A system and method for argon and nitrogen extraction from a feed stream comprising hydrogen, methane, nitrogen and argon, such as a low-pressure tail gas of an ammonia production plant is provided. The disclosed system and method provides for a rectification system wherein an argon depleted gaseous stream and a methane rich liquid stream are produced and subsequently combined in whole or in part prior to vaporization. Nitrogen and argon containing streams may also be produced from the rectification system. An argon stripping column arrangement is also disclosed where residual argon is removed from the methane-rich fuel gas and recycled back to the feed stream.

A system and method for argon and nitrogen extraction from a feed stream comprising hydrogen, methane, nitrogen and argon, such as tail gas of an ammonia production plant is provided. The disclosed system and method provides for nitrogen-argon rectification and the methane rejection within a column system comprised of at least one distillation column. Nitrogen and argon are further separated and to produce liquid products. An argon stripping column arrangement is disclosed where residual argon is further removed from the methane-rich fuel gas and recycled back to the feed stream.

A process for cryogenic separation of a feed stream containing methane and air gases in which: the feed stream is cooled in order to produce a cooled stream, at least one portion of the cooled stream is sent to one level of a distillation column, a bottom stream is drawn off from the distillation column, the bottom stream being enriched in methane relative to the feed stream, a stream enriched in oxygen and in nitrogen relative to the feed stream is drawn off from the distillation column, at least one noncombustible dilution stream that is more volatile than oxygen is introduced into the distillation column at at least one level lower than the one at which the cooled stream is introduced. The dilution stream is extracted from the feed stream. Facility for producing biomethane by purification of biogases derived from non-hazardous waste storage facilities (NHWSF) implementing the process.

A process for cryogenic separation of a feed stream containing methane and air gases in which: the feed stream is cooled in order to produce a cooled stream, at least one portion of the cooled stream is sent to one level of a distillation column, a bottom stream is drawn off from the distillation column, the bottom stream being enriched in methane relative to the feed stream, a stream enriched in oxygen and in nitrogen relative to the feed stream is drawn off from the distillation column, at least one noncombustible dilution stream that is more volatile than oxygen is introduced into the distillation column at at least one level lower than the one at which the cooled stream is introduced. The dilution stream is extracted from the feed stream. Facility for producing biomethane by purification of biogases derived from non-hazardous waste storage facilities (NHWSF) implementing the process.

A system and method for removing nitrogen from natural gas using two fractionating columns, that may be stacked, and a plurality of separators and heat exchangers, with horsepower requirements that are 50-80% of requirements for prior art systems. The fractionating columns operate at different pressures. A feed stream is separated with a vapor portion feeding the first column to produce a first column bottoms stream that is split into multiple portions at different pressures and first column overhead stream that is cooled and separated into vapor and liquid portions to control subcooling of the vapor portion prior to feeding the second column. Heat exchange between first column and second column streams provides first column reflux and reboil heat for a second column ascending vapor stream. Three sales gas streams are produced, each at a different pressure.

A process and an apparatus are disclosed for separation of a hydrocarbon gas stream containing methane and heavier hydrocarbons and significant quantities of nitrogen and carbon dioxide. The gas stream is cooled and expanded, then fractionated in a first distillation column into a first overhead vapor and a hydrocarbon liquid stream containing the majority of the carbon dioxide. The hydrocarbon liquid stream is fractionated into a hydrocarbon vapor stream and a less volatile fraction comprised of heavier hydrocarbons. The first overhead vapor is cooled, expanded, and separated into vapor and liquid streams. Both streams are cooled and expanded before feeding a second distillation column that produces a second overhead vapor that is predominantly nitrogen and a bottom liquid that is predominantly methane. The bottom liquid is vaporized and combined with the hydrocarbon vapor stream to form a volatile residue gas fraction containing the majority of the methane.

The present invention relates to a cold box cycle which allows for independent control of the heat supplied for reboilers associated with the separation columns. More specifically, the invention relates to the tight control of the hydrogen removal separation, thus avoiding the possibility of excess reboiling in this separation. Optimal reboiling also results in a lower temperature of the hydrogen depleted liquid from this separation. As this stream is used to provide a portion of the cooling at the cold end of the primary heat exchanger, lower temperatures facilitate cooling of the incoming syngas feed, reducing carbon monoxide (CO) losses into the crude hydrogen stream from the high pressure separator. Lower CO in the crude hydrogen allows for smaller hydrogen purification equipment.

A method for separating nitrogen from an inlet gas having less than 25 mole % nitrogen includes supplying the inlet gas having less than 25 mole % nitrogen to a nitrogen separation system configured with cryogenic refrigeration.

A system and method for removing nitrogen from natural gas using two fractionating columns, that may be stacked, and a plurality of separators and heat exchangers, with horsepower requirements that are 50-80% of requirements for prior art systems. The fractionating columns operate at different pressures. A feed stream is separated with a vapor portion feeding the first column to produce a first column bottoms stream that is split into multiple portions at different pressures and first column overhead stream that is cooled and separated into vapor and liquid portions to control subcooling of the vapor portion prior to feeding the second column. Heat exchange between first column and second column streams provides first column reflux and reboil heat for a second column ascending vapor stream. Three sales gas streams are produced, each at a different pressure.

A system and method for argon and nitrogen extraction and liquefaction from a low-pressure tail gas of an ammonia production plant is provided. The preferred tail gas of the ammonia production plant comprises methane, nitrogen, argon, and hydrogen. The disclosed system and method provides for the methane rejection via rectification and hydrogen rejection by way of a side stripper column or phase separator. The resulting nitrogen and argon containing stream is separated and liquefied in a double column distillation system.