A high efficiency bleaching method for cellulosic pulp includes: (a) providing a charge of aqueous cellulosic pulp to a bleaching vessel at a consistency of from 10% to 30% along with a peroxy bleaching agent and an alkaline agent effective to adjust pH of the charge to 9.5 to 12.5; and (b) bleaching the aqueous cellulosic pulp in the bleaching vessel while maintaining a bleaching temperature of from 110° F. (43° C.) to 135° F. (57° C.) and a pH of the charge from 9.5 to 12.5 for an extended bleaching retention time. The bleaching method is advantageously used to bleach low brightness recycle pulp, and/or as part of a multistage process with bleaching stages of lesser duration, and/or as a high peroxy efficiency, low dose bleaching process or in connection with concurrently storing and bleaching pulp.

This disclosure relates to methods of making novel dissolving wood pulps by processes comprising acid prehydrolysis, pulping, and a multi-stage bleaching process comprising oxidation with a catalyst and peroxide under acidic conditions, as well as to products made therefrom having a combination of medium-purity, low viscosity, and improved reactivity, filterability, and/or clogging that can be used as a substitute for traditional high-purity dissolving pulps in a wide variety of applications.

The present application relates to a method for preparing dissolving pulp by TCF bleaching of poplar KP, including: preparing poplar KP by pre-hydrolysis kraft process with poplar as a raw material, and OZQP bleaching of the poplar KP to obtain dissolving pulp, wherein O denotes oxygen delignification, Z denotes ozone bleaching, Q denotes chelating treatment, and P denotes hydrogen peroxide bleaching. The dissolving pulp prepared by the same exhibits that all indexes can meet the requirements of excellent products in dissolving pulp industry standard (QB/T4898-2015), and most of the indexes are far superior to those of excellent products, and thus it can completely replace imported dissolving pulp.

In a process/an apparatus for producing bleached cellulose in which a lignin- and cellulose-containing suspension is subjected to at least one process step for oxygen-assisted bleaching in a reactor, such as alkaline oxygen delignification, oxygen-enhanced extraction or oxygen-enhanced peroxide bleaching, the oxygen required for the oxygen-assisted bleaching is supplied to the reactor at least partially in the form of oxygen-containing nanobubbles. The small size and high stability of the nanobubbles allow uniform distribution of the oxygen in the suspension and a comparatively long exposure time. The efficiency of the bleaching is thus substantially increased.

In some embodiments, a method may include treating pulp. The method may include contacting a wood pulp with a singlet oxygen source. The method may include contacting the wood pulp with an alkaline peroxide source. The singlet oxygen source may include a peracetate oxidant solution and generating a reactive oxygen species. The peracetate oxidant solution may include peracetate anions and a peracid. In some embodiments, the peracetate solution may include a pH from about pH 10 to about pH 12. In some embodiments, the peracetate solution has a molar ratio of peracetate anions to peracid ranging from about 60:1 to about 6000:1. In some embodiments, the peracetate solution has a molar ratio of peracetate to hydrogen peroxide of greater than about 16:1. The peracetate oxidant solution may provide enhanced treatment methods of bleaching, brightening, and delignifying pulp fibers involving the use of peracetate oxidant solutions.

A high efficiency bleaching method for cellulosic pulp includes: (a) providing a charge of aqueous cellulosic pulp to a bleaching vessel at a consistency of from 10% to 30% along with a peroxy bleaching agent and an alkaline agent effective to adjust pH of the charge to 9.5 to 12.5; and (b) bleaching the aqueous cellulosic pulp in the bleaching vessel while maintaining a bleaching temperature of from 110° F. (43° C.) to 135° F. (57° C.) and a pH of the charge from 9.5 to 12.5 for an extended bleaching retention time. The bleaching method is advantageously used to bleach low brightness recycle pulp, and/or as part of a multistage process with bleaching stages of lesser duration, and/or as a high peroxy efficiency, low dose bleaching process or in connection with concurrently storing and bleaching pulp.

In a process for producing bleached mechanical woodpulp, said process comprising the steps of a) delaminating comparatively large particles of wood, which have optionally been pretreated with chemicals and/or water, into modified particles of wood, b) grinding the modified particles of wood from a) in one or more refiners, c) optionally treating the stalk obtained in step b) with oxidative or reductive bleaching agents, a composition Z is present during step a) and/or step b), said composition Z comprising one or more of the following components (Z1) to (Z3): a salt of dithionous acid H.sub.2S.sub.2O.sub.4 (Z1), a dithionous acid or dithionous acid derivative generator compound (Z2), a salt of sulfurous acid (sulfite) plus sodium tetraborohydride (Z3) and also optionally additives (Z4).

This disclosure relates to methods of making novel dissolving wood pulps by processes comprising acid prehydrolysis, pulping, and a multi-stage bleaching process comprising oxidation with a catalyst and peroxide under acidic conditions, as well as to products made therefrom having a combination of medium-purity, low viscosity, and improved reactivity, filterability, and/or clogging that can be used as a substitute for traditional high-purity dissolving pulps in a wide variety of applications.

The present disclosure belongs to the technical field of papermaking, and specifically relates to a short-sequence ECF bleaching process X/Z/D-E.sub.OP-D or X/D/Z-E.sub.OP-D for kraft wood pulp, comprising the following steps: (1) sequential bleaching (X/Z/D or X/D/Z): subjecting an oxygen delignified wood pulp to X/Z/D.sub.1 or X/D.sub.1/Z sequential bleaching to prepare a semi-bleached pulp; (2) reinforced alkaline extraction treatment (E.sub.OP): performing hydrogen peroxide and oxygen enhanced alkaline extraction treatment on the pulp after sequential bleaching to further dissolve the residual lignin in the pulp; (3) supplemental bleaching (D): performing a chlorine dioxide supplemental bleaching on the pulp after the enhanced alkaline extraction treatment to obtain a fully bleached pulp (88% ISO).

The present invention relates to a method for bleaching an unbleached or pre-bleached paper pulp comprising at least the following consecutive steps: a) preparing an unbleached or pre-bleached paper pulp having a pH of at least 8, b) bringing the paper pulp obtained at the end of step a) into contact with chlorine dioxide, c) when the pH of the paper pulp obtained from step b) is lower than 10, adding at least one Brønsted base to the paper pulp, d) adding hydrogen peroxide to the paper pulp obtained at the end of step c), e) maintaining the paper pulp obtained at the end of step d) in a first bleaching tower, f) optionally, adding sulphuric acid to the paper pulp obtained at the end of step e) and maintaining the obtained paper pulp in a second bleaching tower, the method dispensing with the need for a step of washing the paper pulp before the end of step e), and, if applicable, before the end of step f).