The present disclosure relates to thermoplastic collagen elastomer compositions comprising collagen, at least one reactive thermoplastic elastomer, and at least one softener, as well as composite materials made from these compositions. Methods of making and using the thermoplastic collagen elastomer composite materials to produce engineered leather are also disclosed.

A preparation method for producing a light-transparent artificial leather comprises the steps of: mixing, stirring, grinding, filtering and defoaming primary raw materials, including toner with a particle size of 0.5˜10 nm, polymer powder and a plasticizer, to produce a light-transparent pigment; mixing the light-transparent pigment with secondary raw materials, including polymer powder, a plasticizer, a stabilizer and an inorganic additive, and stirring, grinding, filtering and defoaming the mixture to produce a light-transparent epidermal layer material; mixing a base fabric, glue and a support layer material with the epidermal layer material and making the mixture into a semi-finished artificial leather product, which comprises the light-transparent epidermal layer, a support layer, a glue layer and a base fabric; and applying a surface treating agent on to the surface of the light-transparent epidermal layer to produce a light-transparent artificial leather (e.g., for an automobile interior).

A leather-like sheet includes: a fiber base material; an intermediate resin layer stacked on one surface of the fiber base material; and a surface resin layer stacked on the intermediate resin layer. The surface resin layer contains a polyether-based polyurethane and spherical fine particles having a heat resistance at 200° C., and has a content ratio of the spherical fine particles of 5 to 40 mass %. The spherical fine particles have a specific heat of 0.95 kJ/(kg.Math.K) or more, a particle size D.sub.50 (median diameter) at a cumulative distribution of 50 vol %, of 2.5 to 10 μm, and a particle size D.sub.10 at a cumulative distribution of 10 vol % of the spherical fine particles which satisfies a condition that a particle size dispersity D.sub.50/D.sub.10≤3.

The present invention relates to a process for the production of a dyed biopolymer comprising the steps of providing at least one biopolymer-producing microorganism, providing at least one dye-producing microorganism, culturing said at least one biopolymer-producing microorganism to produce at least a biopolymer, and culturing said dye-producing microorganism wherein said dye-producing microorganism produce at least a dye suitable to dye at least part of said biopolymer, whereby a dyed biopolymer is obtained. The present invention also relates to a dyed biopolymer, to process for the production of a dyed composite article comprising at least the dyed biopolymer and to articles comprising the dyed biopolymer.

A colored resin sheet includes a resin and a colorant dispersed in the resin, and has an average value of visible light transmittances for a red range of a wavelength of 680 to 780 nm, of 50% or more. The colored resin sheet has a combination of a lightness L* value and an average value of light transmittances for an entire visible light range of a wavelength of 380 to 780 nm, respectively, of: a) 15 or less, and 15% or more; b) greater than 15 and less than or equal to 35, and 25% or more; or c) greater than 35 and less than or equal to 60, and 40% or more. A leather-like sheet includes a colored resin layer and a surface having a lightness L* value of 40 or less, and has an average value of visible light transmittances for the red range, of 5% or more.

Disclosed is a grain-finished leather-like sheet including: a fiber base material; a polyurethane intermediate layer stacked on the fiber base material; and a polyurethane skin film stacked directly on the polyurethane intermediate layer or via another polyurethane layer, wherein the polyurethane skin film contains a silicone-modified polyurethane, and the grain-finished leather-like sheet has an uneven surface whose skewness (Ssk), kurtosis (Sku), and maximum height (Sz) of surface roughness in accordance with ISO 25178 respectively satisfy −0.4≤Ssk≤−0.2, 3≤Sku≤4, 60 μm≤Sz≤150 μm.

The present invention relates to an aqueous paste composition for textile coating, comprising: 1-60 parts by weight of at least one material having tensile modulus of at least 2000 MPa, 1-24 parts by weight of at least one antistatic agent, 16-60 parts by weight of at least one binder, and 50-200 parts by weight of water. The invention also relates to a process for producing a coated fabric, to a coated fabric as obtainable trough said process, and to a garment comprising it.

Disclosed is a napped artificial leather napped including: a non-woven fabric that is an entangle body of ultrafine fibers; and an elastic polymer impregnated into the non-woven fabric, the napped artificial leather having, at least on one side thereof, a napped surface formed by napping the ultrafine fibers, wherein the ultrafine fibers contain 0.5 mass % or more of a pigment (A), the elastic polymer contains 0 to 0.01 mass % of a pigment (B), and the ultrafine fibers and the elastic polymer are undyed; the napped surface has a lightness L* value of 25 or less in a color coordinate space (L*a*b* color space); and a ratio of an area occupied by the elastic polymer, observed on the napped surface, to a total area of an area occupied by the ultrafine fibers and the area occupied by the elastic polymer is 0.5% or less.

Disclosed are a soft solvent-free flame-retardant polyurethane synthetic leather and a preparation method therefor. The soft solvent-free flame-retardant polyurethane synthetic leather comprises an antifouling layer, a surface layer, an intermediate layer, a bonding layer and a base cloth in sequence from top to bottom, wherein the bonding layer is prepared from component A and an isocyanate; the molar ratio of —NCO in the isocyanate to —OH in the component A is 0.85-0.93; and the component A is composed of a polyhydric alcohol, an inhibition-type catalyst, a flame retardant, a filler and a viscosity modifier in parts by weight.

Disclosed are a soft solvent-free flame-retardant polyurethane synthetic leather and a preparation method therefor. The soft solvent-free flame-retardant polyurethane synthetic leather comprises an antifouling layer, a surface layer, an intermediate layer, a bonding layer and a base cloth in sequence from top to bottom, wherein the bonding layer is prepared from component A and an isocyanate; the molar ratio of —NCO in the isocyanate to —OH in the component A is 0.85-0.93; and the component A is composed of a polyhydric alcohol, an inhibition-type catalyst, a flame retardant, a filler and a viscosity modifier in parts by weight. The polyurethane synthetic leather prepared by the present invention has daily life antifouling properties, a good durability, is soft to the touch, is strongly skin-friendly, and has a very superior flame-retardant performance, and also has excellent antifouling, scratch resistance and flexure resistance properties; the production process is simple, efficient and environmentally friendly and same can satisfy market demands.

A composite material formed by combining a polyurethane material with an unclickable foam layer and a scrim layer through roll and flat form technology. The composite material is embossed to form pillowlike chambers or cells delineated by a network of emboss pattern lines formed by the bonding between these layers.