A solar powered absorption cooling system employing refrigerant-absorbent solutions such as water and lithium bromide and hybrid storage capabilities, and a method of employing the system in refrigeration and air conditioning units. The system includes a first temperature control valve and second temperature control valve that together regulate the flow of solar heating fluid into the generator and substantially reduce absorbent crystal formation.

A thermochemical heat pump has a solvent evaporator (26), an evaporator exchanger (49) thermally associated with a hot source (27), a reactor having a solvent vapour inlet, at least one source of a saline composition containing at least one salt that is soluble in the solvent, and at least one cooling exchanger (81) thermally associated with a cold source. The reaction device (29) has at least one condensation reactor (52) with a solution inlet connected to the cooling exchanger, a solution outlet connected to the cooling exchanger, at least one injection of saline composition between the outlet and the inlet of the condensation reactor (52), and a valve for adjusting the mass flow of each salt introduced into the liquid solution by this injection.

This invention relates to using an imidazolium bromide ionic liquid as an additive to lithium bromide in the absorbent for an absorption chiller. The imidazolium bromide ionic liquid is useful to increase the working region and to lower the risk of crystallization in an absorption chiller. The invention provides an absorption chiller comprising a mixture of a refrigerant and an absorbent, and the absorbent comprises lithium bromide and one or more imidazolium bromide ionic liquids.

An absorption cycle apparatus including a working fluid is presented. The working fluid includes a metal halide, water and a zwitterion additive, wherein the zwitterion additive includes an amino acid, 2,2′-[(phosphonomethyl)imino]diaceticacid, 3-[(2-hydroxyethyl)amino]-1-propanesulfonic acid, or combinations thereof. A method of controlling crystallization in a working fluid of an absorption cycle apparatus is also presented.

This invention relates to using a guanidinium-based ionic liquid as an absorbent material in an absorption chiller. The invention provides an absorption chiller comprising a mixture of a refrigerant and an absorbent, and the absorbent is a guanidinium-based ionic liquid. A preferred refrigerant is water. This invention also provides a method for synthesizing N,N,N′,N′,N″,N″-hexamethylguanidinium acetate.

The invention relates to a thermochemical heat pump comprising a solvent evaporator (26), an evaporator exchanger (49) thermally associated with a hot source (27), a reaction device (29) comprising a solvent vapour inlet, at least one source of a saline composition containing at least one salt that is soluble in said solvent, at least one cooling exchanger (81) thermally associated with a cold source. The reaction device (29) comprises at least one condensation reactor (52) comprising a solution inlet connected to said cooling exchanger, a solution outlet connected to said cooling exchanger, at least one injection of saline composition between the outlet and the inlet of the condensation reactor (52), and a device for adjusting the mass flow of each salt introduced into the liquid solution by this injection.

This invention relates to using an imidazolium bromide ionic liquid as an additive to lithium bromide in the absorbent for an absorption chiller. The imidazolium bromide ionic liquid is useful to increase the working region and to lower the risk of crystallization in an absorption chiller. The invention provides an absorption chiller comprising a mixture of a refrigerant and an absorbent, and the absorbent comprises lithium bromide and one or more imidazolium bromide ionic liquids.

An absorption cycle apparatus including a working fluid is presented. The working fluid includes a metal halide, water and a zwitterion additive, wherein the zwitterion additive includes an amino acid, 2,2-[(phosphonomethyl)imino]diaceticacid, 3-[(2-hydroxyethyl)amino]-1-propanesulfonic acid, or combinations thereof. A method of controlling crystallization in a working fluid of an absorption cycle apparatus is also presented.

An absorption cooling system that includes a plurality of solar collectors, a generator containing a dilute absorbent-refrigerant solution, a condenser, an evaporator, an absorber, a heat exchanger located between the generator and the absorber, first, second, and third storage tanks, a first temperature control valve located between the solar collectors and the first storage tank, a second temperature control valve located between the first storage tank and the generator, and a plurality of additional valves, wherein the first temperature control valve and the second temperature control valve are configured to regulate a flow of a heating fluid into the generator by automatically toggling between an open mode or a closed mode in response to a controller signal indicating a presence or an absence of a set point of a solid absorbent content in the dilute absorbent-refrigerant solution of the generator.

An absorption cooling system that includes a plurality of solar collectors, a generator containing a dilute absorbent-refrigerant solution, a condenser, an evaporator, an absorber, a heat exchanger located between the generator and the absorber, first, second, and third storage tanks, a first temperature control valve located between the solar collectors and the first storage tank, a second temperature control valve located between the first storage tank and the generator, and a plurality of additional valves, wherein the first temperature control valve and the second temperature control valve are configured to regulate a flow of a heating fluid into the generator by automatically toggling between an open mode or a closed mode in response to a controller signal indicating a presence or an absence of a set point of a solid absorbent content in the dilute absorbent-refrigerant solution of the generator.