A sensor element includes an element body, an upper connector electrode disposed on a first surface of the element body, and a protective layer that covers at least a front end-side part of the first surface. The protective layer includes a first specific protective layer having a thickness T1 of 10 μm or less. The ratio T1/T2 of the thickness T1 to the thickness T2 of a front-side portion of the protective layer which faces the front end of the first specific protective layer is 1.0 or less.

A sensor element includes: an element base made of an oxygen-ion conductive solid electrolyte; an internal space provided inside the element base; an electrochemical pump cell configured to pump oxygen in and out between the internal space and outside; a porous thermal shock resistant layer provided to an outermost peripheral part in a predetermined range at one end part of the element base, at which a gas inlet is provided; and a buffer layer adjacent to the thermal shock resistant layer on a pump surface and a heater surface. A thermal diffusion time in a thickness direction of the thermal shock resistant layer is 0.4 sec to 1.0 sec inclusive, and a total thermal diffusion time in a stacking direction of the thermal shock resistant layer and the buffer layer is 0.2 sec to 1.0 sec inclusive.

A sensor element includes an element base made of an oxygen-ion conductive solid electrolyte, an internal space provided inside the element base, an electrochemical pump cell that pumps oxygen in and out between the internal space and outside, and a porous thermal shock resistant layer provided to an outermost peripheral part in a predetermined range at one end part of the element base, at which a gas inlet is provided. A thermal diffusion time in a thickness direction of the thermal shock resistant layer is 0.4 sec to 1.0 sec inclusive. A thermal diffusion time at a leading end part of the thermal shock resistant layer covering the gas inlet at a farthest leading end position at the one end part is longest, and a thermal diffusion time at a pump surface is longer than a thermal diffusion time at a heater surface.

A gas sensor includes a sensor element having electrode pads, metal terminal members connected to the respective electrode pads, separators, and lead wires connected to the rear ends of the metal terminal members. Each metal terminal member has a forward locking portion and a rear locking portion provided at the forward and rear ends, respectively. The separator is composed of a forward separator and a rear separator connected to each other. The forward separator includes a first locking portion having a rearward-facing surface, and the rear separator includes a second locking portion having a forward-facing surface. The metal terminal member is held between the forward separator and the rear separator in a state in which the forward locking portion is in locking engagement with the rearward-facing surface and the rear locking portion is in locking engagement with the forward-facing surface.

A mixed-potential type gas sensor capable of preferably determining the concentration of THC including a kind of gas having a large C number is provided. A sensor element composed of an oxygen-ion conductive solid electrolyte is provided with, on its surface, a sensing electrode formed of a cermet of Pt, Au, and an oxygen-ion conductive solid electrolyte, and includes a reference electrode and a porous surface protective layer that covers at least said sensing electrode. An Au abundance ratio on a surface of noble metal particles forming the sensing electrode is 0.3 or more. The surface protective layer has a porosity of 28% to 40%, a thickness of 10 to 50 μm, and an area ratio of a coarse pore having a pore size of 1 μm or larger of 50% or more; or has a porosity of 28% to 40% and a thickness of 10 to 35 μm.

A gas sensor includes a sensing element having an electrode pad a metal terminal, and a separator that has insertion holes in which the metal terminal is held. The metal terminal includes a main body and an elastic portion that is integrally connected to the main body and is elastically connected to the electrode pad at a predetermined contact point. The main body includes a front-end-side restricting portion and a rear-end-side restricting portion that restrict the movement of the main body by contacting wall surfaces of the insertion hole when the main body moves in a direction intersecting the direction of an axial line. The contact point is located between the front-end-side restricting portion and the rear-end-side restricting portion in the direction of the axial line. The front-end-side restricting portion and the rear-end-side restricting portion are connected to each other so that a flat board portion is interposed therebetween.

A gas sensor includes a sensing element that includes an electrode pad, a metal terminal, and a separator. The metal terminal includes a lead-wire-connecting portion, a main body, a protruding piece that protrudes from a front-end side, and an elastic portion connected to an end of the protruding piece and to the electrode pad. An area S1 of a first opposed surface of a primary surface facing an insertion hole of the separator is larger than an area S2 of a second opposed surface of a secondary surface facing the insertion hole, and a part of the second opposed surface contacts an inner circumferential surface of the separator forming the insertion hole, and the first opposed surface is separated from the inner circumferential surface, where surfaces of the main body and the protruding piece that are located opposite the elastic portion are the primary surface and the secondary surface.

A metal terminal includes a front-side terminal member and a rear-side terminal member. The front-side terminal member includes a female connection portion, and the rear-side terminal member includes a male connection portion. The female connection portion has an insertion port in which the male connection portion is inserted. The insertion port is formed in a shape that prevents the insertion port and the male connection portion from coming into contact with each other when the male connection portion is inserted therein. The female connection portion includes a terminal contact portion which brings the male connection portion and the female connection portion into contact with each other by pressing the male connection portion toward the female connection portion inside the female connection portion.

A sensor element includes: an element base including: a ceramic body made of an oxygen-ion conductive solid electrolyte, and having an inlet at one end portion thereof; at least one internal chamber located inside the ceramic body, and communicating with the gas inlet; and an electrochemical pump cell including an outer electrode, an inner electrode facing the chamber, and a solid electrolyte therebetween, and a porous leading-end protective layer covering a leading end surface and four side surfaces in a predetermined range of the element base on the one end portion, wherein the protective layer has an extension extending into the gas inlet and fixed to an inner wall surface of the ceramic body demarcating the gas inlet, and a gap communicating with the gas inlet is located in the protective layer, with demarcated by a portion of the protective layer continuous with the extension.

A first gas sensor having a first sensor element includes a first protective cover that protects the first sensor element, and a second gas sensor having a second sensor element includes a second protective cover that protects the second sensor element. The first protective cover is coated with an oxidation catalyst for one target component from among a plurality of target components, and the second protective cover is coated with an inert catalyst for the one target component.