A suede type artificial leather having an antifouling property is provided. A polymeric elastomer is impregnated in a nonwoven fabric formed by three-dimensionally interlacing ultrafine fibers and raising is formed, wherein the polymeric elastomer is a fluorine-containing modified polyurethane, and the fluorine-containing modified polyurethane is obtained by a polymerization of a urethane prepolymer having isocyanate groups at terminals, obtained by reacting a diol and a diisocyanate, and a fluorinated carbon compound having hydroxy functional groups at both terminals. The fluorine-containing modified polyurethane has a weight average molecular weight of 500,000 to 800,000. The suede type artificial leather is prepared by using the fluorine-containing polyurethane elastomer.

Disclosed is a napped artificial leather napped including: a non-woven fabric that is an entangle body of ultrafine fibers; and an elastic polymer impregnated into the non-woven fabric, the napped artificial leather having, at least on one side thereof, a napped surface formed by napping the ultrafine fibers, wherein the ultrafine fibers contain 0.5 mass % or more of a pigment (A), the elastic polymer contains 0 to 0.01 mass % of a pigment (B), and the ultrafine fibers and the elastic polymer are undyed; the napped surface has a lightness L* value of 25 or less in a color coordinate space (L*a*b* color space); and a ratio of an area occupied by the elastic polymer, observed on the napped surface, to a total area of an area occupied by the ultrafine fibers and the area occupied by the elastic polymer is 0.5% or less.

The invention refers to a process for the preparation of a microfibrous non-woven fabric based on polyester or polyamide microfibers immersed in a polyurethane matrix, and having a thickness equal to or less than 0.65 mm, a flat or slightly mottled appearance and a nap length of less than 350 μm. The non-woven fabric is used for the preparation of coverings for consumer goods, particularly for the preparation of covers and cases for electronic products.

The invention relates to a method for producing a surface-structured layered material which has a backing layer (I) and a polyurethane layer (2) connected thereto, the backing layer (I) used, in particular in pieces, being a leather, preferably a smoothed full-grain leather or a split cowskin, a textile material, preferably a woven fabric or a knitted fabric, a cellulose fibre material, a split foam, a leather fibre material or a microfibre fleece and being connected to the layer (2), and the layer (2) applied to the backing layer (I) being at least one, preferably a single layer formed of a PU foam, in particular containing gas pockets, preferably a whipped PU foam optionally containing hollow microspheres and/or a PU foam containing hollow microspheres. According to the invention: —the PU foam, in particular containing gas pockets, is created with a PU dispersion mixture, wherein the individual PU dispersions used to create the PU dispersion mixture exhibit different softening points in the dry state; —to create the PU dispersion mixture, one or more PU dispersions having heat—preferably melting and contact adhesive properties and a softening point in the dry state greater than 40° C., preferably greater than 45° C., in an amount of 18 to 52 wt ¾ of the finished PU dispersion mixture is/are mixed with one or more PU dispersions without melting and contact adhesive properties and with a softening point greater than 95° C., preferably greater than 125° C., in an amount of 39 to 73 wt ¾ of the finished PU dispersion mixture; —the PU dispersion mixture for the layer (2) is applied to the backing layer (I) with a thickness such that the layer has a thickness in the dried state of 0.075 to 0.450 mm, preferably 0.150 to 0.280 mm; —before or during structuring of the PU foam, a further layer (3) of a non-foamed PU dispersion which is a mixture of multiple PU dispersions is applied to the layer (2); —the backing layer (I) is optionally cut or punched into banks or pattern parts before or after the application of the PU foam, in particular after the drying thereof, and the coated blanks or pattern parts are subjected to stamping or structuring under pressure and temperature; and —the backing layer (1), the further layer (3) and the layer (2) are compressed and joined to one another and structured with a die (4) under application of a contact pressure of 4 to 48 kg/cm2, preferably 4 to 48 kg/cm2, in particular 18 to 25 kg/cm2.

