A urethane compound (A) including units formed from (A1) an isocyanate and (A2) a long-chain alcohol represented by the formula HO—Z(Y—R).sub.n [wherein the R moieties are each independently —O—, —NH—, —O—C(═O)—, —NH—C(═O)—, —C(═O)—NH—, —O—C(═O)—NH—, —NH—C(═O)—O—, —NH—C(═O)—NH—, —NH—S(═O).sub.2—, —S(═O).sub.2—NH—, —NH—(CH.sub.2).sub.m—NH—S(═O).sub.2—, —NH—(CH.sub.2).sub.m—S(═O).sub.2—NH—, etc. (m is an integer of 1-5), Z is a direct bond or a di- or trivalent hydrocarbon group having 1-5 carbon atoms, and n is 1 or 2]. Also disclosed is a urethane mixture containing the urethane compound (A), and at least one selected from the polyisocyanate (A1), the long-chain alcohol (A2), a blocking agent (A3) and an alcohol compound (A4); an aqueous urethane composition; a method for producing the aqueous urethane composition; a method of treating a substrate; and a treated textile product.

To provide a water/oil repellent composition whereby it is possible to obtain an article which is excellent in each of water-repellency, oil-repellency, washing durability, heavy rain durability and texture, a method for producing said composition, and an article which is excellent in each of water-repellency, oil-repellency, washing durability, heavy rain durability and texture. The water/oil repellent composition comprises a copolymer having units based on a monomer (a), units based on a monomer (b) and units based on a monomer (c), and a liquid medium. Monomer (a): a compound represented by (Z—Y).sub.nX (Z: a C.sub.1-6 perfluoroalkyl group, etc.; Y: a divalent organic group, etc.; n: 1 or 2; X: a polymerizable unsaturated group). Monomer (b): a (meth)acrylate having no polyfluoroalkyl group and having an alkyl group with at least 20 carbon atoms. Monomer (c): a compound represented by CH.sub.2═CR.sup.1C(O)O—[(C.sub.2H.sub.4O).sub.a(C.sub.4H.sub.8O).sub.b]—H (R.sup.1: a hydrogen atom or a methyl group, and a/b=1 to 3).

An aqueous emulsion contains a copolymer having three components: a) to c). Component a) has at least one biuret or isocyanurate substructure. Component b) is selected from polysiloxanes and polyhydrocarbons, preferably polysiloxanes. Component c) contains a hydrocarbon which is different from component b) and has at least 6 carbon atoms and not more than 3 heteroatoms selected from N, O, and S. Component b) is joined to 2 different or identical components a) via at least two positions.

An oil repellent agent including a modified natural product having at least one hydroxyl group, wherein a hydrogen atom of the hydroxyl group is replaced with an R group represented by —Y—Z, wherein Y represents a direct bond, —C(═O)—, —C(═O)—NR′— or —C(═S)—NR′—, where R′ represents a hydrogen atom or a C.sub.1 to C.sub.4 alkyl group); and Z represents a hydrocarbon group having 1 to 40 carbon atoms and optionally having a substituent or a polysiloxane. The natural material is a natural product other than starch and preferably is a monosaccharide, a polysaccharide, glycerin or polyglycerin. Also disclosed is a textile product to which the oil-resistant agent is attached, an oil-resistant paper and a method of treating paper with the oil-resistant agent.

A dispersion containing a fluorine-containing polymer and a liquid medium. The fluorine-containing polymer includes a repeating unit derived from a fluorine-containing monomer (a) having a Q value of 2.0 or more and comprising a fluoroalkyl group, and a repeating unit derived from a chloride monomer (b) that is at least one selected from vinyl chloride and vinylidene chloride. Further, the dispersion has a concentration of unreacted chloride monomer (b) of 2.0 ppm or less.

Articles are provided that include a fibrous substrate and porous polymeric particles. At least 50% of the porous polymeric particles are bound to the fibrous substrate. Methods of making the articles are provided that include providing porous polymeric particles, providing a fibrous substrate, and binding the porous polymeric particles to the fibrous substrate. The articles can be used for fluid management.

The present invention relates generally to compositions comprising polyelectrolytes complexes (PECs) of anionic and cationic biopolymers capable of forming barriers on fiber based materials. Also disclosed is a fibre based material with a barrier coating against oil and water, wherein the material is provided with a barrier from at least two layers formed from at least one composition comprising a polyelectrolyte complex (PEC) of a cationic biopolymer and an anionic biopolymer, The two layers result in improvements in both oil resistance and water resistance compared to the same material provided with a single layer of said at least one composition.

Esters of polylactic acid, including polyethylene glycol esters of polylactic acid are disclosed. Exemplary esters of polylactic acid can be used as textile finishes. Methods of making the esters of polylactic acid via direct and transesterification reactions are also disclosed.

A method for coating a textile material, said method includes the following steps: a) incorporating activated carbon in powder form into a coating composition including an aqueous solvent and at least one organosilicon precursor, wherein the organosilicon precursor represents from 5 to 50% by volume relative to the whole of the aqueous solvent and organosilicon precursor, b) impregnating the textile material with the coating composition by padding and c) drying the impregnated textile material, characterised in that the coating composition contains no polycarboxylic acid or catalyst.

A soil-resistant fiber fabric having excellent water/oil repellency and excellent soil dirt resistance is obtained by fixing colloidal silica to a fiber fabric, and by subsequently treating the fiber fabric with a water/oil repellent fluorine compound, thereby having the water/oil repellent fluorine compound adhere to a surface of the fiber fabric.