Patent classifications
F01N3/2825
Three-zone two-layer TWC catalyst in gasoline waste gas applications
A three-way catalyst article, and its use in an exhaust system for internal combustion engines, is disclosed. The catalyst article for treating exhaust gas comprising: a substrate comprising an inlet end, an outlet end with an axial length L; an inlet catalyst layer beginning at the inlet end and extending for less than the axial length L, wherein the inlet catalyst layer comprises an inlet palladium component; an outlet catalyst layer beginning at the outlet end and extending for less than the axial length L, wherein the outlet catalyst layer comprises an outlet rhodium component; and wherein the outlet catalyst layer overlaps with the inlet catalyst layer.
Selective catalytic reduction catalyst composition
A SCR catalyst composition comprises a SCR catalyst; and a binder comprising a porous inorganic material, wherein the porous inorganic material comprises a disordered arrangement of delaminated layers, has a disordered porous structure, and has a multimodal pore size distribution comprising at least a first modal maximum having a macroporous or mesoporous pore size and a second modal maximum having a microporous pore size. The SCR catalyst composition can be manufactured using the method comprising the steps of: (i) providing an inorganic material having a layered structure; (ii) contacting the material with a cationic surfactant to form a swollen material; (iii) agitating the swollen material to form an agitated material; and (iv) calcining the agitated material to recover a delaminated inorganic material, wherein an SCR catalyst is mixed with the inorganic material prior to step (iv).
Batch compositions comprising pre-reacted inorganic particles and methods of manufacture of green bodies therefrom
Batch compositions containing pre-reacted inorganic spheroidal particles, small amount of fine inorganic particles (“fines”), and an extremely large amount of liquid vehicle. The batch compositions contain pre-reacted inorganic particles having a particle size distribution with 20 μm≤D50≤100 μm, D90≤100 μm, and D5≥10 μm; less than 20 wt % of fine inorganic particles (fines) whose particle distribution(s) have a median diameter of less than 5 μm; and a liquid vehicle in a weight percent (LV %≥28%) by super-addition to all inorganic particles in the batch composition. Fast extruding batch compositions having extremely high Tau Y/Beta ratios are provided. Green bodies, such as green honeycomb bodies and methods of manufacturing green honeycomb bodies are provided, as are other aspects.
EXHAUST TREATMENT APPARATUS AND METHOD
The present invention relates to an exhaust treatment apparatus (1) for an internal combustion engine (5). The apparatus includes a catalyst chamber (15) containing a catalyst (35). One or more exhaust gas inlets (11A-D) are provided for supplying exhaust gases from the internal combustion engine (5) to the catalyst chamber (C). An exhaust gas outlet (21) for supplying exhaust gases from the catalyst chamber to a turbocharger (25). An injection nozzle (19) is provided for introducing a reductant (23) into the exhaust gases between the catalyst (15) and the turbocharger (25). The reductant (23) and the exhaust gases can undergo mixing as they pass through the turbocharger (25). The catalyst (15) can have a three-dimensional open structure to facilitate the flow of exhaust gases. The invention also relates to a method of treating exhaust gases from an internal combustion engine (5).
CATALYZED CERAMIC CANDLE FILTER AND METHOD OF CLEANING PROCESS OFF- OR EXHAUST GASES
Ceramic candle filter and use of the filter in the removal of particulate matter in form of soot, ash, metals and metal compounds, together with hydrocarbons and optionally nitrogen oxides being present in process off-gas or engine exhaust gas, wherein a noble metal comprising catalyst is arranged on the permeation side of the filter and/or on the dispersion side of the filter and/or within wall of the filter, said noble metal comprising catalyst contains a noble metal in an amount of between 20 and 1000 ppm/weight of the filter.
CONTROL METHOD FOR REDUCTANT GENERATION DEVICE, EXHAUST PURIFICATION METHOD, REDUCTANT GENERATION SYSTEM, AND EXHAUST PURIFICATION SYSTEM
A method for controlling a reductant generation device 100, the reductant generation device 100 including: a sprayer 10 capable of spraying a reductant precursor 50; and a heater 20 comprising a ceramic substrate 21, the heater 20 being arranged on a downstream side of the sprayer 10 and capable of heating the reductant precursor 50 to generate a reductant 60. The method includes: a permeation step of spraying the reductant precursor 50 from the sprayer 10 and permeating the ceramic substrate 21 with the reductant precursor 50 when the heater is not heated; and after the permeation step, a heating step A of heating the reductant precursor 50 by the heater 20 and generating the reductant 60 while spraying the reductant precursor 50 from the sprayer 10.
METAL OXIDE-BASED SCR CATALYST COMPOSITION
The present disclosure provides SCR catalyst compositions capable of reducing nitrogen oxide (NO.sub.x) emissions in engine exhaust. The catalyst compositions include a reducible metal oxide support containing ceria, one or more transition metal oxides as a redox promotor; and an oxide of niobium, tungsten, silicon, molybdenum, or a combination thereof as an acidic promotor. The redox promotor and the acid promotor are both supported on the reducible metal oxide support. Further provided are SCR catalyst articles coated with such compositions, processes for preparing such catalyst compositions and articles, an exhaust gas treatment system including such catalyst articles, and methods for reducing NO.sub.x in an exhaust gas stream using such catalyst articles and systems.
A CATALYST ARTICLE FOR CAPTURING PARTICULATE MATTER
The present invention relates to a catalyst washcoat composition comprising a slurry comprising at least one platinum group metal and/or at least one non-platinum group metal supported on at least one support; and at least one pore forming agent having a particle size ranging from 100 nm to 5.0 μm, wherein the pore forming agent is selected from carbon nano-tubes, carbon nano-fibres, activated carbon, resins, cellulose powder, and polymer spheres. The present invention also provides a catalyst article for capturing particulate matter of size ranging from 1.0 nm to 100 μm, said article comprising the catalyst washcoat deposited on a substrate and calcined to form pores of which 50%-100% have a pore size ranging from 100 nm to 5.0 μm.
Exhaust gas purification catalyst
The present invention provides an exhaust gas purification catalyst including an alkaline earth metal supported in a highly dispersed state on a porous carrier. A catalyst layer of the exhaust gas purification catalyst provided by the invention has an alkaline earth metal-supporting region including a porous carrier, a catalyst metal belonging to the platinum group, and a sulfate of at least one type of alkali earth metal supported on the porous carrier. In a cross-section of this region, a Pearson correlation coefficient R.sub.Ae/M is at least 0.5 as calculated using α and β for each pixel obtained by carrying out area analysis by FE-EPMA under conditions of pixel size of 0.34 μm×0.34 μm, and measured pixel number 256×256, and by measuring the characteristic X-ray intensity (α:cps) of the alkaline earth metal element (Ae) and the characteristic X-ray intensity (β:cps) of the main constituent element of the inorganic compound constituting the porous carrier for each pixel.
Heater, method of manufacturing the same, and system
A heater may include: a conductive ceramic cylinder tube in which cell-arrays are concentrically arranged, each cell-array including cells which are arranged in a circumferential direction of the ceramic cylinder tube; an inner electrode electrically coupled to an inner wall portion of the ceramic cylinder tube; and an outer electrode electrically coupled to an outer wall portion of the ceramic cylinder tube. Non-linear portions are radially arranged in the ceramic cylinder tube, each non-linear portion extending in a radial direction of the ceramic cylinder tube while having a plurality of bends or curves between the inner wall portion and outer wall portion of the ceramic cylinder tube. The inner and outer electrodes are provided such that current flows radially at least via said non-linear portions between the inner and outer electrodes.