One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing a integrated heat exchanger, multiple gas-liquid separators, external refrigeration systems, and a rectifier attached to a liquid product drum.

A system for separating olefinic hydrocarbon and hydrogen in an effluent fluid stream from a dehydrogenation reactor includes a heat exchanger that receives and partially condenses the effluent fluid stream so that a mixed phase effluent stream is formed. A primary separation device receives and separates the mixed phase effluent stream into a primary vapor stream and a primary liquid product stream. A heat exchanger receives and partially condenses the primary vapor stream so that a mixed phase primary stream is formed. A secondary separation device receives and separates the mixed phase primary stream into a secondary vapor stream and a secondary liquid product stream. A heat exchanger receives and warms the secondary vapor stream to provide refrigeration for partially condensing the effluent fluid stream and a heat exchanger receives and warms the secondary vapor stream to provide refrigeration for partially condensing the primary vapor stream. A mixed refrigerant compression system provides refrigerant to a heat exchanger to provide refrigeration.

A process for purifying a gaseous feed stream of natural gas including methane, CO.sub.2 and heavy hydrocarbons including step a): cooling the gaseous feed stream in a heat exchanger; step b): introducing the cooled stream into a phase-separating chamber to produce a liquid stream depleted in methane and enriched in heavy hydrocarbons and a gaseous stream; step c): separating the gaseous stream obtained from step b) in a first membrane producing at least one CO.sub.2-enriched permeate stream and a residual stream enriched in methane; step d): introducing the residual stream obtained from step c) into a phase-separator to produce a liquid stream and a gaseous stream; step e): heating the gaseous stream obtained from step d) by introducing it into the heat exchanger used in step a) counter-currentwise with the feed stream thereby producing a gaseous stream depleted in CO.sub.2 and enriched in methane.

A main heat exchanger receives and partially condenses an effluent fluid stream so that a mixed phase effluent stream is formed. A primary separation device receives and separates the mixed phase effluent stream into a primary vapor stream including hydrogen and a primary liquid stream including an olefinic hydrocarbon. The main heat exchanger receives and warms at least a portion of the primary vapor stream to provide refrigeration for partially condensing the effluent fluid stream. The main heat exchanger also receives, warms and partially vaporizes the primary liquid stream. A mixed refrigerant compression system also provides refrigeration in the main heat exchanger.

One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing a integrated heat exchanger, multiple gas-liquid separators, external refrigeration systems, and a rectifier attached to a liquid product drum.

A system for separating olefinic hydrocarbon and hydrogen in an effluent fluid stream from a dehydrogenation reactor includes a heat exchanger that receives and partially condenses the effluent fluid stream so that a mixed phase effluent stream is formed. A primary separation device receives and separates the mixed phase effluent stream into a primary vapor stream and a primary liquid product stream. A heat exchanger receives and partially condenses the primary vapor stream so that a mixed phase primary stream is formed. A secondary separation device receives and separates the mixed phase primary stream into a secondary vapor stream and a secondary liquid product stream. A heat exchanger receives and warms the secondary vapor stream to provide refrigeration for partially condensing the effluent fluid stream and a heat exchanger receives and warms the secondary vapor stream to provide refrigeration for partially condensing the primary vapor stream. A mixed refrigerant compression system provides refrigerant to a heat exchanger to provide refrigeration

One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing a integrated heat exchanger, multiple gas-liquid separators, external refrigeration systems, and a rectifier attached to a liquid product drum.

A main heat exchanger receives and partially condenses an effluent fluid stream so that a mixed phase effluent stream is formed. A primary separation device receives and separates the mixed phase effluent stream into a primary vapor stream including hydrogen and a primary liquid stream including an olefinic hydrocarbon. The main heat exchanger receives and warms at least a portion of the primary vapor stream to provide refrigeration for partially condensing the effluent fluid stream. The main heat exchanger also receives, warms and partially vaporizes the primary liquid stream. A mixed refrigerant compression system also provides refrigeration in the main heat exchanger.

A method and a system for separating a feed flow which contains at least hydrogen and a hydrocarbon with three or four carbon atoms per molecule, in particular propane, propylene, propadiene, butane, 1-butene, 2-butene, and/or 1,3-butadiene. The condensed feed flow is cooled over multiple cooling steps in at least two heat exchangers and is then separated into a condensate and a residual gas flow after each cooling step. The at least two heat exchangers are operated at least two different temperature levels, wherein a hot heat exchanger is operated at an average temperature level, and a cold heat exchanger is operated at a lower temperature level. An internal refrigerant which is made of a part of one of the condensate flows and a part of one of the residual gas flows, is used to dispense a part of the heat from the cold heat exchanger.

One or more specific embodiments disclosed herein includes a method for separating hydrogen from an olefin hydrocarbon rich compressed effluent vapor stream, employing a integrated heat exchanger, multiple gas-liquid separators, external refrigeration systems, and a rectifier attached to a liquid product drum.