A sheet material has good mechanical properties, flexibility, lightweight properties, and quality, and also relates to a production method therefor. The sheet material includes, as constitutional components, an elastic polymer and nonwoven fabric composed mainly of ultrafine hollow fiber with an average monofilament diameter in the range of 0.05 to 10 μm, the ultrafine hollow fiber containing 2 to 60 hollows.

The present invention concerns a process for preparing a microfibrous multilayer composite material comprising: 1) realizing a non-woven microfibrous semi-finished product made up of microfibres of one or more polymers dispersed in a polyurethane matrix (semi-finished product IE); 2) cutting the semi-finished product lengthwise into two layers; 3) buffing at least one layer on one side (side N) so as to extract the microfibres and form the nap, thereby obtaining a semi-finished raw product; 4) cutting at least one semi-finished raw product lengthwise parallel to the surfaces, producing an non-woven intermediate product, containing the buffed side (side N) and a waste layer (containing the side that has not been buffed—side S); 5) coupling the non-woven intermediate product (on the side opposite side N) to a fabric made of polyethylene terephthalate fibres by means of the application of a thermoplastic polyurethane adhesive that can be cross-linked between the non-woven intermediate product and the fabric; 6) submitting the multilayer composite material to a jet dyeing process. The invention also concerns a multilayer composite material that can be obtained by the process of the invention and the use thereof for covering the internal side of roofs or headliners of vehicles and for covering furnishing elements.

A decorative molding sheet including: an artificial leather substrate that includes a non-woven fabric containing ultrafine fibers with an average fineness of 0.001 to 1 dtex and an elastic polymer applied in the non-woven fabric, and that has a leather-like finished surface; and a resin layer that is formed on a back surface of the artificial leather substrate relative to the leather-like finished surface, and that contains a vinyl chloride-vinyl acetate copolymer, and a preform molded body obtained by shaping the decorative molding sheet into a three-dimensional shape are used.

A sheet material includes a polymeric elastomer and a fiber-entangled body including, as a constituent element, a nonwoven fabric including ultrafine fibers having an average single fiber diameter of 1.0 μm or more and 10.0 μm or less. The ultrafine fibers include a polyester-based resin including a black pigment (a.sub.1). The black pigment (a.sub.1) has an average particle diameter of 0.05 μm or more and 0.20 μm or less and has a coefficient of variation (CV) of the average particle diameter of 75% or less. The polymeric elastomer includes a polyurethane including a black pigment (b). The sheet material has a nap coverage of 70% or more and 100% or less on a surface having a nap.

A purpose of the present invention is to provide a sheet-shaped article and a manufacturing method therefor, said sheet-shaped article demonstrating both a supple texture and superior wear resistance. In order to achieve this purpose, a sheet-shaped article according to the present invention is a sheet-shaped article that includes, in a fibrous base material, a polymer elastic body with a hydrophilic group, said fibrous base material comprising extremely fine fibers with an average individual fiber fineness of 0.1 μm to 10 μm, wherein the sheet-shaped article has N-acylurea bonding or isourea bonding within the polymer elastic body, and a monovalent positive ion-including inorganic salt is present at a rate of 0.1 mass % to 5 mass % with regard to the mass of the polymer elastic body.

Disclosed is a leather-like sheet having a lightness L* of 35 or less, and including a fiber structure including fiber dyed with a dye composition including C.I. Basic Blue 3 and at least one blue cationic dye other than C.I. Basic Blue 3, and an elastic polymer contained in internal voids of the fiber structure, or the fiber structure. Also disclosed is a leather-like sheet having a lightness L* of 35 or less, and including a fiber structure including fiber dyed with an azo-based blue cationic dye, and an elastic polymer contained in internal voids of the fiber structure, wherein the leather-like sheet or the fiber structure has a color difference (ΔE), determined when treated for 48 hours under moist and hot conditions of 80° C. and a moisture of 90%, of ΔE≤2. or the fiber structure.