A paperboard structure including a paperboard substrate having a first major side and a second major side, a barrier coating layer on the first major side of the paperboard substrate, a top coat on the first major side of the paperboard substrate, wherein the barrier coating layer is positioned between the paperboard substrate and the top coat, and the paperboard structure providing a blocking rate of less than 2 at 50° C. and at 60 psi in a 24-hour period.

The present invention relates to an aqueous barrier coating composition comprising: 50-99.9% by weight of one or more anionic low molecular weight polysaccharide(s) having a degree of polymerization (DP) in the range of 2-12; 0.1-10% by weight of a polycationic polymer; based on the total dry weight of the aqueous barrier coating composition.

An example of a coating composition includes an inorganic pigment, a latex, a cationic fixing agent, and a stabilizer selected from the group consisting of ethopropoxylated polyarylphenol, ethoxylated tristyrylphenol, modified fatty alcohol polyglycol ethers, and combinations thereof. Another example of a coating composition consists essentially of an inorganic pigment, a latex, a cationic fixing agent, a stabilizer selected from the group consisting of ethopropoxylated polyarylphenol, ethoxylated tristyrylphenol, modified fatty alcohol polyglycol ethers, and combinations thereof, and water.

Inorganic particulate compositions containing inorganic particles associated with a copolymer of a hydrophilic monomer and a hydrophobic monomer associated with the inorganic particles are provided. The particulate composition satisfies at least one of the following properties: a BET surface area of the inorganic particles is greater than 8 m.sup.2/g, a Hegman value of the inorganic particles is 75 microns or less, and a rate of water loss from the composition upon drying from a moisture level greater than 2% wt % is at least 30% greater than a composition having a corresponding content of a polyacrylate polymer associated with the particles. A method to prepare the composition and formulations for inks, paints, coatings and filled polymeric articles containing the inorganic particulate composition are also provided.

Inorganic particulate compositions containing inorganic particles associated with a copolymer of a hydrophilic monomer and a hydrophobic monomer associated with the inorganic particles are provided. The particulate composition satisfies at least one of the following properties: a BET surface area of the inorganic particles is greater than 8 m.sup.2/g, a Hegman value of the inorganic particles is 75 microns or less, and a rate of water loss from the composition upon drying from a moisture level greater than 2% wt % is at least 30% greater than a composition having a corresponding content of a polyacrylate polymer associated with the particles. A method to prepare the composition and formulations for inks, paints, coatings and filled polymeric articles containing the inorganic particulate composition are also provided.

A coated paper or paperboard structure includes a paper or paperboard substrate and a basecoat applied to the paper or paperboard substrate to yield a basecoat outer surface. The basecoat includes a water-soluble polymer binder and pigment.

The present invention relates to a water-resistant mineral-coated cellulose-based substrate, comprising a cellulose-based substrate, and a mineral-coating layer disposed on at least one surface of said substrate, said mineral coating comprising 50-95 wt % of a particulate mineral and 5-50 wt % of a water-dispersible binder based on the total dry weight of the mineral coating, and wherein said mineral-coating layer has been subjected to grafting with a fatty acid halide. The invention further relates to a method for manufacturing the water-resistant mineral-coated cellulose-based substrate.

The present invention relates to a process for producing an aqueous polymer dispersion by free-radically initiated aqueous emulsion polymerization, by polymerizing, in an aqueous medium, (a) 40 to 75 parts by weight of at least one vinylaromatic compound and (b) 24.9 to 59.9 parts by weight of at least one conjugated aliphatic diene (c) 0.1 to 10 parts by weight of at least one monomer comprising acid groups and (d) 0 to 20 parts by weight of at least one other monoethylenically unsaturated monomer, the amounts of the monomers (a) to (d) adding up to 100 parts by weight, in a monomer feed process in the presence of a free-radical initiator, with the proviso that the vinylaromatic compound is metered in under polymerization conditions in a continuous mass flow over a period of at least 120 minutes, the metering of the conjugated aliphatic diene is started at a time at which at least 5% and not more than 30% of the vinylaromatic compound has already been metered in in a continuous mass flow and optionally, the polymerization is initiated in an aqueous polymerization mixture comprising up to 5% of the vinylaromatic compound and comprising no aliphatic diene, and also to the aqueous polymer dispersions produced by the process and to the use of these as a binder, adhesive, sizing agent for fibers, for the production of coatings or for the production of a paper coating slip.

A basecoat including a pigment blend that includes a ground calcium carbonate component and a hyperplaty clay component, wherein the ground calcium carbonate component has a coarse particle size distribution, and wherein the hyperplaty clay component has an average aspect ratio of at least 40:1.

A basecoat including a pigment blend that includes a ground calcium carbonate component and a hyperplaty clay component, wherein the ground calcium carbonate component has a coarse particle size distribution, and wherein the hyperplaty clay component has an average aspect ratio of at least 40:1.