The present invention is a synthetic leather including a base fabric (i), an intermediate layer (ii), and a skin layer (iii), in which the intermediate layer (ii) is formed of an aqueous urethane resin composition (C) containing a urethane resin (A) and an aqueous medium (B), the urethane resin (A) is a reaction product of a polyol (a1) containing a polyol (a1-1) having an anionic group and an aromatic polyisocyanate (a2), and has an anionic group in a concentration of 0.35 mmol/g or less, the skin layer (iii) is formed of an aqueous urethane resin composition (Z) containing a urethane resin (X) and an aqueous medium (Y), and the urethane resin (X) is a reaction product obtained by using a polyol (b1), a reactive silicone (b2) having a functional group which reacts with an isocyanate group, and a polyisocyanate (b3) as essential raw materials.

According to exemplary inventive practice, a personal armor system includes a textile-based layer not exceeding ½-half-inch thickness, and an elastomeric coating not exceeding ⅛-inch thickness. The textile-based layer includes a fiber reinforcement and a resin binder. The combined areal density of the textile-based layer and the elastomeric coating does not exceed 2.5 psf. According to a first mode of inventive practice, the elastomeric coating is essentially a strain-rate-sensitivity-hardening elastomer, and the areal density of the textile-based layer does not exceed 2.3 psf. According to a second mode of inventive practice, the elastomeric coating is essentially a microparticle-filled strain-rate-sensitivity-hardening elastomeric matrix material, and the areal density of the textile-based layer does not exceed 1.7 psf. The microparticles (e.g., spherical glass microparticles) do not exceed, by weight, 30 percent of the strain-rate-sensitivity-hardening elastomeric matrix material. The textile-based layer affords ballistic protection; the elastomeric coating affords protection against sharp/pointed objects.

The present disclosure provides layered collagen materials comprising one or more collagen/polymer matrix layers. The collagen/polymer matrix layer(s) are formed of a collagen blended with one or more polymers. The collagen blended within the polymer(s) can be dissolved within the polymer(s). The one or more collagen/polymer matrix layers can be attached to a substrate layer, for example a fabric layer.

A process of making a synthetic leather includes (i) first, contacting a textile with an aqueous solution containing a cationic hydroxyethylcellulose polymer to form a modified textile component; (ii) subsequently, impregnating the modified textile component with an aqueous polyurethane dispersion externally stabilized with an anionic surfactant; and (iii) precipitating the polyurethane in the modified textile component. And a synthetic leather formed by the process.

Some embodiments relate to a roofing material. The roofing material comprises a substrate, and a coating on the substrate. The coating comprises at least a polymer A, a polymer B, and at least one filler. The polymer A, the polymer B, the at least one filler are present in an amount sufficient to result in the coating having: A) a Tear CD property of at least 1000 g-f; and B) at least one of an interpenetrating polymer network, a semi-interpenetrating polymer network, or any combination thereof. Other embodiments relate to additional roofing materials, methods for preparing roofing materials, and the like.

The present disclosure provides layered collagen materials comprising one or more collagen/polymer matrix layers. The collagen/polymer matrix layer(s) are formed of a collagen blended with one or more polymers. The collagen blended within the polymer(s) can be dissolved within the polymer(s). The one or more collagen/polymer matrix layers can be attached to a substrate layer, for example a fabric layer.

A process of making a synthetic leather includes (i) first, contacting a textile with an aqueous solution containing a cationic hydroxyethylcellulose polymer to form a modified textile component; (ii) subsequently, impregnating the modified textile component with an aqueous polyurethane dispersion externally stabilized with an anionic surfactant; and (iii) precipitating the polyurethane in the modified textile component. And a synthetic leather formed by the process.

Provided are a process, the process includes (i) first, contacting a textile with an aqueous solution containing a cationic hydroxyethylcellulose polymer to form a modified textile component; (ii) subsequently, impregnating the modified textile component with an aqueous polyurethane dispersion externally stabilized with an anionic surfactant, the aqueous polyurethane dispersion including a second surfactant; and (iii) precipitating the polyurethane in the modified textile component. Also disclosed are a synthetic leather produced by the process.

The present invention is to provide a method for manufacturing synthetic leather in which, after obtaining a thickened liquid by adding a thickening agent (B) with an oxyethylene group content of 2×10.sup.−2 mol/g or less to an aqueous urethane resin composition containing an aqueous urethane resin (A) having an acid value of 0.01 mgKOH/g or higher in a range of 0.01 to 30 parts by mass relative to 100 parts by mass of the aqueous urethane resin (A), the thickened liquid is coated on a base and coagulated with a coagulating agent (C) containing a metal salt (c-1). As the thickening agent, it is preferable to use one or more kinds of thickening agent that is selected from the group consisting of a cellulose thickening agent, an acryl thickening agent, and a urethane thickening agent. Furthermore, as the metal salt (c-1), calcium nitrate is preferable.

A synthetic leather is lightweight and highly durable to abrasion, and a foamed resin layer can give the synthetic leather. The foamed resin layer includes a poly(vinyl chloride) resin and a thermoplastic polyurethane elastomer. The thermoplastic polyurethane elastomer preferably has a Shore A hardness of 50 to 80. The foamed resin layer preferably has an apparent density of 0.3 to 0.7 g/cm.sup.3. The foamed resin layer preferably has an average cell size of 50 to 250 m.