Patent classifications
F01N2330/08
HONEYCOMB STRUCTURE AND EXHAUST GAS PURIFYING DEVICE
A pillar shaped honeycomb structure includes: an outer peripheral wall; and porous partition walls disposed on an inner side of the outer peripheral wall, the partition walls defining a plurality of cells, each of the cells penetrating from one end face to other end face to form a flow path, wherein at least one cell of the cells has a magnetic substance coated with glass.
EXHAUST GAS PURIFICATION CATALYST COMPOSITION AND EXHAUST GAS PURIFICATION CATALYST
An object of the present invention is to provide an exhaust gas purification catalyst composition and an exhaust gas purification catalyst, each of which includes a pyrochlore-type CeO.sub.2—ZrO.sub.2-based complex oxide having an improved oxygen storage capacity (particularly, an improved oxygen storage capacity after being exposed to a high temperature environment), and, in order to achieve the above-mentioned object, the present invention provides an exhaust gas purification catalyst composition and an exhaust gas purification catalyst, each of which contains a pyrochlore-type CeO.sub.2—ZrO.sub.2-based complex oxide that contains Y and Mg and thus exhibits an excellent oxygen storage capacity (particularly, an excellent oxygen storage capacity after being exposed to a high temperature environment).
HONEYCOMB STRUCTURE AND EXHAUST GAS PURIFYING DEVICE
A pillar shaped honeycomb structure including pillar shaped honeycomb segments joined together via joining material layers, wherein each of the pillar shaped honeycomb segment includes: an outer peripheral wall; and a porous partition wall disposed on an inner side of the outer peripheral wall, the partition wall defining a plurality of cells, each of the plurality of cells extending from one end face to other end face to form a flow path, wherein a joining material forming the joining material layers includes magnetic particles, and wherein the joining material contains aggregates, and at least a part of the aggregates comprises the magnetic particles.
HONEYCOMB STRUCTURE AND EXHAUST GAS PURIFYING DEVICE
A pillar shaped honeycomb structure includes: an outer peripheral wall; and a porous partition wall disposed on an inner side of the outer peripheral wall, the partition wall defining a plurality of cells, each of the plurality of cells extending from one end face to the other end face to form a flow path. The partition wall is a porous body containing aggregates and binding materials binding the aggregates. At least a part of the aggregates includes magnetic particles.
Combustion system
A combustion system operated at low cost is provided. A combustion system 1 includes a combustion device 10 that burns fuel, an exhaust line L1 through which exhaust gas flows, the exhaust gas being generated through combustion of the fuel in the combustion device 10, an air preheater 30 that is disposed in the exhaust line L1 and that recovers heat from the exhaust gas, and a denitration device 40 that is disposed in the exhaust line L1 and that removes nitrogen oxide from the exhaust gas using a denitration catalyst. The denitration device 40 is disposed downstream from the air preheater 30 in the exhaust line L1, and the denitration catalyst contains 43 wt % or more of vanadium pentoxide and has a BET specific surface area of 30 m.sup.2/g or more.
Powder for catalysts and catalyst for exhaust gas purification
A catalyst powder according to the present invention is a catalyst powder that includes: a core portion that contains ceria and zirconia; and a surface layer portion that is located on the core portion and contains ceria and zirconia. The ratio (M.sub.2/M.sub.1) is 0.30 or more and 0.95 or less, the ratio (M.sub.2/M.sub.1) being the ratio of a mole fraction M.sub.2 (mol %) of cerium in the surface layer portion measured using X-ray photoelectron spectroscopy to a mole fraction M.sub.1 (mol %) of cerium in the entire powder. It is preferable that the ratio (M.sub.4/2/M.sub.3/1) between M.sub.3/1 and M.sub.4/2 is 1.1 or more and 5.0 or less, wherein M.sub.3/1 (=M.sub.3/M.sub.1) represents the ratio between a mole fraction M.sub.3 (mol %) of zirconium in the entire powder and a mole fraction M.sub.1 (mol %) of cerium in the entirety of the powder, and M.sub.4/2 (=M.sub.4/M.sub.2) represents the ratio between a mole fraction M.sub.4 (mol %) of zirconium measured using X-ray photoelectron spectroscopy and a mole fraction M.sub.2 (mol %) of cerium measured using X-ray photoelectron spectroscopy.
Method for recycling denitration catalyst
There is provided a method for recycling a catalyst that exhibits a high denitration efficiency at a relatively low temperature and does not cause oxidation of SO.sub.2 in a selective catalytic reduction reaction that uses ammonia as a reducing agent. A method for recycling a denitration catalyst includes a step of spraying an aqueous solution with a pH of 7 or more onto a used denitration catalyst while the denitration catalyst is set in a denitration device to remove a surface of the denitration catalyst. The denitration catalyst contains 43 wt % or more of vanadium pentoxide and has a BET specific surface area of 30 m.sup.2/g or more. The denitration catalyst after recycling is used for denitration at 200 C. or lower.
Denitration catalyst and method for producing the same
There is provided a catalyst that exhibits a high denitration efficiency at a relatively low temperature and does not cause oxidation of SO.sub.2 in a selective catalytic reduction reaction that uses ammonia as a reducing agent. A denitration catalyst is obtained by coating a substrate with a catalyst component. The catalyst component contains 43 wt % or more of vanadium pentoxide and has a BET specific surface area of 30 m.sup.2/g or more. The denitration catalyst is used for denitration at 200 C. or lower.
Method for recycling denitration catalyst
There is provided a method for recycling a catalyst that exhibits a high denitration efficiency at a relatively low temperature and does not cause oxidation of SO.sub.2 in a selective catalytic reduction reaction that uses ammonia as a reducing agent. A method for recycling a denitration catalyst includes a step of removing a used denitration catalyst from a denitration device and then coating the used denitration catalyst with a catalyst component. The catalyst component contains 43 wt % or more of vanadium pentoxide and has a BET specific surface area of 30 m.sup.2/g or more, and the denitration catalyst after recycling is used for denitration at 200 C. or lower.
Combustion system for ships
A combustion system for ships operated at low cost is provided. A combustion system 1 for ships includes an internal combustion engine 20 that burns fuel, an exhaust line L2 through which exhaust gas flows, the exhaust gas being generated through combustion of the fuel in the internal combustion engine 20, an exhaust heat recovery device 40 that is disposed in the exhaust line L2 and that recovers exhaust heat from the exhaust gas discharged from the internal combustion engine 20, and a denitration device 50 that is disposed in the exhaust line L2 and that removes nitrogen oxide from the exhaust gas using a denitration catalyst. The denitration device 50 is disposed downstream from the exhaust heat recovery device 40 in the exhaust line L2. The denitration catalyst contains 43 wt % or more of vanadium pentoxide and has a BET specific surface area of 30 m.sup.2/g or more.