Processes and apparatuses for recovering a high purity carbon dioxide stream. A first separation zone that may include a cryogenic fractionation column provides the high-purity CO.sub.2 stream. A vapor stream from the cryogenic fractionation column is passed to a second separation zone to separate the CO.sub.2 from the other components. The second separation zone may include a pressure swing adsorption unit or a solvent separation unit. The second separation zone provides a hydrogen enriched gas stream that may be used in a gas turbine. The second stream from the second separation zone includes carbon dioxide and, after a pressure increase in a compressor, may be recycled to the first separation zone.

A system and method for capturing and separating carbon dioxide from mixed gas streams. The gas stream is processed in a structure including a compression module comprising a plurality of compressors, intercoolers and inter-stage condensate separators. The flow path from the compression module includes a plurality of flow separators, gas stream splitters, heat exchangers and at least a first mixer and a first expander. The gas stream is sequentially compressed and cooled to form process condensate and separate it from the compressed gas stream. The gas stream is further dried and cooled to liquefy carbon dioxide and separate it from the non-condensable portion. Selective expansion of liquid carbon dioxide streams provides cooling for the system, and further energy efficiency is achieved by selective recycling of portions of gas streams, allowing for compact equipment and economical operation, while providing for high purity product streams of carbon dioxide.

A method to condense and recover CO.sub.2 from CO.sub.2 containing streams. A first step involve providing at more than one heat exchanger, with each heat exchanger having a first flow path for passage of a first fluid and a second flow path for passage of a second fluid. A second step involves passing a stream of very cold natural gas sequentially along the second flow path of each heat exchanger until it is heated for distribution and concurrently passing a CO.sub.2 containing stream sequentially along the first flow path of each heat exchanger, allowing the water vapor portion of the CO.sub.2 containing stream to condense and precipitate on the condensing heat exchangers. A third step involves passing a water vapor free CO.sub.2 containing stream to a cryogenic heat exchanger to condense, precipitate and recover CO.sub.2. This processes results in the recovery of CO.sub.2 and water vapor from CO.sub.2 containing streams using condensing heat exchangers, chiller, compressor, expander and power generator to recover the low value thermal heat available in CO.sub.2 containing waste streams.

A thermoacoustic refrigerator includes at least one pair of pulse combustion tubes (10), preferably Rijke tubes, each tube (10) having a pair of spaced-apart Stirling engines (12), coupled together but with no separating membrane therebetween.

The invention relates to a method and apparatus for removing CO.sub.2 gas emissions from a coal combustion power plant, comprising a means for physically removing the CO.sub.2 gas from the coal, and then using a turbo compressor and turbo expander device to produce super chilled air, which can then be mixed with the CO.sub.2 gas to form frozen CO.sub.2 crystals which can agglomerate together to form dry ice blocks, wherein the ice blocks can be easily transported and stored, and/or used for commercial purposes (such as for the beverage industry). The heating (compression) and cooling (expansion) processes preferably generate additional energy which can then be used to offset the substantial costs associated with separating the CO.sub.2 gas from the coal.

A method of simultaneously liquefying CO2 and cooling natural gas, including providing a compressed CO2 loop, comprising a pressurized cooling stream, wherein a first compressed cooling stream and a second compressed cooling stream are produced by a CO2 compressor. Providing at least a portion of the first compressed cooling stream to a CO2 liquefaction system, wherein the first compressed cooling stream provides at least a portion of the refrigeration required by the CO2 liquefaction system. Providing at least a portion of the second compressed cooling stream to the pre-cooling system of a natural gas liquefaction system, wherein the second compressed cooling stream provides at least a portion of the refrigeration required by the natural gas pre-cooling.

The disclosure relates generally to methods as well as configurations for cryogenically separating carbon dioxide and hydrogen and particularly to methods and configurations for cryogenically separating carbon dioxide and hydrogen from a syngas stream to produce high quality carbon dioxide stream(s) and/or high quality hydrogen stream(s). In an embodiment, a system for cryogenically separating carbon dioxide from a syngas stream comprises a pressure swing adsorption system, wherein the pressure swing adsorption (PSA) system separates a syngas input stream into a hydrogen-rich stream and a carbon dioxide-rich stream. The PSA unit outputs the hydrogen-rich stream and the carbon dioxide-rich stream and a carbon dioxide capturing unit cryogenically converts the carbon dioxide-rich stream to a dense phase. The hydrogen-rich stream may be used as a fuel source and/or a feedstock for chemical synthesis, and the dense phase carbon dioxide may be sequestered and stored, or used as a chemical feedstock.

A marine vessel and method for carbon capture and sequestration are described. The marine vessel includes a buoyant hull, a cryogenic storage tank within the hull, and a gaseous carbon dioxide loading manifold. The marine vessel also includes a carbon dioxide liquefaction system in fluid communication with the cryogenic storage tank downstream of the carbon dioxide liquefaction system and with the gaseous carbon dioxide loading manifold upstream of the carbon dioxide liquefaction system. Finally, the marine vessel includes a carbon dioxide supercritical system in fluid communication with the cryogenic storage tank. In operation, the marine vessel moves between multiple locations, where gaseous carbon dioxide is onboarded, liquified and stored. Thereafter, the marine vessel transports the liquified carbon dioxide to a location adjacent an offshore geological reservoir. The liquefied carbon dioxide is then pressurized to produce supercritical carbon dioxide, which is then injected directly into the reservoir from the marine vessel.

A system and method for power generation and CO.sub.2 sequestration include a fuel cell system configured to generate power using natural gas (NG), a container configured to store liquid natural gas (LNG), and a fluid processor configured to convert LNG received from the container into NG and to convert exhaust output from the fuel cell system to dry ice by transferring heat between and the LNG and the exhaust.

A process may be utilized to coat urea-containing granules with organic polymers. The process may involve compressing gaseous carbon dioxide and condensing the carbon dioxide to obtain liquid carbon dioxide, increasing the pressure and/or the temperature above the critical point of carbon dioxide and obtaining supercritical carbon dioxide, dissolving an organic polymer in the supercritical carbon dioxide to obtain a polymer-containing solution, and mixing the polymer-containing solution with urea-containing granules and lowering the temperature and/or the pressure below the critical point of carbon dioxide and obtaining coated urea-containing granules and gaseous carbon dioxide. In some cases the organic polymer may include biodegradable polymers, and the polymer-containing solution may contain between 20 to 70% by weight biodegradable polymers.