Dyes of formula (1)

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their production and their use.

Dyes of formula (1)

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their production and their use.

Methods for coloration of substrates, including textiles, by plasma polymerization of dyes to which polymerizable moieties have been chemically bonded at sites on the dye capable of bonding to such moieties, and that have been deposited on at least one surface of the substrate, are described. Atmospheric pressure plasmas were used for the polymerization process. Generally, the plasma polymerization is performed away from the dye deposition so that undeposited dye is not exposed to the plasma. Textiles may include cotton, polyester, wool, silk, acrylics, polypropylene, polyolefins, aramids, and nylon, and blends thereof. The plasma-polymerizable moiety may be chosen from acrylates, methacrylates, and vinyl amides. Dye functional groups may include hydroxyl groups, carboxyl groups, amines: primary, secondary, and tertiary, epoxides, carboxylic acids, and chlorides, and dyes may include acid dyes, disperse dyes, azo dyes, vat dyes, sulfur dyes, direct dyes, reactive dyes, basic dyes, pigment dyes, aniline dyes, anthraquinone dyes, and coumarin dyes, as examples.

Provided are a compound represented by Formula 1, a tautomer of the compound or a salt of the compound or the tautomer, a coloring composition and a dyed article containing the compound represented by Formula 1, the tautomer of the compound, or the salt of the compound or the tautomer, and a dyeing method using the compound represented by Formula 1, the tautomer of the compound, or the salt of the compound or the tautomer. In Formula 1, X, R, Ar, n, and m1 are as defined in the specification.

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A colored dispersion that contains (A) C.I. Disperse Orange 25, (B) a specific dye such as C.I. Disperse Orange 49, 62, 71, 73, or 148, and water. When the total (A) C.I. Disperse Orange 25 and (B) specific dye content of the colored dispersion is 100 parts by mass, the (B) specific dye content of the colored dispersion is less than 20 parts by mass. A recording medium to which the colored dispersion has been adhered and a textile printing method for hydrophobic fibers that uses the colored dispersion.

A colored dispersion that contains (A) C.I. Disperse Orange 25, (B) a specific dye such as C.I. Disperse Orange 49, 62, 71, 73, or 148, and water. When the total (A) C.I. Disperse Orange 25 and (B) specific dye content of the colored dispersion is 100 parts by mass, the (B) specific dye content of the colored dispersion is less than 20 parts by mass. A recording medium to which the colored dispersion has been adhered and a textile printing method for hydrophobic fibers that uses the colored dispersion.

A compound represented by the Formula (1), in which, in the Formula (1), R.sup.1 and R.sup.2 each independently represent an alkyl group having 1 to 12 carbon atoms, and the alkyl group having 1 to 12 carbon atoms may have a substituent; R.sup.3 represents a halogen atom, a nitro group, a cyano group, an alkoxycarbonyl group having 2 to 12 carbon atoms, or an acyl group having 2 to 12 carbon atoms; and R.sup.1 and R.sup.2 may be bonded to each other to form a ring, is provided.

A compound represented by the Formula (1), in which, in the Formula (1), R.sup.1 and R.sup.2 each independently represent an alkyl group having 1 to 12 carbon atoms, and the alkyl group having 1 to 12 carbon atoms may have a substituent; R.sup.3 represents a halogen atom, a nitro group, a cyano group, an alkoxycarbonyl group having 2 to 12 carbon atoms, or an acyl group having 2 to 12 carbon atoms; and R.sup.1 and R.sup.2 may be bonded to each other to form a ring, is provided.

An ink jet ink composition for textile printing including a dye and 5% to 30% by mass of a cyclic amide that is liquid at normal temperature and that has a normal boiling point in the range of 190 C. to 260 C., wherein the hue angle h defined by the CIELAB color space on a recording medium ranges from 15 to 80 degrees.

An ink jet ink composition for textile printing including a dye and 5% to 30% by mass of a cyclic amide that is liquid at normal temperature and that has a normal boiling point in the range of 190 C. to 260 C., wherein the hue angle h defined by the CIELAB color space on a recording medium ranges from 15 to 80 degrees.