A system for the generation of mechanical or electrical energy from heat energy, where increasing a height or pressure in a liquid chamber of the system containing a liquid increases an efficiency of the system up to a hundred percent or increases such efficiency until a critical temperature or pressure of the vapor (gas) is reached at the bottom of liquid chamber or in the boiler of the system depending upon the increment in height, pressure and the type of liquid used in the system. An increase in height of the system for such increased efficiency can be adjusted to a smaller height by maintaining a series of liquid and gas chambers where the vapor flows through the series of chambers or by adding pressure valves. The heat energy from high to low temperature sources can be convened to mechanical and electrical energy.

Systems related to concentrated solar combination heating and power generation; solar heating; industrial heat driven power generation; thermal storage systems and heat exchanger and power generation systems therefore, including any of the above with optional supplemental fuel production, and associated methods, are generally described.

The invention provides a process for removal of gaseous decomposition products from high temperature heat transfer fluid HTF of an operational solar thermal power plant having an HTF circuit, in which a volume increase of the HTF in the HTF circuit which is caused by incident solar radiation in an HTF-traversed solar field and consequent heating by day takes place regularly in a day-night cycle and the additional volume formed by the volume increase is collected from the HTF circuit in an expansion vessel, a portion of the additional volume of the HTF is transferred into a drainage vessel operated at relatively low pressure in which gaseous decomposition products and low-boiling constituents escape from the HTF, wherein the low-boiling constituents are condensed, and during the volume contraction of the HTF occurring during the night-time cooling a portion of the additional volume of the HTF is recycled from the drainage vessel into the expansion vessel and from the expansion vessel into the HTF circuit, wherein the volumes in the expansion vessel and the drainage vessel becoming vacant as a result of the transferrals of the HTF are filled with inert gas.

The invention provides a process for removal of gaseous decomposition products from high temperature heat transfer fluid HTF of an operational solar thermal power plant having an HTF circuit, in which a volume increase of the HTF in the HTF circuit which is caused by incident solar radiation in an HTF-traversed solar field and consequent heating by day takes place regularly in a day-night cycle and the additional volume formed by the volume increase is collected from the HTF circuit in an expansion vessel, a portion of the additional volume of the HTF is transferred into a drainage vessel operated at relatively low pressure in which gaseous decomposition products and low-boiling constituents escape from the HTF, wherein the low-boiling constituents are condensed, and during the volume contraction of the HTF occurring during the night-time cooling a portion of the additional volume of the HTF is recycled from the drainage vessel into the expansion vessel and from the expansion vessel into the HTF circuit, wherein the volumes in the expansion vessel and the drainage vessel becoming vacant as a result of the transferrals of the HTF are filled with inert gas.

A zero-emission, closed-loop and hybrid solar-produced syngas power cycle is introduced utilizing an oxygen transport reactor (OTR). The fuel is syngas produced within the cycle. The separated oxygen inside the OTR through the ion transport membrane (ITM) is used in the syngas-oxygen combustion process in the permeate side of the OTR. The combustion products in the permeate side of the OTR are CO.sub.2 and H.sub.2O. The combustion gases are used in a turbine for power production and energy utilization then a condenser is used to separate H.sub.2O from CO.sub.2. CO.sub.2 is compressed to the feed side of the OTR. H.sub.2O is evaporated after separation from CO.sub.2 and fed to the feed side of the OTR.

A zero-emission, closed-loop and hybrid solar-produced syngas power cycle is introduced utilizing an oxygen transport reactor (OTR). The fuel is syngas produced within the cycle. The separated oxygen inside the OTR through the ion transport membrane (ITM) is used in the syngas-oxygen combustion process in the permeate side of the OTR. The combustion products in the permeate side of the OTR are CO.sub.2 and H.sub.2O. The combustion gases are used in a turbine for power production and energy utilization then a condenser is used to separate H.sub.2O from CO.sub.2. CO.sub.2 is compressed to the feed side of the OTR. H.sub.2O is evaporated after separation from CO.sub.2 and fed to the feed side of the OTR.