A small-scale thermoelectric power generator and combustion apparatus, components thereof, methods for making the same, and applications thereof. The thermoelectric power generator can include a burner including a matrix stabilized combustion chamber comprising a catalytically enhanced, porous flame containment portion. The combustion apparatus can include components connected in a loop configuration including a vaporization chamber; a mixing chamber connected to the vaporization chamber; a combustion chamber connected to the vaporization chamber; and a heat exchanger connected to the combustion chamber. The combustion chamber can include a porous combustion material which can include a unique catalytic material.

A scroll heating device includes a base, a reaction region, and a first and a second channel. The reaction region is at the center of the base. The two channels are located on the base and extend spirally from the reaction region toward the periphery of the base. The width of each channel is gradually reduced as the channel extends from adjacent to the center of the base toward the periphery of the base. The first channel allows a gas that flows into the first channel through the periphery of the base toward the center of the base to flow toward the reaction region at a progressively slower rate, enter the reaction region slowly through the gradually widening first channel, and therefore stay in the reaction region for longer. The combusted exhaust enters the second channel from adjacent to the center of the base and exits through the periphery of the base.

A scroll heating device includes a base, a reaction region, and a first and a second channel. The reaction region is at the center of the base. The two channels are located on the base and extend spirally from the reaction region toward the periphery of the base. The width of each channel is gradually reduced as the channel extends from adjacent to the center of the base toward the periphery of the base. The first channel allows a gas that flows into the first channel through the periphery of the base toward the center of the base to flow toward the reaction region at a progressively slower rate, enter the reaction region slowly through the gradually widening first channel, and therefore stay in the reaction region for longer. The combusted exhaust enters the second channel from adjacent to the center of the base and exits through the periphery of the base.

A small-scale thermoelectric power generator and combustion apparatus, components thereof, methods for making the same, and applications thereof. The thermoelectric power generator can include a burner including a matrix stabilized combustion chamber comprising a catalytically enhanced, porous flame containment portion. The combustion apparatus can include components connected in a loop configuration including a vaporization chamber; a mixing chamber connected to the vaporization chamber; a combustion chamber connected to the vaporization chamber; and a heat exchanger connected to the combustion chamber. The combustion chamber can include a porous combustion material which can include a unique catalytic material.