A method for automatically dispensing and vending carbon dioxide (CO2) snow block is disclosed. The automatic dispensing system contains multiple containers of different volumes. A user can input the volume of CO2 snow block into a controller, such as a programmable logic controller (PLC). The controller uses the inputted volume and process information to determine which container to utilize for the automated filling process. The controller can configure the selected container into a filling orientation into which liquid CO2 can flow to generate CO2 snow block. Upon detection of the completion of the fill, the container is configured into a dispensing orientation from which the CO2 snow block is released into an access region from which the user can retrieve the CO2 snow block. The control methodology may also be used to auto charge a single container located within a charging station as disclosed herein.

A method for automatically dispensing and vending carbon dioxide (CO2) snow block is disclosed. The automatic dispensing system contains multiple containers of different volumes. A user can input the volume of CO2 snow block into a controller, such as a programmable logic controller (PLC). The controller uses the inputted volume and process information to determine which container to utilize for the automated filling process. The controller can configure the selected container into a filling orientation into which liquid CO2 can flow to generate CO2 snow block. Upon detection of the completion of the fill, the container is configured into a dispensing orientation from which the CO2 snow block is released into an access region from which the user can retrieve the CO2 snow block. The control methodology may also be used to auto charge a single container located within a charging station as disclosed herein.

Systems and apparatus for providing long-term cold storage of solid materials such as dry ice are disclosed. The solid materials are stored in a tank configured to maintain the materials in their solid state. The tank is designed with a port sufficiently large to facilitate ingress and egress of the solid materials. A cryogenic liquid is used within the tank to substantially prevent the solid materials from sticking to each other, and to maintain the solid materials at a low temperature.

A methane transportation system is provided. The system may include a methane source configured to dispense methane at a first location, and an underwater vehicle. The underwater vehicle may include a propulsion system configured to transport the underwater vehicle underwater from the first location to a second location and a vessel defining a storage chamber configured to receive water and the methane from the methane source. The storage chamber of the vessel may have a pressure exceeding one atmosphere and a temperature during transport from the first location to the second location sufficient to form methane clathrate in the storage chamber. The system may further include a methane receiver configured to receive the methane released from the storage chamber at the second location. Related methods are also provided.

Disclosed are a refueling method and station for supplying one or more energy carriers to vehicles, wherein the refueling station is connected to a road network and thereby accessible to road vehicles, wherein the energy carriers comprise hydrogen, the refueling station having in a hydrogen production unit configured to produce hydrogen (H.sub.2) and carbon (C) from a hydrocarbon compound by at least one processing unit configured to produce the hydrogen and carbon by pyrolysis of the hydrocarbon compound, wherein the refueling station is configured to supply a hydrogen powered vehicle with the produced hydrogen.

A methane transportation system is provided. The system may include a methane source configured to dispense methane at a first location, and an underwater vehicle. The underwater vehicle may include a propulsion system configured to transport the underwater vehicle underwater from the first location to a second location and a vessel defining a storage chamber configured to receive water and the methane from the methane source. The storage chamber of the vessel may have a pressure exceeding one atmosphere and a temperature during transport from the first location to the second location sufficient to form methane clathrate in the storage chamber. The system may further include a methane receiver configured to receive the methane released from the storage chamber at the second location. Related methods are also provided.

Systems and apparatus for providing long-term cold storage of solid materials such as dry ice are disclosed. The solid materials are stored in a tank configured to maintain the materials in their solid state. The tank is designed with a port sufficiently large to facilitate ingress and egress of the solid materials. A cryogenic liquid is used within the tank to substantially prevent the solid materials from sticking to each other, and to maintain the solid materials at a low temperature.

A methane transportation system is provided. The system may include a methane source configured to dispense methane at a first location, and an underwater vehicle. The underwater vehicle may include a propulsion system configured to transport the underwater vehicle underwater from the first location to a second location and a vessel defining a storage chamber configured to receive water and the methane from the methane source. The storage chamber of the vessel may have a pressure exceeding one atmosphere and a temperature during transport from the first location to the second location sufficient to form methane clathrate in the storage chamber. The system may further include a methane receiver configured to receive the methane released from the storage chamber at the second location. Related methods are also provided.

A method for automatically dispensing and vending carbon dioxide (CO2) snow block is disclosed. The automatic dispensing system contains multiple containers of different volumes. A user can input the volume of CO2 snow block into a controller, such as a programmable logic controller (PLC). The controller uses the inputted volume and process information to determine which container to utilize for the automated filling process. The controller can configure the selected container into a filling orientation into which liquid CO2 can flow to generate CO2 snow block. Upon detection of the completion of the fill, the container is configured into a dispensing orientation from which the CO2 snow block is released into an access region from which the user can retrieve the CO2 snow block. The control methodology may also be used to auto charge a single container located within a charging station as disclosed herein.

Systems and apparatus for providing long-term cold storage of solid materials such as dry ice are disclosed. The solid materials are stored in a tank configured to maintain the materials in their solid state. The tank is designed with a port sufficiently large to facilitate ingress and egress of the solid materials. A cryogenic liquid is used within the tank to substantially prevent the solid materials from sticking to each other, and to maintain the solid materials at a low temperature.