A polyurethane resin composition includes a reaction product of an aliphatic polyisocyanate derivative having an average number of isocyanate groups of 2 or more; a long-chain active hydrogen compound including a hydrocarbon group having 12 or more and 30 or less carbon atoms and an active hydrogen group in combination; a cationic active hydrogen compound including an active hydrogen group and a cationic group in combination; and an acid compound capable of a salt with the cationic group. The concentration of the hydrocarbon group is 30% or more and 85% or less.

A polyurethane resin composition includes a reaction product of an aliphatic polyisocyanate derivative having an average number of isocyanate groups of 2 or more; a long-chain active hydrogen compound including a hydrocarbon group having 12 or more and 30 or less carbon atoms and an active hydrogen group in combination; a cationic active hydrogen compound including an active hydrogen group and a cationic group in combination; and an acid compound capable of a salt with the cationic group. The concentration of the hydrocarbon group is 30% or more and 85% or less.

A urethane compound (A) including units formed from (A1) an isocyanate and (A2) a long-chain alcohol represented by the formula HO—Z(Y—R).sub.n [wherein the R moieties are each independently —O—, —NH—, —O—C(═O)—, —NH—C(═O)—, —C(═O)—NH—, —O—C(═O)—NH—, —NH—C(═O)—O—, —NH—C(═O)—NH—, —NH—S(═O).sub.2—, —S(═O).sub.2—NH—, —NH—(CH.sub.2).sub.m—NH—S(═O).sub.2—, —NH—(CH.sub.2).sub.m—S(═O).sub.2—NH—, etc. (m is an integer of 1-5), Z is a direct bond or a di- or trivalent hydrocarbon group having 1-5 carbon atoms, and n is 1 or 2]. Also disclosed is a urethane mixture containing the urethane compound (A), and at least one selected from the polyisocyanate (A1), the long-chain alcohol (A2), a blocking agent (A3) and an alcohol compound (A4); an aqueous urethane composition; a method for producing the aqueous urethane composition; a method of treating a substrate; and a treated textile product.

A urethane compound (A) including units formed from (A1) an isocyanate and (A2) a long-chain alcohol represented by the formula HO—Z(Y—R).sub.n [wherein the R moieties are each independently —O—, —NH—, —O—C(═O)—, —NH—C(═O)—, —C(═O)—NH—, —O—C(═O)—NH—, —NH—C(═O)—O—, —NH—C(═O)—NH—, —NH—S(═O).sub.2—, —S(═O).sub.2—NH—, —NH—(CH.sub.2).sub.m—NH—S(═O).sub.2—, —NH—(CH.sub.2).sub.m—S(═O).sub.2—NH—, etc. (m is an integer of 1-5), Z is a direct bond or a di- or trivalent hydrocarbon group having 1-5 carbon atoms, and n is 1 or 2]. Also disclosed is a urethane mixture containing the urethane compound (A), and at least one selected from the polyisocyanate (A1), the long-chain alcohol (A2), a blocking agent (A3) and an alcohol compound (A4); an aqueous urethane composition; a method for producing the aqueous urethane composition; a method of treating a substrate; and a treated textile product.

Disclosed is a retro-reflective fabric, having an inner surface and an outer surface; one or more strands of retro-reflective yarn incorporated into the fabric; and a reflective ink coupled to the outer surface of the fabric. Also provided is a method of making a retro-reflective fabric, including: providing a coated retro-reflective yarn; incorporating the coated retro-reflective yarn into the weave or knit of a fabric; and disposing a reflective ink into an outward facing surface of the fabric.

Disclosed is a retro-reflective fabric, having an inner surface and an outer surface; one or more strands of retro-reflective yarn incorporated into the fabric; and a reflective ink coupled to the outer surface of the fabric. Also provided is a method of making a retro-reflective fabric, including: providing a coated retro-reflective yarn; incorporating the coated retro-reflective yarn into the weave or knit of a fabric; and disposing a reflective ink into an outward facing surface of the fabric.

A water repellent composition includes a polyurethane resin compound, a non-fluorine water repellent compound, a surfactant, and a liquid medium. The polyurethane resin compound includes at least one kind selected from the group consisting of a first polyurethane resin compound, a second polyurethane resin compound, and a third polyurethane resin compound:

A water repellent composition includes a polyurethane resin compound, a non-fluorine water repellent compound, a surfactant, and a liquid medium. The polyurethane resin compound includes at least one kind selected from the group consisting of a first polyurethane resin compound, a second polyurethane resin compound, and a third polyurethane resin compound:

Fabrics that are exhibit water repellency, abrasion resistance, and optionally flame resistance are described herein. The fabrics include a plurality of fibers (such as flame resistant fibers) and a finish that imparts water repellency and abrasion resistance to the fibers. The fabrics are free or substantially free from alkylfluoropolymers. Also described herein are garments including the fabrics.

Fabrics that are exhibit water repellency, abrasion resistance, and optionally flame resistance are described herein. The fabrics include a plurality of fibers (such as flame resistant fibers) and a finish that imparts water repellency and abrasion resistance to the fibers. The fabrics are free or substantially free from alkylfluoropolymers. Also described herein are garments including the fabrics.