The present disclosure provides methods, devices, systems and kits for producing polymeric microbeads, including lanthanide-encoded microbeads. Among others, the present disclosure provides methods, systems and kits for producing functionalized microbeads that include on their surfaces amphipathic moieties with free reactive groups that remain free and can be used for covalently coupling molecules or moieties of inters to the microbeads.

An improved adhesive composition having increased insulative properties is provided. The adhesive composition having improved insulative properties includes a starch component; an alkaline component; sodium tetraborate; water; and a plurality of expandable microspheres. Products having improved insulation capabilities and methods of making the products having improved insulation capabilities are also provided. The present adhesive and products including the adhesive is environmentally friendly.

An improved adhesive composition having increased insulative properties is provided. The adhesive composition having improved insulative properties includes a starch component; an alkaline component; sodium tetraborate; water; and a plurality of expandable microspheres. Products having improved insulation capabilities and methods of making the products having improved insulation capabilities are also provided. The present adhesive and products including the adhesive is environmentally friendly.

An adhesive composition that improves structural integrity and insulative properties when applied to a cellulosic substrate is provided. The adhesive composition includes a plurality of microspheres and an emulsion-based polymer that has (i) an elastic modulus greater than 0.5 MPa in the range temperature range of 70° C. to 110° C.; (ii) an absolute log(E)/T slope of less than 0.05 in the range temperature range of 70° C. to 110° C.; and (iii) a tan d value less than 0.6 at 90° C.

An adhesive composition that improves structural integrity and insulative properties when applied to a cellulosic substrate is provided. The adhesive composition includes a plurality of microspheres and an emulsion-based polymer that has (i) an elastic modulus greater than 0.5 MPa in the range temperature range of 70° C. to 110° C.; (ii) an absolute log(E)/T slope of less than 0.05 in the range temperature range of 70° C. to 110° C.; and (iii) a tan d value less than 0.6 at 90° C.

An intermediate laminate product includes a first paper layer including lignocellulose fibres, and a dry coating layer applied to one surface of the first paper layer, the coating including expandable microspheres having an expansion temperature (T.sub.E), at least one polysaccharide, and a plasticizing additive which is capable of forming a thermoplastic blend with the polysaccharide. An expanded laminate structure includes the intermediate laminate product and a second paper layer comprising lignocellulose fibres, which is attached to the dry coating by heat lamination. A liquid packaging board includes the expanded laminate structure and a liquid barrier layer. A process for forming the expanded laminate structure includes applying a second paper layer to the coating of the intermediate product at a second temperature (T2), which is above the expansion temperature (T.sub.E) of the microspheres, whereby the microspheres expand, and at which the plasticizing additive causes plasticizing of the polysaccharide, to form a thermoplastic blend.

Discloses is a packaging paper for food having a grammage between 20 g/m.sup.2 and 40 g/m.sup.2, and having a filler content of less than 20 wt. % relative to the weight of the uncoated paper. On at least one side the packaging paper has a coating that contains a vegetable oil encapsulated in a polymer, and also talc and a binder. Both sides of the finished packaging paper have a Cobb 60 value of 14 g/m.sup.2 to 22 g/m.sup.2.

Discloses is a packaging paper for food having a grammage between 20 g/m.sup.2 and 40 g/m.sup.2, and having a filler content of less than 20 wt. % relative to the weight of the uncoated paper. On at least one side the packaging paper has a coating that contains a vegetable oil encapsulated in a polymer, and also talc and a binder. Both sides of the finished packaging paper have a Cobb 60 value of 14 g/m.sup.2 to 22 g/m.sup.2.

A document which may be a security document has a thermochromic coating which may be a thermochromic ink on the substrate of the document. The ink may include several thermochromic materials which transition from various different colors to substantially clear in appearance as the ink is warmed to various temperatures. The combination of the colors of the thermochromic materials can give the document a different color at a number of different temperatures, until the coating is warmed to the highest color change point. When at or above the highest color change temperature, the coating becomes substantially transparent and the printed area assumes the color of the underlying substrate. The coating may also include non-reactive materials of yet another color that mixes with the colors of the thermochromic materials. The document may additionally include printed indicia on the substrate that are masked by the thermochromic materials at certain temperatures, and not masked by the thermochromic materials at other temperatures.

An improved adhesive composition having increased insulative properties is provided. The adhesive composition having improved insulative properties includes a starch component; an alkaline component; sodium tetraborate; water; and a plurality of expandable microspheres. Products having improved insulation capabilities and methods of making the products having improved insulation capabilities are also provided. The present adhesive and products including the adhesive is environmentally friendly.