D06N3/0004

SHEET MATERIAL AND METHOD FOR PRODUCING SAME

The sheet material according to the present invention has a polymer elastic body and a fibrous base material comprising ultrafine fibers, wherein the average single fiber diameter of the ultrafine fibers is 0.1 .Math.m to 10.0 .Math.m, the polymer elastic body has a hydrophilic group and an N-acylurea bond and/or an isourea bond, and the following conditions are satisfied : the longitudinal stiffness, in accordance with method A (45° cantilever method) in the text of “8.21 Stiffness” of JIS L 1096:2010 “Testing Methods for Woven and Knitted Fabrics”, is 40 mm to 140 mm ; and after immersion for 24 hours in N,N-dimethylformamide, the following are obtained in wear testing using a pressing load of 12.0 kPa and 20,000 friction cycles in accordance with method E (Martindale method) in the text of “8.19 Wear Strength and Friction Discoloration” of JIS L 1096:2010 “Testing Methods for Woven and Knitted Fabrics”: a grade of at least 4 and a wear loss of not more than 25 mg.

GRAPHENE-IMPREGNATED MICROFIBER FABRIC

Graphene-impregnated microfiber fabrics and methods for producing such fabrics are disclosed. In one example, a method of producing a graphene-impregnated microfiber fabric comprises providing a microfiber substrate comprising polymer fibers. Graphene is mixed into a polymer-based dispersion to create a graphene-impregnated polymer-based dispersion. The graphene-impregnated microfiber fabric is formed by immersing the microfiber substrate in the graphene-impregnated polymer-based dispersion to coat the polymer fibers of the substrate with the graphene and the polymer of the polymer-based dispersion. The fabric is removed from the dispersion and dried.

SHEET MATERIAL AND METHOD FOR PRODUCING SAME

The purpose of the present invention is to provide: a sheet-like article which has a good balance between soft texture and excellent light resistance; and a method for producing this sheet-like article. In order to achieve this purpose, a sheet-like article according to the present invention has the following configuration. Specifically, a sheet-like article which contains a polymer elastic body in a fibrous base material, wherein: the fibrous base material is composed of ultrafine fibers that have an average single fiber diameter of from 0.1 μm to 10 μm; the polymer elastic body has a hydrophilic group, while containing a polyether diol as a constituent; the polymer elastic body internally has an N-acylurea bond and/or an isourea bond; and the condition 1 and the condition 2 described below are satisfied. Condition 1: The bending resistance in the lengthwise direction as determined in accordance with specific standards is from 40 mm to 140 mm. Condition 2: The abrasion weight loss after 20,000 cycles of a Martindale abrasion test set forth in JIS L 1096 (2005) after a light resistance test as performed under the conditions defined in accordance with specific standards is 25 mg or less.

Artificial Leather and Production Method Therefor

Provided is an artificial leather that has texture (stiffness), a luxuriant feel (dispersibility of fiber bundles), and a slick feel (resin clusters of appropriate size) and can be used suitably as a seat cover material or interior design material for interiors, cars, airplanes, railway cars, etc. and garment accessory products. This artificial leather comprises a fiber sheet and a polyurethane resin and is characterized in that: the fiber sheet comprises at least a fiber layer (A) that forms a first outer surface of the artificial leather; the k-nearest neighbor distance proportion (k=9, radius r=20 μm) between cross-sections of single fibers configuring the fiber layer (A) in a thickness direction cross-section of the artificial leather is 10-80%; the cross-sectional polyurethane resin area ratio in a thickness direction cross-section of the fiber layer (A) is 10-30%; and the standard deviation of the cross-sectional polyurethane resin area ratio in a thickness direction cross-section of the fiber layer (A) is 25% or less.

