A method of hydraulic fracturing of an oil producing formation includes the provision of a heating apparatus which is transportable and that has a vessel for containing water. A water stream of cool or cold water is transmitted from a source to a means for increasing the temperature of the cool or cold water, the cool or cold water stream being at ambient temperature. The means for increasing the temperature of the cool or cold water has an inlet that receives cool or cold water from the source and an outlet that enables a discharge of a mix of cool or cold water and the hot water. After mixing in the means for increasing the temperature of the cool or cold water, the water assumes a temperature that is suitable for mixing with chemicals that are used in the fracturing process, such as a temperature of about 40°-120° F.+ (4.4° - 48.9° C.+). An outlet discharges a mix of the cool or cold and hot water to tanks. In the mixing tanks, a proppant and an optional selected chemical or chemicals are added to the water which has been warmed. From the tanks, the water with proppant and optional chemicals is injected into the well for part of the hydraulic fracturing operation.

A method for operating a kerogen-rich unconventional gas reservoir characterized by there being multiple hydraulically-fractured wells drilled thereinto comprises: recovering a methane-containing gas from a first hydraulically-fractured well drilled into the gas reservoir, steam-methane reforming the recovered methane-containing gas to yield a hydrogen gas and an inorganic carbon-containing gas, injecting at least a portion of the hydrogen gas into a second hydraulically-fractured well drilled into the gas reservoir, and injecting at least a portion of the inorganic carbon-containing gas into a third hydraulically-fractured well drilled into the gas reservoir.

A method of hydraulic fracturing of an oil producing formation includes the provision of a heating apparatus which is transportable and that has a vessel for containing water. A water stream of cool or cold water is transmitted from a source to a manifold, the cool or cold water stream being at ambient temperature. The manifold has an inlet that receives cool or cold water from the source and an outlet that enables a discharge of a mix of cool or cold water and the hot water. After mixing in the manifold, the water assumes a temperature that is suitable for mixing with chemicals that are used in the fracturing process, such as a temperature of about 40°-120° F.+(4.4-48.9 C+). An outlet discharges a mix of the cool or cold and hot water to tanks. In the tanks, a proppant and an optional selected chemical or chemicals are added to the water which has been warmed. From the tanks, the water with proppant and optional chemicals is injected into the well for part of the hydraulic fracturing operation.

Methods for creating or enhancing a fracture in a subterranean formation include introducing a pad fluid into a formation at a rate and pressure sufficient to create or enhance at least one fracture therein. The pad fluid can include a pad base fluid, micro-proppant particulates, a gas-generating chemical, and an activator, and wherein either the gas-generating chemical or the activator or both are encapsulated. The methods can include placing the micro-proppant particulates, etc. into the fracture; releasing the activator from its encapsulation; reacting the gas-generating chemical and the activator in the fracture so as to generate gas and heat, thereby creating or enhancing at least one microfracture therein; introducing a fracturing fluid into the formation, wherein the fracturing fluid comprises a fracturing base fluid and macro-proppant particulates and placing the macroproppant particulates into the fracture so as to form a proppant pack therein.

This application relates to systems and methods for stimulating hydrocarbon bearing formations using a hybrid downhole tool that uses a high power laser and chemicals.

Disclosed is a method for extracting shale oil and gas by fracturing, and chemical retorting in oil shale in-situ horizontal well and a process for implementing the method. In the method and process, an inclined well is drilled from the ground to the upper part of an underground oil shale stratum, and a horizontal well is drilled in parallel to the oil shale stratum in the upper part of the oil shale stratum. Behind the horizontal well and the inclined well in the upper part, an inclined well leading to the lower part of the oil shale stratum is drilled, and a horizontal well is drilled in parallel to the lower part of the oil shale stratum. Highly pressurized media are injected into the horizontal well in the upper part of the oil shale stratum.

A silicone polymer is provided, modified with at least one functional group from the class of anthraquinone amide groups; anthraquinone sulfonamide groups; thioxanthone amide groups; or thioxanthone sulfone amide groups. The polymer can be combined with a hydrocarbon solvent or with supercritical carbon dioxide (CO.sub.2), and is very effective for increasing the viscosity of either medium. A process for the recovery of oil from a subterranean, oil-bearing formation is also described, using supercritical carbon dioxide modified with the functionalized silicone polymer. A process for extracting natural gas or oil from a bedrock-shale formation is also described, again using the modified silicone polymer.

Use of supercritical Y-grade natural gas liquids for a variety of processes and across numerous industrial applications is described herein. The low viscosity, high density, and tunable solvent properties of supercritical Y-grade natural gas liquids are useful for example in enhanced reservoir recovery and treatment, control of chemical reactions and processes, and/or single or two-phase separations.

The invention relates to a system for generating superheated steam using hydrogen peroxide, formed by: a container for storing hydrogen peroxide, which stores a solution of peroxide that is used during the reaction to generate superheated steam; a hydrogen peroxide discharge pump connected to a first connecting duct, said discharge pump being used to pump the hydrogen peroxide solution to a reaction container via a second connecting duct; and a steam generating reaction container or reactor, in which the reaction takes place and the superheated steam is generated, said reaction container or reactor receiving the hydrogen peroxide solution in order for the reaction to take place and the superheated steam to be generated and subsequently conveyed through a nozzle and an outlet duct towards installations that are to undergo cleaning and/or stimulation.

Provided is a method and composition for the in-situ generation of synthetic sweet spots in tight-gas formations. The composition can include nitrogen generating compounds, which upon activation, react to generate heat and nitrogen gas. The method of using the composition includes injecting the composition into a tight-gas formation such that upon activation, heat and nitrogen gas are generated. Upon the generation of nitrogen gas and heat within the formation, microfractures are produced within the formation and the hydrostatic pressure within the reservoir is reduced to less than the reservoir fluid pressure, such that the rate of production of hydrocarbons from the formation is increased.