A textile material comprises a plurality of yarns, the yarns containing an intimate blend of dyed polyphenylene sulfide fibers and cellulosic fibers. The dyed polyphenylene sulfide fibers comprising a disperse dye that is distributed substantially evenly across the cross-sectional area of the fibers. A method for dyeing textile materials containing polyphenylene sulfide fibers comprises the steps of (a) providing a textile material comprising yarns which contain an intimate blend of polyphenylene sulfide fibers and cellulosic fibers, (b) providing a dye liquor comprising a liquid medium and a disperse dye, (c) applying the dye liquor to the textile material, (d) heating the textile material under ambient atmosphere to a temperature sufficient to evaporate substantially all of the liquid medium from the textile material, and (e) heating the textile material under ambient atmosphere to a temperature of about 180° C. or more to fix the disperse dye to the polyphenylene sulfide fibers.

A colored resin particle dispersion containing colored resin particles and water, in which the colored resin particles contain an oil-soluble dye and a polymer P containing a structural unit represented by Formula (1), a structural unit represented by Formula (2), and a hydrophilic group, an ink, an ink set, and an inkjet printing method. L.sup.1 represents a chain hydrocarbon group having 4 to 10 carbon atoms, two *1's each represent a bonding position, L.sup.2 represents a chain hydrocarbon group having 2 to 25 carbon atoms which may contain an oxygen atom or the like, or a polymer chain having a number-average molecular weight of 500 or greater, Y.sup.1 and Y.sup.2 each independently represent —O—, —S—, or, —NRz-, Rz represents a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms, and two *2's each represent a bonding position.

##STR00001##

Disclosed is an environmentally friendly method that enables the pre-treatment and dyeing processes applied to cellulosic products used in the production of textile products such as towels, bathrobes to be carried out in a single bath with natural, biological preparations.

The present invention relates to a colorant mixture comprising (A) at least one blue- or black-dyeing disperse dye of formula ##STR00001## wherein R.sub.1 denotes hydrogen or halogen, R.sub.2 and R.sub.3 are each independently of the other hydrogen; C.sub.1-C.sub.8-alkyl which is unsubstituted or substituted with hydroxy, cyano, C.sub.1-C.sub.4alkoxy or halogen; —(CH.sub.2).sub.n—O—(CH.sub.2).sub.mR.sub.4, wherein R.sub.4 denotes hydrogen or C.sub.1-C.sub.8-alkyl, n is a number from 2 to 6 and m is a number from 0 to 6; C.sub.5-C.sub.24aryl which is unsubstituted or substituted with hydroxy, carboxy, cyano, C.sub.1-C.sub.8alkyl, C.sub.1-C.sub.4alkoxy or halogen; or C.sub.6-C.sub.30aralkyl which is unsubstituted or substituted with hydroxy, cyano, C.sub.1-C.sub.4alkyl, C.sub.1-C.sub.8alkoxy groups or halogen; and (B) at least one yellow-, orange- or red-dyeing disperse dye, solvent dye, vat dye or pigment; and to the use thereof in dyeing or printing cellulose or cellulose blend fibre materials.

The present invention relates to a colorant mixture comprising

(A) at least one blue- or black-dyeing disperse dye of formula

##STR00001## wherein R.sub.1 denotes hydrogen or halogen, R.sub.2 and R.sub.3 are each independently of the other hydrogen; C.sub.1-C.sub.8-alkyl which is unsubstituted or substituted with hydroxy, cyano, C.sub.1-C.sub.4alkoxy or halogen; —(CH.sub.2).sub.n—O—(CH.sub.2).sub.mR.sub.4, wherein R.sub.4 denotes hydrogen or C.sub.1-C.sub.8-alkyl, n is a number from 2 to 6 and m is a number from 0 to 6; C.sub.5-C.sub.24aryl which is unsubstituted or substituted with hydroxy, carboxy, cyano, C.sub.1-C.sub.8alkyl, C.sub.1-C.sub.4alkoxy or halogen; or C.sub.6-C.sub.30aralkyl which is unsubstituted or substituted with hydroxy, cyano, C.sub.1-C.sub.4alkyl, C.sub.1-C.sub.8alkoxy groups or halogen; and

(B) at least one yellow-, orange- or red-dyeing disperse dye, solvent dye, vat dye or pigment; and to the use thereof in dyeing or printing cellulose or cellulose blend fibre materials.