LIGHT-EMITTING DISPLAY DEVICE, AND A LIGHT-BLOCKING LAYER-EQUIPPED FIBER SHEET FOR USE IN LIGHT-EMITTING DISPLAY DEVICE
20230053585 · 2023-02-23 · ·

A light-emitting display device includes: a light-emitting member; and a light-blocking layer-equipped fiber sheet that covers a light-emitting surface of the light-emitting member. The light-blocking layer-equipped fiber sheet includes a fiber sheet, and a light-blocking layer that is partially printed on at least one surface of the fiber sheet. The surface of the fiber sheet on which the light-blocking layer is formed has an arithmetic mean height Sa of 3 to 20 μm, as measured based on ISO 25178, and the fiber sheet has an apparent density of 0.5 g/cm.sup.3 or more.

Grained artificial leather and method for manufacturing grained artificial leather

Disclosed is a grain-finished artificial leather including an artificial leather base material, and a grain layer stacked on the artificial leather base material. The artificial leather base material includes a fiber-entangled body including ultrafine fibers having an average fineness of 0.4 dtex or less, an elastic polymer, and fine particles having an average particle size of 10 μm or less. The content ratio of the fine particles is 10 to 40 mass %, and the ratio of the elastic polymer to the total amount of the elastic polymer and the fine particles is 20 to 80 mass %. Also, a total of an apparent density of the elastic polymer and an apparent density of the fine particles is 0.23 to 0.55 g/cm.sup.3.

LEATHER-LIKE SHEET
20230033018 · 2023-02-02 · ·

A leather-like sheet includes: a fiber base material; an intermediate resin layer stacked on one surface of the fiber base material; and a surface resin layer stacked on the intermediate resin layer. The surface resin layer contains a polyether-based polyurethane and spherical fine particles having a heat resistance at 200° C., and has a content ratio of the spherical fine particles of 5 to 40 mass %. The spherical fine particles have a specific heat of 0.95 kJ/(kg.Math.K) or more, a particle size D.sub.50 (median diameter) at a cumulative distribution of 50 vol %, of 2.5 to 10 μm, and a particle size D.sub.10 at a cumulative distribution of 10 vol % of the spherical fine particles which satisfies a condition that a particle size dispersity D.sub.50/D.sub.10≤3.

Automobile instrument panel surface material and method of manufacturing same

An automobile instrument panel surface material includes a microfiber having an average single fiber diameter of 0.3 to 7 μm; and polyurethane, the automobile instrument panel surface material having nap formed of the microfiber, the automobile instrument panel surface material having, of light fastnesses measured according to a light fastness measurement method of JIS L 0843:2006 under conditions of a xenon arc intensity of 110 MJ/m2, a fading by gray scale evaluation of grade 3.5 or higher, the automobile instrument panel surface material having a glass haze of 10.0% or less as measured according to a glass haze evaluation method of ISO 6452:2007 under conditions of a heating temperature of 100° C. and a heating time of 20 hours.

NAPPED ARTIFICIAL LEATHER

A napped artificial leather includes: a non-woven fabric that is art entangled body of ultrafine fibers, and an elastic polymer applied into the non-woven fabric; where the napped artificial leather has, on at least one side thereof, a napped surface formed by napping the ultrafine fibers. Each of the ultrafine fibers is art ultrafine fiber having a fineness of 0.5 dtex or less, and a tensile strength of 6 to 9 mN. A plurality of the ultrafine fibers form a fiber bundle, and the ultrafine fibers that form the fiber bundle are not constrained by the elastic polymer in a region of the napped artificial leather other than a surface layer portion. A content ratio of the elastic polymer is 16 to 40 mass %, and the napped artificial leather has an apparent density of 0.38 g/cm.sup.3 or more.

METHOD FOR MANUFACTURING SHEET-LIKE PRODUCT

Provided is a production method in which a sheet-like article that has high moist heat resistance and has good surface quality and texture can be produced, regardless of the coagulation technique used for the polyurethane, by an environmentally friendly manufacturing process that is designed to cause reaction of a crosslinking agent while maintaining the texture possessed by the material before crosslinking. The production method for sheet-like articles is a sheet-like article production method characterized by impregnating a fibrous base material with water dispersed polyurethane as a binder, coagulating it to provide a sheet, adding a solution or dispersion liquid of a crosslinking agent to the sheet, and then heating it at a temperature of 100° C. or more and 200° C. or less.