A black ink composition for inkjet printing that contains a water-soluble organic solvent, a resin emulsion, a dispersing agent, and at least four types of sublimation dyes. At least three of the sublimation dye types are C.I. disperse yellow, C.I. disperse red, and C.I. disperse blue, and at least one of the sublimation dye types has a maximum absorption wavelength in the wavelength band of 640 nm to less than 680 nm as measured from a visible spectral absorption of a solution obtained by dissolving the dye in acetone. An ink set for inkjet printing that includes the black ink composition for inkjet printing, and a method for printing on hydrophobic fibers that uses the composition and the ink set.

A black ink composition for inkjet printing that contains a water-soluble organic solvent, a resin emulsion, a dispersing agent, and at least four types of sublimation dyes. At least three of the sublimation dye types are C.I. disperse yellow, C.I. disperse red, and C.I. disperse blue, and at least one of the sublimation dye types has a maximum absorption wavelength in the wavelength band of 640 nm to less than 680 nm as measured from a visible spectral absorption of a solution obtained by dissolving the dye in acetone. An ink set for inkjet printing that includes the black ink composition for inkjet printing, and a method for printing on hydrophobic fibers that uses the composition and the ink set.

A printing method includes selecting a dye sublimation ink, having: a disperse dye colorant dispersion; a primary solvent selected from the group consisting of glycerol, ethoxylated glycerol, 2-methyl-1,3-propanediol, dipropylene glycol, and combinations thereof; a surfactant selected from the group consisting of nonionic surfactants, anionic surfactants, and combinations thereof; an additive selected from the group consisting of a buffer, a biocide, a chelating agent, and combinations thereof; and a balance of water. An operating energy that includes a margin over a turn-on energy (TOE) for a thermal inkjet printhead is applied to a heating resistor of the printhead, wherein the margin ranges from about 10% to about 25% over the TOE. The dye sublimation ink is printed from the thermal inkjet printhead i) directly onto a textile substrate, or ii) onto a transfer medium to form an image thereon; and the image is transferred onto the textile substrate.

A printing method includes selecting a dye sublimation ink, having: a disperse dye colorant dispersion; a primary solvent selected from the group consisting of glycerol, ethoxylated glycerol, 2-methyl-1,3-propanediol, dipropylene glycol, and combinations thereof; a surfactant selected from the group consisting of nonionic surfactants, anionic surfactants, and combinations thereof; an additive selected from the group consisting of a buffer, a biocide, a chelating agent, and combinations thereof; and a balance of water. An operating energy that includes a margin over a turn-on energy (TOE) for a thermal inkjet printhead is applied to a heating resistor of the printhead, wherein the margin ranges from about 10% to about 25% over the TOE. The dye sublimation ink is printed from the thermal inkjet printhead i) directly onto a textile substrate, or ii) onto a transfer medium to form an image thereon; and the image is transferred onto the textile substrate.

The present invention relates to a method of colouring polymer substrates at low temperatures. The method comprises subjecting the polymer substrate that is to be coloured to a colouring liquor comprising a solvent in which the colourant has a high solubility and then adding a solvent in which the colourant has a low solubility, typically water.