A method of clearing well casing (3) or tubing from a target region of an oil/gas well (1) borehole is provided. The clearance of the oil/gas well bore hole being achieved by employing chemical agents (9) that consume, weaken or melt the well casing/tubing. In some aspects of the method the well casing is cleared to expose the rock formation within which the well borehole is formed so that the rock formation can be accessed from within the well casing/tubing. In other aspects of the method the removal of inner tubing structures is used to facilitate the unimpaired deployment of repair tools down the well borehole.

A ferromagnetic fluid can be used to provide a temporary barrier in a wellbore. A magnetic sub can generate an electromagnetic field within the wellbore. The ferromagnetic fluid is retained at a desired location within the wellbore by the electromagnetic field. Ferromagnetic particles in the fluid can clump together or settle to form the temporary barrier. A zonal isolation fluid such as a metallic fluid, a cement composition, or a curable resin composition can be introduced on top of the temporary barrier. The zonal isolation fluid can solidify to form a permanent or semi-permanent barrier to provide zonal isolation of different zones of the subterranean formation.

A method of plugging a hydrocarbon well includes deploying a downhole tool to remove at least a portion of a casing at a section of well to be plugged. Deploying a blocking device downhole to block a bottom of the section of well to be plugged. Deploying a plugging material downhole onto the blocking device to fill an area to be plugged. Deploying an exothermic fluid downhole, wherein activation of the exothermic material liquefies the plugging material. Allowing the plugging material and the exothermic fluid to solidify form a cast-in-place plug that fills the section of well to be plugged.

The present invention provides a cartridge (1) for a chemical heater used in down-hole operations. The cartridge (1) comprises a quantity of a chemical reaction heat source (2) wrapped in a temporary coating (3) that is capable of maintaining the shape of the cartridge (1) prior to use but which is consumed during the burn of the heater. The present invention also provides a eutectic/bismuth based alloy well plugging/sealing tool (5). The tool (5) having a tubular heater body (6) with an internal cavity (8) capable of receiving a chemical heat source and a quantity of eutectic/bismuth based alloy (7) provided in thermal communication with the heater body (6) around an outer surface of the heater body (6). The tool has a sleeve (10) provided around an outer surface of the alloy (7), which insulates and/or mechanically protects the alloy (7) down-hole. In this way the sleeve (10) enables the diameter of tool (5) to be reduced whilst maintaining its functionality. In further aspect, the present invention also discloses the provision of a refractory lining (20) on the inner walls of the tubular heater body of chemical heaters, such as the heater (6) used in the eutectic/bismuth based alloy well plugging/sealing tool (5).

A method and apparatus for sealing a well conduit includes moving a plugging tool (21) to a first position in the well conduit, the plugging tool (21) comprising a perforating tool (12) and a hollow mandrel (8) with a heater (8) inside and a meltable material on the outside. The perforating tool (12) is actuated to create openings in the well conduit. The heater (8) is operated to melt or activate the material disposed on an exterior of the mandrel (9). The melted material is allowed to solidify in the conduit to form a plug and to flow into the openings to fill a cross-section of an annular space outside the conduit. A logging tool (2) may thereafter be inserted into the hollow mandrel (9) to check the integrity of the plug.

A wellbore is plugged using a bismuth alloy. The wellbore is arranged so that a liquid bismuth alloy sets with an excess pressure of the plug relative to the borehole fluid pressure along a desired seal height distance.

A method of conditioning a well bore featuring an annulus (50) between a bore-lining tubing (20) and a surrounding bore wall (110) comprises pumping conditioning fluid through an inner tubing (10) located within the bore-lining tubing (20) and into a portion of the well bore containing the bore-lining tubing to affect the temperature of the portion of the well bore containing the bore-lining tubing. The annulus (50) between the bore-lining tubing (20) and the surrounding bore wall (110) is at least partially filled with settable material (54). The affected temperature of the portion of the well bore containing the bore-lining tubing influences the setting of the settable material. For example, heating the bore may accelerate setting of the material, while cooling the bore may retard setting of the material.

Methods of actuating a well tool can include releasing chemical energy from at least one portion of a reactive material, thermally expanding a substance in response to the released chemical energy, and applying pressure to a piston as a result of thermally expanding the substance, thereby actuating the well tool, with these steps being repeated for each of multiple actuations of the well tool. A well tool actuator can include a substance contained in a chamber, one or more portions of a reactive material from which chemical energy is released, and a piston to which pressure is applied due to thermal expansion of the substance in response to each release of chemical energy. A well tool actuator which can be actuated multiple times may include multiple portions of a gas generating reactive material, and a piston to which pressure is applied due to generation of the gas.

A first aspect of the invention provides a gas or oil well tubing having an annular packer mounted thereon, wherein the annular packer is formed from an eutectic alloy. By prefabricating the annular packer on the tubing it can be placed in situ from the outset and thus can be active by melting at any time to form a eutectic seal quickly and easily. An annular packer with by-pass conduits is also provided to enable cement to be pumped past the annular packer when it is in situ. The annular packer is further provided with conduit clearance means to clear cement from within the conduits.

Embodiments of the invention provide methods and composition for stimulating a hydrocarbon-bearing, heavy oil containing formation, a deep oil reservoir, or a tight oil reservoir, whereby exothermic reactants are utilized to generate in-situ steam and nitrogen gas downhole in the formation or the reservoir as an enhanced oil recovery process. An oil well stimulation method is provided, which includes injecting, into the one of the formation and the reservoir, an aqueous composition including an ammonium containing compound and a nitrite containing compound. The method further includes injecting, into the one of the formation and the reservoir, an activator. The activator initiates a reaction between the ammonium containing compound and the nitrite containing compound, such that the reaction generates steam and nitrogen gas, increasing localized pressure and improving oil mobility, in the one of the formation and the reservoir, thereby enhancing oil recovery from the one of the formation and the reservoir.