A method and system for producing liquid air wherein liquid refrigerant is cycled between two core tanks maintained at a temperature sufficient to liquify compressed air passed through condensing tubing in the interior of the core tanks. Liquid refrigerant is cycled by alternating high pressure gas from a high pressure tank to one of the core tanks, which forces liquid refrigerant from this tank through an expansion device to expand a portion of the liquid refrigerant to absorb heat in the other core tank, the resulting refrigerant gas being driven into a low pressure tank. A compression device transfers the refrigerant gas from the low pressure tank to the high pressure tank and maintains the pressure in the high pressure tank. Connections between the low and high pressure tanks and the core tanks are reversed with each cycle.

A system and method for liquefying a hydrogen gas feed stream uses a high-pressure hydrogen stream from a storage source to provide refrigeration to the system. After providing refrigeration to the system, the hydrogen from the high-pressure storage source is at a pressure not lower than the pressure of a cold box feed stream of the system, where the cold box feed stream includes the hydrogen gas feed stream and at least one recycle stream, and is not recycled back through the system but instead exits the system.

Systems and processes for detecting leaks into a refrigeration system having a heat exchanger where the process side is configured to operate at a higher pressure than the refrigerant side. The system includes a refrigerant circulation system including a refrigerant feed pipe fluidly connected to and configured to provide a refrigerant to an inlet of the refrigerant side of the heat exchanger, as well as a refrigerant effluent pipe fluidly connected to and configured to receive a refrigerant from an outlet of the refrigerant side of the heat exchanger. One or more sensors are provided, the sensors being configured to measure a property of the refrigerant, such as temperature, pressure, or flow rate, for example. Additionally, the system for detecting leaks includes a digital control system configured to provide an alert when a signal from at least one of the one or more sensors is indicative of a leak from the process side of the heat exchanger to the refrigerant side of the heat exchanger.

A method of efficient cold recovery from a liquid hydrogen stream includes warming a cold liquid hydrogen stream by indirect heat exchange with a cold feed air stream in an ASU sub-cooler, thereby producing a warmed liquid hydrogen stream. Wherein at least a portion of the cool inlet air stream is introduced into a cold booster, thereby producing the compressed cool feed air stream. Wherein at least a first portion of the further cooled feed air stream is introduced into an expander, thereby producing an expanded feed air stream. Wherein a second portion of the further cooled feed air stream is further cooled, thereby producing the cold feed air stream. And, wherein the liquid oxygen stream has a first molar mass flow rate, and the cold liquid hydrogen stream has a second molar flow rate that is between 1.5 and 2.5 times the first molar mass flow rate.

Certain embodiments of the invention relate to a facility for refrigerating a fluid to a cryogenic temperature, comprising a circuit for the fluid to be refrigerated, comprising an upstream end connected to a source and a downstream end connected to a refrigerated and/or liquefied fluid collection member, the facility comprising at least one exchanger for precooling the fluid leaving the upstream end, the precooling exchanger exchanging heat with a precooling circuit composed of a flow of vaporization gas from a user, the facility further comprising a heat exchanger assembly for cooling by heat exchange with the circuit of fluid to be cooled downstream of the precooling exchanger, the facility comprising a device for cooling by heat exchange with at least a part of the cooling heat exchanger assembly, said cooling device comprising a first refrigerator with a refrigeration cycle of a cycle gas in a working circuit, the cycle gas preferably comprising hydrogen and/or helium, the working circuit of the first refrigerator comprising a member for compressing the cycle gas, a member for cooling the cycle gas, a member for expanding the cycle gas and a member for heating the cycle gas, the precooling exchanger being composed of at least one of the following materials: stainless steel or grades of stainless steel, Inconel, nickel, titanium or plastic material compatible with use at cryogenic temperatures.

A process for liquefying hydrogen gas including the following is disclosed: cooling the hydrogen gas to an intermediate temperature by heat exchange with a refrigerant circulating in a refrigeration loop provided with a higher temperature expander and a lower temperature expander, wherein the outlet stream from the lower temperature expander contains some condensed refrigerant; a means is provided of separating the condensate from the circulating refrigerant; and further cooling of the hydrogen gas by heat exchange with evaporation and reheating of the said condensate.

The fluid in the refrigeration loop is typically methane (such as natural gas after removal of carbon dioxide, water vapor and other impurities), or nitrogen, or a mixture thereof.

A method and system for producing liquid air wherein liquid refrigerant is cycled between two core tanks maintained at a temperature sufficient to liquify compressed air passed through condensing tubing in the interior of the core tanks. Liquid refrigerant is cycled by alternating high pressure gas from a high pressure tank to one of the core tanks, which forces liquid refrigerant from this tank through an expansion device to expand a portion of the liquid refrigerant to absorb heat in the other core tank, the resulting refrigerant gas being driven into a low pressure tank. A compression device transfers the refrigerant gas from the low pressure tank to the high pressure tank and maintains the pressure in the high pressure tank. Connections between the low and high pressure tanks and the core tanks are reversed with each cycle.

A method of liquefying hydrogen, including dividing a hydrogen stream into at least a first fraction and a second fraction, introducing the first fraction into a refrigeration cycle of a hydrogen liquefaction unit, thereby liquefying a product hydrogen stream, withdrawing one or more warm hydrogen stream(s) from the hydrogen liquefaction unit, and returning the one or more warm hydrogen stream to the hydrogen stream, wherein the second fraction is combined with a high-pressure nitrogen stream to form an ammonia synthesis gas stream.

Contemplated plants for flexible ethane recovery and rejection by allowing to switch the top reflux to the demethanizer from residue gas to the deethanizer overhead product and by controlling the flow ratio of feed gas to two different feed gas exchangers. Moreover, the pressure of the demethanizer is adjusted relative to the deethanizer pressure for control of the ethane recovery and rejection.

A precool heat exchanger system receives a stream of first cryogenic fluid for warming a second cryogenic fluid. A first splitter receives and divides a first cryogenic fluid stream into a motive stream and a secondary cooling stream. An ejector receives the motive stream. An expansion device receives and expands the secondary cooling stream and directs at least a portion of it to the precool heat exchanger system so that a second cryogenic fluid is cooled. First cryogenic fluid from the precool heat exchanger is directed into the ejector suction port and the pressure therein is reduced. A primary separation device divides a first cryogenic fluid mixed phase stream from the ejector into a first cryogenic fluid vapor stream and a liquid recycle stream that exit the primary separation device. A recycle pump directs first cryogenic fluid to the first splitter.