A gas sensor includes a sensor element having electrode pads, metal terminal members connected to the respective electrode pads, separators, and lead wires connected to the rear ends of the metal terminal members. Each metal terminal member has a forward locking portion and a rear locking portion provided at the forward and rear ends, respectively. The separator is composed of a forward separator and a rear separator connected to each other. The forward separator includes a first locking portion having a rearward-facing surface, and the rear separator includes a second locking portion having a forward-facing surface. The metal terminal member is held between the forward separator and the rear separator in a state in which the forward locking portion is in locking engagement with the rearward-facing surface and the rear locking portion is in locking engagement with the forward-facing surface.

A sensor element includes: an element base including: a ceramic body made of an oxygen-ion conductive solid electrolyte, and having an inlet at one end portion thereof; at least one internal chamber located inside the ceramic body, and communicating with the gas inlet; and an electrochemical pump cell including an outer electrode, an inner electrode facing the chamber, and a solid electrolyte therebetween, and a porous leading-end protective layer covering a leading end surface and four side surfaces in a predetermined range of the element base on the one end portion, wherein the protective layer has an extension extending into the gas inlet and fixed to an inner wall surface of the ceramic body demarcating the gas inlet, and a gap communicating with the gas inlet is located in the protective layer, with demarcated by a portion of the protective layer continuous with the extension.

Methods for forming a metal oxide electrolyte improve ionic conductivity. Some of those methods involve applying a first metal compound to a substrate, converting that metal compound to a metal oxide, applying a different metal compound to the metal oxide, and converting the different metal compound to form a second metal oxide. That substrate may be in nanobar form that conforms to an orientation imparted by a magnetic field or an electric field applied before or during the converting. Electrolytes so formed can be used in solid oxide fuel cells, electrolyzers, and sensors, among other applications.

Disclosed is a gas sensor element having: a solid electrolyte body containing oxygen-ion conductive ZrO.sub.2; a detection electrode disposed on the solid electrolyte body to be exposed to a gas under measurement; and a reference electrode disposed on the solid electrolyte body to be exposed to a reference gas. In the gas sensor element, the detection electrode contains Pt and ZrO.sub.2; the detection electrode has a thickness of 3 to 10 μm; the amount of ZrO.sub.2 contained relative to Pt in the detection electrode is 12 to 18 wt %; the detection electrode has a porosity of 5% or lower; and, in a particle size distribution graph of ZrO.sub.2 particles in the detection electrode, a cumulative value of peaks appearing in a range of 0.025 μm to 0.200 μm is 60 to 75%, and a cumulative value of peaks appearing in a range of 1.000 μm to 3.162 μm is 2 to 7%.

There is provided a method of manufacturing a gas sensor that includes: forming an insulating layer on a main surface of a substrate; forming a porous oxide layer on the insulating layer; and forming a porous metal layer on the porous oxide layer, wherein the forming the porous metal layer is performed by depositing a constituent material of the porous metal layer in an inclined direction with respect to a normal line of a main surface.

A solid electrolyte includes partially stabilized zirconia in which a stabilizer forms a solid solution in zirconia. The partially stabilized zirconia includes at least monoclinic phase particles and cubic phase particles as crystal particles that configure the partially stabilized zirconia, and an abundance ratio of the monoclinic phase particle is 5 to 25% by volume. The partially stabilized zirconia includes stabilizer low-concentration phase particles of which concentration of the stabilizer at a particle center is equal to or less than 1 mol %, as the crystal particles. The stabilizer low-concentration phase particles have a particle-size distribution of number frequency thereof having a peak at which an average particle size is 0.6 to 1.0 μm, and a particle size at 10% of a cumulative number is 0.5 μm or greater, and of the overall low-concentration phase particles, 50% by volume or greater belong to the peak.

A sensor element and fabrication method thereof, the sensor element includes: a main pump cell including an inner pump electrode facing a first inner space into which a measurement gas is introduced, an external pump electrode provided on an element surface, and a solid electrolyte therebetween; an auxiliary pump cell including an auxiliary pump electrode provided facing a second inner space, the external pump electrode, and the solid electrolyte therebetween; and a measurement pump cell including a measurement electrode, the external pump electrode, and the solid electrolyte therebetween. The inner pump electrode has a porosity of 10 - 25%, the auxiliary pump electrode has a porosity of 30 - 50%, a thickness ratio of both the electrodes is 1.0 - 4.0, and current flowing to the main pump cell has a current density of 0.05 - 0.5 mA/mm.sup.2 when the measurement gas has an oxygen concentration of 20.5%.

The ion sensor of the present invention is a current measurement type ion sensor that measures a current to measure a target ion, and includes an organic phase retaining layer containing an organic phase capable of forming an interface with the sample containing the target ion, a first electrode to which the organic phase retaining layer is laminated and containing a first insertion material composed of an inorganic compound, a second electrode arranged so as to face the organic phase holding layer and in contact with the sample.

A particulate matter sensor includes a shield through which exhaust gases flow in a direction of flow from upstream to downstream. A sensing element with a positive electrode and a negative electrode separated from the positive electrode by an electrode gap is located within the shield. The positive electrode includes a plurality of positive electrode branches each having positive electrode extensions extending downstream and separated from each other by positive electrode slots. A positive electrode extension tip for each has a positive electrode extension tip width. The negative electrode includes negative electrode branches each having negative electrode extensions extending upstream which are each flanked on each side thereof by a plurality of negative electrode slots. A negative electrode extension tip for each has a negative electrode extension tip width. A sum of the positive electrode extension tip widths is greater than a sum of the negative electrode extension tip widths.

A gas sensor includes a sensor element, and the sensor element includes a bottomed tubular solid electrolyte, a detection electrode provided on an outer surface of the solid electrolyte, a reference electrode provided on an inner surface of the solid electrolyte. The detection electrode of the sensor element includes a detection electrode section provided at a position on a tip side of an axial direction, an attachment electrode section provided at a position on a base end side of the axial direction, and a lead electrode section provided at a position where the detection electrode section is connected to the attachment electrode section. An insulating layer is provided between a tube of the solid electrolyte and each of the attachment electrode section and the lead electrode section.