogen atom molar ratios and water. The compositions optionally comprise at least one of a defoamer, a coalescent agent, a preservative, a co-emulsifier, chain extender, crosslinker and a rheology modifier. The compositions are useful for application to induce hydrophobicity to inorganic, organic or fiber based materials without undesirable backwetting or re-wetting effects.

An object of the present invention is to provide a ligand-immobilized sea-island composite fiber in which generation of fine particles due to peeling of a sea component from an island component and generation of fine particles due to destruction of a fragile sea component are both suppressed. The present invention provides a sea-island composite fiber comprising a sea component and island components, in which a value (L/S) obtained by dividing the average total length (L) of the perimeter of all island components in a cross section perpendicular to the fiber axis by the average cross-sectional area (S) of the cross section is from 1.0 to 50.0 μm.sup.−1, a distance from the surface to the outermost island component is 1.9 μm or less, and an amino group-containing compound is covalently bonded to a polymer constituting the sea component at a charge density of 0.1 μmol or more and less than 500 μmol per 1 gram dry weight.

A fine cellulose fiber composite in which a modifying group is bound to a carboxy group of fine cellulose fibers, the fine cellulose fibers having a carboxy group content of 0.1 mmol/g or more, wherein the fine cellulose fiber composite has an average aspect ratio of 1 or more and 150 or less; and a resin composition containing the fine cellulose fiber composite and a resin. The resin composition containing a fine cellulose fiber composite of the present invention has excellent heat resistance, and the molded article of this resin composition has excellent mechanical strength, heat resistance, and dimensional stability. Accordingly, the present invention can be suitably used in various industrial applications such as daily sundries, household electric appliance parts, wrapping materials for household electric appliance parts, and automobile parts.

A fine cellulose fiber composite in which a modifying group is bound to a carboxy group of fine cellulose fibers, the fine cellulose fibers having a carboxy group content of 0.1 mmol/g or more, wherein the fine cellulose fiber composite has an average aspect ratio of 1 or more and 150 or less; and a resin composition containing the fine cellulose fiber composite and a resin. The resin composition containing a fine cellulose fiber composite of the present invention has excellent heat resistance, and the molded article of this resin composition has excellent mechanical strength, heat resistance, and dimensional stability. Accordingly, the present invention can be suitably used in various industrial applications such as daily sundries, household electric appliance parts, wrapping materials for household electric appliance parts, and automobile parts.

The invention relates to [1] a cellulose fiber composite excellent in dispersion stability, in which at least one amine selected from a polyamine and a monoamine having a reactive functional group bonds to anion-modified cellulose fibers, and which satisfies at least one of amine introduction ratio of 60% or less (requirement 1) and average polymerization degree of anion-modified cellulose fibers of 300 or less (requirement 2), [2] a dispersion in which the cellulose fiber composite is dispersed in a medium, [3] a resin composition produced by blending the cellulose fiber composite and a resin, [4] a molded article produced by molding the cellulose fiber composite or the resin composition, and [5] a method for producing the cellulose fiber composite.

An antibacterial textile and a preparation method thereof are provided. The antibacterial textile provides advantages as followings: various sources for raw material ingredients; low cost and good antibacterial effect; safe and eco-friendly; simple in preparation method; and easy operation. Therefore, the present invention is widely applicable in industrial production.

A fiber is provided as a substrate for a functional nanostructure (coated fiber), composed of (a) a fiber substrate; (b) a reactive dye conjugating moiety covalently bound to the fiber substrate; (c) a bonding agent covalently bound to the reactive dye conjugating moiety; and (d) the functional nanostructure bound to the bonding agent. A method of making the coated fiber is also provided, involving the following steps in any order: covalently binding the reactive dye conjugating moiety to the fiber; covalently binding a bonding agent to the reactive dye conjugating moiety; and binding the functional nanostructure to the bonding agent. The nanostructures are tenaciously attached to the fibers, resisting very rough treatments, and can be made using inexpensive and widely available reactive dyes under non-stringent synthesis conditions.

A fiber is provided as a substrate for a functional nanostructure (coated fiber), composed of (a) a fiber substrate; (b) a reactive dye conjugating moiety covalently bound to the fiber substrate; (c) a bonding agent covalently bound to the reactive dye conjugating moiety; and (d) the functional nanostructure bound to the bonding agent. A method of making the coated fiber is also provided, involving the following steps in any order: covalently binding the reactive dye conjugating moiety to the fiber; covalently binding a bonding agent to the reactive dye conjugating moiety; and binding the functional nanostructure to the bonding agent. The nanostructures are tenaciously attached to the fibers, resisting very rough treatments, and can be made using inexpensive and widely available reactive dyes under non-stringent synthesis conditions.

The disclosure provides a composition comprising a modified cellulosic surface having aliphatic fatty acid molecules and amine-silica particles that are covalently bonded to cellulose fibers of the cellulosic surface. Also disclosed is a composition comprising a modified cellulosic surface including low surface energy molecules and amine functionalized nanotubes decorated with silica nanoparticles that are covalently bonded to cellulose fibers of the cellulosic surface. Also disclosed is a process for increasing hydrophobicity of a cellulosic surface. Also disclosed is a process for increasing hydrophobicity and surface roughness of a cellulosic surface. Also disclosed are products comprising the compositions and modified cellulosic surfaces of the present invention.

The disclosure provides a composition comprising a modified cellulosic surface having aliphatic fatty acid molecules and amine-silica particles that are covalently bonded to cellulose fibers of the cellulosic surface. Also disclosed is a composition comprising a modified cellulosic surface including low surface energy molecules and amine functionalized nanotubes decorated with silica nanoparticles that are covalently bonded to cellulose fibers of the cellulosic surface. Also disclosed is a process for increasing hydrophobicity of a cellulosic surface. Also disclosed is a process for increasing hydrophobicity and surface roughness of a cellulosic surface. Also disclosed are products comprising the compositions and modified cellulosic surfaces of the present invention.