The present invention relates to a high pressure process for Pre-Combustion and Post-Combustion CO.sub.2 capture (HP/MP/LP gasification) from a CO.sub.2 gas stream (CO2-Stream) by way of CO.sub.2 total subcritical condensation (CO2-CC), separation of liquid CO.sub.2, higher pressure elevation of obtained liquid CO.sub.2 via HP pump, superheating of CO.sub.2 up to high temperature for driving of a set of CO.sub.2 expander turbines for additional power generation (CO2-PG), EOR or sequestration (First new Thermodynamic Cycle). The obtained liquid CO.sub.2 above, will be pressurized at a higher pressure and blended with HP water obtaining high concentrated electrolyte, that is fed into HP low temperature electrochemical reactor (HPLTE-Syngas Generator) wherefrom the cathodic syngas and anodic oxygen will be performed. In particular the generated HP oxygen/syngas will be utilized for sequential combustion (“H.sub.2/O.sub.2-torches”) for super-efficient hydrogen based fossil power generation (Second new Thermodynamic Cycle).

A combined cooling, heating and power system is formed by integrating a CO.sub.2 cycle subsystem, an ORC cycle subsystem, and an LNG cold energy utilization subsystem based on an SOFC/GT hybrid power generation subsystem. The combined system can achieve efficient and cascade utilization of energy and low carbon dioxide emission. An SOFC/GT hybrid system is used as a prime mover. High-, medium-, and low-temperature waste heat of the system are recovered through CO.sub.2 and ORC cycles, respectively. Cold energy (for air conditioning and refrigeration), heat, power, natural gas, ice, and dry ice can be provided by using LNG as a cold source of the CO.sub.2 and ORC cycles. Low CO.sub.2 emission is achieved by condensation and separation of CO.sub.2 from flue gas, so energy loss of the system can be reduced, and efficient and cascade utilization of energy can be achieved, thereby realizing energy conservation and emission reduction.

A method for transferring thermal energy to a separate endothermic process includes: (a) providing a carbon dioxide (CO.sub.2) stream and a carbonaceous fuel to a heater; (b) reacting the carbonaceous fuel in the heater to produce a heated stream; (c) transferring heat from the heated stream to the separate endothermic process; (d) separating the CO.sub.2 stream from the heated stream after (c); and (e) recycling the CO.sub.2 stream to the heater after (d).

A method for isolating substantially pure carbon dioxide from flue gas is provided. The method can include combusting carbon based fuel to form flue gas; cooling the flue gas to provide substantially dry flue gas; removing N.sub.2 from the dry flue gas to provide substantially N.sub.2 free flue gas CO.sub.2; and liquifying the substantially N.sub.2 free flue gas CO.sub.2 to form substantially pure carbon dioxide.

A thermal oxidizer employing an oxidation mixer, an oxidation chamber, a retention chamber and a heat dissipater forming a fluid flow path for thermal oxidation of a waste gas. In operation, the oxidation mixer facilitates a combustible mixture of the waste gas and an oxidant into an combustible waste gas stream, the oxidation chamber facilitates a primary combustion reaction of the combustible waste gas stream into an oxygenated waste gas stream, the retention chamber facilitates a secondary combustion reaction of the oxygenated waste gas stream into oxidized gases and the heat dissipator reduces the temperature of the flow of oxidized gases within the heat dissipator, which is communicated to a greenhouse gas processor that extracts greenhouse gas(es) from the vaporized oxidized gases. The greenhouse gas processor may condensate the greenhouse gas(es), acid neutralize the condensation of the greenhouse gas(es), and capture the acid neutralization of the condensation of the greenhouse gas(es).

The present disclosure relates to a boiler system that includes an oxyfuel boiler in which a stream of oxygen and a fuel are combusted to generate a stream of flue gas. A flue gas condenser condenses the cleaned flue gas. A flue gas compression unit produces a stream of pressurized carbon dioxide rich flue gas. A pressure control system measures and controls the pressure after the flue gas conditioning system to a predetermined set value. A flow control system measures and controls the flow after the flue gas compression unit to a predetermined set value. The present disclosure further relates to a method of operating such a boiler system for an oxy-fuel process as well as to a power plant comprising such a system.

A method for transferring thermal energy to a separate endothermic process includes: (a) providing a carbon dioxide (CO.sub.2) stream and a carbonaceous fuel to a heater; (b) reacting the carbonaceous fuel in the heater to produce a heated stream; (c) transferring heat from the heated stream to the separate endothermic process; (d) separating the CO.sub.2 stream from the heated stream after (c); and (e) recycling the CO.sub.2 stream to the heater after (d).

The present disclosure provides for improving flame propagation in a combustor, particularly in a combustor for use in a power production system and method. At least one stream being passed into the combustor (e.g., a fuel, an oxidant, a diluent, a coolant, a working fluid, water, or steam) can be independently heated to a temperature that is about the autoignition temperature of the fuel or greater. Further, flame stabilization, including promoting ignition, can be improved as described herein through controlled addition of one or more NOx species into the combustor or combustion chamber.

A carbon dioxide capturing apparatus using cold heat of liquefied natural gas (LNG) includes a heat exchanger to cool primary coolant using heat exchange between the primary coolant and the LNG; a chiller connected to the heat exchanger and configured to discharge capturing coolant colder than the primary coolant by performing a heat exchange between the capturing coolant and a cooling material; and a capturing cooler configured to capture carbon dioxide contained in flue gas by performing a heat exchange between the capturing coolant discharged from the chiller and the flue gas. A power generation system includes an LNG storage facility; a power generation facility discharging flue gas; a unit for heat exchange between the LNG and a coolant to regasify the LNG and cool the coolant; and a unit for capturing carbon dioxide contained in the flue gas by heat exchange between the discharged flue gas and the coolant.

A combined cooling, heating and power system is formed by integrating a CO.sub.2 and ORC cycle systems, and an LNG cold energy utilization system on the basis of an SOFC/GT hybrid power generation system. The combined systems provide utilization of energy and low carbon dioxide emission. The SOFC/GT is used as a prime mover, high-temperature, medium-temperature, and low-temperature waste heat of the system are recovered through a CO.sub.2 and ORC cycles, cold energy (for air conditioning and refrigeration), heat, power, natural gas, ice, and dry ice is provided by using LNG as a cold source of the CO.sub.2 cycle and the ORC cycle, and low carbon dioxide emission of the system is achieved by condensation and separation of CO.sub.2 from flue gas, so energy losses of the combined system is reduced, and efficient and cascade utilization of energy is achieved, thereby providing energy conservation and emission reduction effect.