The invention relates to a process for printing cellulose textile fibre material or cellulose/polyester mixed textile fibre material, characterised in that the fibre material is treated with a printing paste or printing ink containing a disperse dye of the formula ##STR00001##
wherein
R.sub.1-R.sub.3 are each independently of the other hydrogen, halogen, C.sub.1-C.sub.8-alkyl or C.sub.1-C.sub.8-alkoxy,
R.sub.4 denotes hydrogen, C.sub.1-C.sub.8-alkyl or a group of the formula —SO.sub.2—NR.sub.6R.sub.7,
wherein R.sub.6 and R.sub.7 each independently of the other denote hydrogen,
C.sub.1-C.sub.8-alkyl which is unsubstituted or substituted by hydroxy, halogen, C.sub.1-C.sub.8-alkoxy or C.sub.6-C.sub.24aryl, or
C.sub.6-C.sub.30aralkyl which is unsubstituted or substituted by hydroxy, C.sub.1-C.sub.8alkyl, C.sub.1-C.sub.8alkoxy or halogen,
R.sub.5 represents hydrogen, C.sub.1-C.sub.8-alkyl or a radical of the formula ##STR00002##
wherein R.sub.1-R.sub.4 are as defined above.

The invention relates to a process for printing cellulose textile fibre material or cellulose/polyester mixed textile fibre material, characterised in that the fibre material is treated with a printing paste or printing ink containing a disperse dye of the formula

##STR00001##

wherein
R.sub.1-R.sub.3 are each independently of the other hydrogen, halogen, C.sub.1-C.sub.8-alkyl or C.sub.1-C.sub.8-alkoxy,
R.sub.4 denotes hydrogen, C.sub.1-C.sub.8-alkyl or a group of the formula SO.sub.2NR.sub.6R.sub.7,
wherein R.sub.6 and R.sub.7 each independently of the other denote hydrogen,
C.sub.1-C.sub.8-alkyl which is unsubstituted or substituted by hydroxy, halogen, C.sub.1-C.sub.8-alkoxy or C.sub.6-C.sub.24aryl, or
C.sub.6-C.sub.30aralkyl which is unsubstituted or substituted by hydroxy, C.sub.1-C.sub.8alkyl, C.sub.1-C.sub.8alkoxy or halogen,
R.sub.5 represents hydrogen, C.sub.1-C.sub.8-alkyl or a radical of the formula

##STR00002##

wherein R.sub.1-R.sub.4 are as defined above.

Disclosed is an environmentally friendly method that enables the pre-treatment and dyeing processes applied to cellulosic products used in the production of textile products such as towels, bathrobes to be carried out in a single bath with natural, biological preparations.

A textile material comprises a plurality of yarns, wherein the yarns contain an intimate blend of dyed polyphenylene sulfide fibers and cellulosic fibers. The dyed polyphenylene sulfide fibers comprise a disperse dye that is distributed substantially evenly across the cross-sectional area of the fibers. A method for dyeing textile materials containing polyphenylene sulfide fibers comprises the steps of (a) providing a textile material comprising yarns which contain an intimate blend of polyphenylene sulfide fibers and cellulosic fibers, (b) providing a dye liquor comprising a liquid medium and a disperse dye, (c) applying the dye liquor to the textile material, (d) heating the textile material under ambient atmosphere to a temperature sufficient to evaporate substantially all of the liquid medium from the textile material, and (e) heating the textile material under ambient atmosphere to a temperature of about 180? C. or more to fix the disperse dye to the polyphenylene sulfide fibers.

A colored resin particle dispersion containing colored resin particles and water, in which the colored resin particles contain an oil-soluble dye and a polymer P containing a structural unit represented by Formula (1), a structural unit represented by Formula (2), and a hydrophilic group, an ink, an ink set, and an inkjet printing method. L.sup.1 represents a chain hydrocarbon group having 4 to 10 carbon atoms, two *1's each represent a bonding position, L.sup.2 represents a chain hydrocarbon group having 2 to 25 carbon atoms which may contain an oxygen atom or the like, or a polymer chain having a number-average molecular weight of 500 or greater, Y.sup.1 and Y.sup.2 each independently represent O, S, or, NRz-, Rz represents a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms, and two *2's each represent a bonding position. ##STR00001##