Integrated plants and associated processes for producing ammonia and sulfuric acid have been developed comprising air separation and water electrolysis subsystems and which make surprisingly efficient use of the products from these subsystems (i.e. oxygen and nitrogen from the former and hydrogen and oxygen from the latter). The invention is particularly suitable for use as part of an integrated fertilizer production plant.

A method of controlling an industrial gas production facility comprising: receiving time-dependent power data receiving time-dependent operational characteristic data; defining one or more power constraints for the operational parameters of the power network; defining one or more process constraints for the operational parameters of each industrial gas plant; generating, based on the power data, the operational characteristic data, the one or more power constraints and the one or more process constraints, control set point values for the one or more industrial gas plants to achieve a pre-determined production parameter for the industrial gas production facility; and sending the control set point values to a control system to control the one or more industrial gas plants by adjusting one or more control set points of the industrial gas plants to achieve the pre-determined production parameter for the industrial gas production facility.

A method of controlling an industrial gas production facility comprising: receiving time-dependent power data receiving time-dependent operational characteristic data; defining one or more power constraints for the operational parameters of the power network; defining one or more process constraints for the operational parameters of each industrial gas plant; generating, based on the power data, the operational characteristic data, the one or more power constraints and the one or more process constraints, control set point values for the one or more industrial gas plants to achieve a pre-determined production parameter for the industrial gas production facility; and sending the control set point values to a control system to control the one or more industrial gas plants by adjusting one or more control set points of the industrial gas plants to achieve the pre-determined production parameter for the industrial gas production facility.

A process and a related equipment for making ammonia make-up synthesis gas are disclosed, where: a hydrocarbon feedstock is reformed obtaining a raw ammonia make-up syngas stream; said raw syngas is purified in a cryogenic purification section refrigerated by a nitrogen-rich stream produced in an air separation unit; the nitrogen-rich stream at output of said cryogenic section is further used for adjusting the hydrogen/nitrogen ratio of the purified make-up syngas; an oxygen-rich stream is also produced in said air separation unit and is fed to the reforming section.

Method for the preparation of ammonia synthesis gas by a combination of ATR or secondary reforming process using oxygen from an air separation unit and electrolysis of water for the production of ammonia synthesis gas.

A method including, compressing a first hydrogen stream, and expanding a portion to produce a hydrogen refrigeration stream, cooling a second hydrogen stream thereby producing a cool hydrogen stream, wherein at least a portion of the refrigeration is provided by a nitrogen refrigeration stream, further cooling at least a portion of the cool hydrogen stream thereby producing a cold hydrogen stream, and a warm hydrogen refrigeration stream wherein at least a portion of the refrigeration is provided by the hydrogen refrigeration stream, compressing the warm hydrogen refrigeration stream, mixing the balance of the compressed first hydrogen stream with a high-pressure gaseous nitrogen stream to form an ammonia synthesis gas stream, and wherein the first hydrogen stream and the warm hydrogen refrigeration stream are compressed in the same compressor.

A method of co-producing liquid hydrogen and ammonia, including a hydrogen generator, a nitrogen generator, and a HLU is presented. The method includes pressurizing a hydrogen stream from the hydrogen generator in a hydrogen compressor, dividing the pressurized hydrogen into at least a first portion and a second portion, wherein the first portion includes at least part of the flow of a first refrigeration cycle in the HLU, and the second part comprises at least part of the feed to an ammonia plant. The method also includes pressurizing a nitrogen stream from the nitrogen generator in a HP nitrogen compressor, dividing the pressurized nitrogen stream into at least a first part and a second part, wherein the first part comprises at least part of the flow of a second refrigeration cycle in the HLU, and the second part comprises at least part of the feed to the ammonia plant.

A novel concept for a high energy and material efficient nitric acid production process and system is provided, wherein the nitric acid production process and system, particularly integrated with an ammonia production process and system, is configured to recover a high amount of energy out of the ammonia that it is consuming, particularly in the form of electricity, while maintaining a high nitric acid recovery in the conversion of ammonia to nitric acid. The energy recovery and electricity generation process comprises pressurizing a liquid gas, such as air, oxygen and/or N.sub.2, subsequently evaporating and heating the pressurized liquid gas, particularly using low grade waste heat generated in the production of nitric acid and/or ammonia, and subsequently expanding the evaporated pressurized liquid gas over a turbine. In particular, the generated electricity is at least partially used to power an electrolyzer to generate the hydrogen needed for the production of ammonia. The novel concepts set out in the present application are particularly useful in the production of nitric acid based on renewable energy sources.

Method for the preparation of ammonia synthesis gas by a combination of ATR or secondary reforming process using oxygen from an air separation unit and electrolysis of water for the production of ammonia synthesis gas.

The production of NH.sub.3, Urea, UAN, and DAP, starting from inherently intermittent renewable energy, such as photovoltaic and wind power, is made economical by use of molten salt thermal energy storage (ESS) and water electrolyzer (WE) concentrated oxygen. The process inputs and equipment apply air; hydrogen-containing fuel, such as biomass; WE (concentrated O.sub.2 and H.sub.2 producing); thermal ESS equipped with a turbine and generator to steady the electricity input to the WE; and an ammonia plant. The thermal ESS enables minimally sized process equipment including, the WE, the air separation unit and less hydrogen storage. The concentrated oxygen from the water electrolyzer uniquely enables high-temperature thermal ESS input, water and CO2 collection and other fertilizer products, including Urea, UAN and DAP. DAP production is facilitated by using WE high-purity O.sub.2 oxidation and ammonium nitrate is similarly facilitated by anhydrous NH.sub.3 oxidation.