A metallic or metallized reinforcer has at least a surface of which is at least partially metallic, the at least partially metallic surface being coated with a polybenzoxazine sulfide whose repeating units include at least one unit corresponding to formula (I) or (II): ##STR00001##
in which the two oxazine rings are connected together via a central aromatic group, the benzene ring of which bears one, two, three or four groups of formula —S.sub.x—R in which “x” is an integer from 1 to 8 and R represents hydrogen or a hydrocarbon-based group including 1 to 10 carbon atoms and optionally a heteroatom chosen from O, S, N and P. Such a reinforcement can be used for the reinforcement of a rubber article, in particular a motor vehicle tire.

A tire includes a belt layer in a tread portion. The belt layer includes at least one belt ply. The belt ply includes a plurality of belt cords including a steel single wire having a flat cross-sectional shape. In at least one of the belt cords, the steel single wire has a short diameter direction inclined at an angle θ of less than 90 degrees with respect to a thickness direction of the belt ply.

Provided are a rubber article reinforcing steel wire that is superior in bending fatigue properties to the related art and has a flat cross-sectional shape, and a rubber article using the wire. In a rubber article reinforcing steel wire 10, a major diameter and a minor diameter are substantially perpendicular to each other. Assuming that the major diameter is W, the minor diameter is T, a straight line that passes through a center of the major diameter in a width direction and is parallel to a minor diameter direction is L1, a straight line that passes through a center of the minor diameter in a width direction and is parallel to a major diameter direction is L2, an intersection point of the L1 and the L2 is a center point C, a region within a half of a distance from the center point C to a surface is a central region Rc, and a region outside the central region Rc is a surface layer region Rs, a Vickers hardness Hvc of the central region Rc is more than a Vickers hardness Hvs of the surface layer region Rs; and assuming that a Vickers hardness on the L1 in the surface layer region Rs is Hv1, and a Vickers hardness on the L2 in the surface layer region Rs is Hv2, relationships represented by Hvc−Hv1≦150, Hvc−Hv2≦150, Hv1/Hvc×100≧85.11, and Hv2/Hvc×100≧79.84 are satisfied.

At least a metallic part of a metal or metallized reinforcer, at least the surface of which is at least partially metallic, is coated with a polybenzoxazine, the repeat units of which comprise at least one unit corresponding to the formulae (I) or (II): ##STR00001##
in which Z.sub.1 represents an at least divalent, aliphatic, cycloaliphatic or aromatic bonding group comprising at least one carbon atom and optionally at least one heteroatom selected from O, S, N and P; X.sub.1 and X.sub.2, which are identical or different, represent O or S; Ar.sub.1 and Ar.sub.2, which are identical or different, represent a substituted or unsubstituted phenylene group; and Z.sub.2 represents O or (S).sub.n, the symbol “n” representing an integer equal to 1 or greater than 1. Such a reinforcement can be used for the reinforcement of a rubber article, in particular a motor vehicle tyre.

Provided are: an elastomer-metal cord composite which can improve various performance of a tire, such as steering stability, corrosion propagation resistance, and belt layer separation resistance; and a tire including the same. In an elastomer-metal cord composite (10), a metal cord (2) composed of a bundle of plural metal filaments (1) that are arranged in a single row without being twisted together is coated with an elastomer (3). A gap is provided between adjacent metal filaments, and when the diameter of the metal filaments is defined as D (mm), a gap amount, which is a distance between the surfaces of the adjacent metal filaments that is measured in a direction orthogonal to an extending direction of the metal cord, is defined as G (mm), and the number of metal filaments constituting the metal cord is defined as N (filaments), the elastomer-metal cord composite (10) satisfies a relationship expressed by the following Formula (1): 0.45≤[(D/2).sup.2×π×N]/{D×[D×N+G×(N−1)]}≤0.77 (1) wherein, D and G>0, and N is an integer.

Ultra-High-Strength (UHS) wires are suited to high strength wire, strands, cables and rope applications including robotics force transmission and other high-performance mono- and multifilament wire applications. The wires exhibit high strength, low stretch and fatigue durability. Exemplary UHS materials include binary molybdenum-rhenium or tungsten-rhenium alloys with between 20 and 50 wt. % rhenium. These alloys are processed from a moderate strength (<2 GPa) warm-drawn rod to drawn monofilament wire with extreme nanocrystalline grain refinement, high apparent fatigue durability, and ultimate strength levels exceeding 5 GPa in all cases, and up to 6.8 GPa at monofilament diameters ranging from 7 to 100 μm.

A steel wire having a flat shape in a cross-section perpendicular to a longitudinal direction, wherein an outer shape of the cross-section includes a first straight portion, a second straight portion arranged opposite to the first straight portion, and a first curved portion and a second curved portion that connect the first straight portion to the second straight portion, wherein the first curved portion is arranged opposite to the second curved portion, and wherein a ratio of W1 to W2 is 75% or less, where W1 is an average value of a length of the first straight portion and a length of the second straight portion, and W2 is a maximum distance between the first curved portion and the second curved portion.

A plurality of belt layers 7 are superimposed in a radial direction. The belt layers 7 include a plurality of steel cords 10 arranged in parallel in a row and rubber 11. The steel cords 10 have a 1×4 structure in which four filaments 20 are twisted, and when a center-to-center distance between the steel cords 10 in at least two of the belt layers 7 adjacent in the radial direction is T, and an average diameter of virtual circumscribed circles of the steel cords 10 having the 1×4 structure is D, 1.25≤T/D≤2.25.

A steel wire having a cross section perpendicular to a longitudinal direction having a flat shape, and an outer shape of the cross section including a pair of linear parts opposing each other, and a pair of curved parts opposing each other and connecting the linear parts. The curved part includes a pair of first regions located at positions near the linear parts, and a second region located at a position between the pair of first regions, a radius of curvature, R.sub.1 of the first region is greater than or equal to 0.05 mm but less than 0.15 mm, and a radius of curvature, R.sub.2 of the second region is greater than or equal to 0.13 mm but less than or equal to 0.2 mm, and an angle between the linear part and the curved part is greater than or equal to 165 degrees.

Disclosed are a cable bead and a tire. The cable bead includes a core wire located at the middle position of the bead and at least one layer of outer winding wires wound around the core wire, each layer of outer winding wires being evenly wounded along the circumferential direction of the core wire, where the cross section of the outer winding wires is a flat surface having a major axis and a minor axis; the major axis is perpendicular to the radial direction of the cross section of the bead, and the minor axis is parallel to the radial direction of the cross section of the bead; the outer winding wires are in surface contact with the core wire; and when there are at least two layers of outer winding wires, a line contact is formed between the layers of outer winding wires.